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Nitridophosphate

{{Short description|Class of inorganic chemical compounds}}

A nitridophosphate is an inorganic compound that contains nitrogen bound to a phosphorus atom, considered as replacing oxygen in a phosphate.

Anions include NPN PN3 P3N6. Related compounds include the oxonitridophosphates{{cite journal |last1=Pritzl |first1=Reinhard M. |last2=Prinz |first2=Nina |last3=Strobel |first3=Philipp |last4=Schmidt |first4=Peter J. |last5=Johrendt |first5=Dirk |last6=Schnick |first6=Wolfgang |title=From Framework to Layers Driven by Pressure – The Monophyllo-Oxonitridophosphate β-MgSrP 3 N 5 O 2 and Comparison to its α-Polymorph |journal=Chemistry – A European Journal |date=20 July 2023 |volume=29 |issue=41 |doi=10.1002/chem.202301218|doi-access=free }} imidonitridophosphates,{{Cite journal |last1=Vogel |first1=Sebastian |last2=Schnick |first2=Wolfgang |date=2018-09-20 |title=SrP 3 N 5 NH: A Framework-Type Imidonitridophosphate Featuring Structure-Directing Hydrogen Bonds |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201803210 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=53 |pages=14275–14281 |doi=10.1002/chem.201803210 |pmid=30004596 |s2cid=51616212 |issn=0947-6539|url-access=subscription }} nitridoborophosphates,{{cite journal |last1=Bertschler |first1=Eva-Maria |last2=Bräuniger |first2=Thomas |last3=Dietrich |first3=Christian |last4=Janek |first4=Jürgen |last5=Schnick |first5=Wolfgang |title=Li 47 B 3 P 14 N 42 —A Lithium Nitridoborophosphate with [P 3 N 9 ] 12− , [P 4 N 10 ] 10− , and the Unprecedented [B 3 P 3 N 13 ] 15− Ion |journal=Angewandte Chemie International Edition |date=18 April 2017 |volume=56 |issue=17 |pages=4806–4809 |doi=10.1002/anie.201701084|pmid=28370871 }} and nitridosilicatephosphates.{{Cite journal |last1=Eisenburger |first1=Lucien |last2=Oeckler |first2=Oliver |last3=Schnick |first3=Wolfgang |date=March 2021 |title=High-Pressure High-Temperature Synthesis of Mixed Nitridosilicatephosphates and Luminescence of AE SiP 3 N 7 :Eu 2+ ( AE =Sr, Ba) |journal=Chemistry – A European Journal |language=en |volume=27 |issue=13 |pages=4461–4465 |doi=10.1002/chem.202005495 |issn=0947-6539 |pmc=7986791 |pmid=33464635}} By changing the phosphorus, related materials include nitridovanadates and nitridorhenates.{{Cite journal |last1=Chaushli |first1=Azad |last2=Jacobs |first2=Herbert |last3=Weisser |first3=Ulrike |last4=Strähle |first4=Joachim |date=September 2000 |title=Li5ReN4, ein Lithium–Nitridorhenat(VII) mit anti-Flußspat-Überstruktur |url=https://onlinelibrary.wiley.com/doi/10.1002/1521-3749(200009)626:93.0.CO;2-T |journal=Zeitschrift für anorganische und allgemeine Chemie |volume=626 |issue=9 |pages=1909–1914 |doi=10.1002/1521-3749(200009)626:9<1909::AID-ZAAC1909>3.0.CO;2-T|url-access=subscription }}

Nitridophosphate compounds include elements from the alkali metals, alkaline earths, first row transition metals, rare earth elements, and some other main group elements.{{cite journal |last1=Kloß |first1=Simon D. |last2=Schnick |first2=Wolfgang |title=Nitridophosphates: A Success Story of Nitride Synthesis |journal=Angewandte Chemie International Edition |date=11 June 2019 |volume=58 |issue=24 |pages=7933–7944 |doi=10.1002/anie.201812791}}

Characteristics

Nitridophosphate compounds nearly always contain phosphorus in tetrahedral configuration. They can be characterised by the condensation index K which is the ratio of numbers of phosphorus tetrahedral centres to nitrogen vertices. As more nitrogen atoms are shared between phosphorus, condensation increases. The maximum is for P3N5 which no longer has any capacity for cations. For K of 1/2 three dimensional frameworks are produced. For 2/7 or 3/7 layered arrangements of tetrahedra are produced. For 1/3 chains or ring structures are prominent. 1/4 is for uncondensed PN4 compounds. Tow PN4 tetrahedra can also share an edge: P2N6, as the P-N bond is not very polarised, so there is less electrostatic repulsion. Uncondensed compounds are sensitive to air and water but highly condensed compounds are water or acid stable.

Nitridophosphate compounds are usually insulators and are transparent to light.

Formation

Heating P3N5 with a metal nitride at gigapascal pressure and a temperatures of over 1000 °C forms nitridophosphates. P3N5 decomposes over 850°C at ambient pressure. However there are a few nitridophosphates that do no require such high temperatures to form.{{Cite journal |last1=Bertschler |first1=Eva-Maria |last2=Dietrich |first2=Christian |last3=Leichtweiß |first3=Thomas |last4=Janek |first4=Jürgen |last5=Schnick |first5=Wolfgang |date=2018-01-02 |title=Li + Ion Conductors with Adamantane-Type Nitridophosphate Anions β-Li 10 P 4 N 10 and Li 13 P 4 N 10 X 3 with X =Cl, Br |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201704305 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=1 |pages=196–205 |doi=10.1002/chem.201704305 |pmid=29027753 |issn=0947-6539|url-access=subscription }}{{cite journal |last1=Wendl |first1=Sebastian |last2=Mardazad |first2=Sara |last3=Strobel |first3=Philipp |last4=Schmidt |first4=Peter J. |last5=Schnick |first5=Wolfgang |title=HIP to be Square: Simplifying Nitridophosphate Synthesis in a Hot Isostatic Press |journal=Angewandte Chemie |date=5 October 2020 |volume=132 |issue=41 |pages=18397–18400 |doi=10.1002/ange.202008570|bibcode=2020AngCh.13218397W |pmc=7590079 }}

Heating ammonia under pressure with red phosphorus, and metals, metal nitrides or metal azides is a method called ammonothermal synthesis.{{cite journal |last1=Mallmann |first1=Mathias |last2=Wendl |first2=Sebastian |last3=Schnick |first3=Wolfgang |title=Crystalline Nitridophosphates by Ammonothermal Synthesis |journal=Chemistry – A European Journal |date=11 February 2020 |volume=26 |issue=9 |pages=2067–2072 |doi=10.1002/chem.201905227|pmid=31909508 |pmc=7027869 }}

Use

Nitridophosphates are under investigation as luminescent materials, that can covert blue light into red.

List

class="wikitable"

!formula

!system

!space group

!unit cell

!volume

!density

!comment

!reference

HPN2

|tetragonal

|I{{overbar|4}}2d

|a = 4.6182 c = 7.0204 Z = 4

|

|

|

|{{Cite journal |last1=Wendl |first1=Sebastian |last2=Schnick |first2=Wolfgang |date=2018-10-22 |title=SrH 4 P 6 N 12 and SrP 8 N 14 : Insights into the Condensation Mechanism of Nitridophosphates under High Pressure |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201803125 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=59 |pages=15889–15896 |doi=10.1002/chem.201803125 |pmid=30136742 |s2cid=52066954 |issn=0947-6539|url-access=subscription }}{{Cite journal |last1=Schnick |first1=W. |last2=Lücke |first2=J. |date=April 1992 |title=Darstellung, Kristallstruktur und IR-spektroskopische Untersuchung von Phosphor(V)-nitrid-imid, HPN 2 |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19926100120 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=610 |issue=4 |pages=121–126 |doi=10.1002/zaac.19926100120 |issn=0044-2313}}

HPN3

|

|

|

|

|

|

|{{Cite journal |last1=Schnick |first1=Wolfgang |last2=Schultz-Coulon |first2=Verena |date=February 1993 |title=Ca 2 PN 3 : A New Phosphorus( V ) Nitride with One-Dimensional Infinite Chains of Corner-Sharing PN 4 Tetrahedra |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.199302801 |journal=Angewandte Chemie International Edition in English |language=en |volume=32 |issue=2 |pages=280–281 |doi=10.1002/anie.199302801 |issn=0570-0833}}

β-HP4N7

|monoclinic

|C2/c

|a = 12.873 b = 4.6587 c = 8.3222 β = 102.351° Z = 4

|487.55

|3.037

|colourless

|{{Cite journal |last1=Baumann |first1=Dominik |last2=Schnick |first2=Wolfgang |date=2014-08-04 |title=High-Pressure Polymorph of Phosphorus Nitride Imide HP 4 N 7 Representing a New Framework Topology |url=https://pubs.acs.org/doi/10.1021/ic500767f |journal=Inorganic Chemistry |language=en |volume=53 |issue=15 |pages=7977–7982 |doi=10.1021/ic500767f |issn=0020-1669|url-access=subscription }}

γ-HP4N7

|monoclinic

|C2/c

|a=6.82983 b=7.24537 c=8.96504 β = 111.5557° Z = 4

|412.604

|3.572

|high pressure form > 12 GPa; P in trigonal bipyramid

|{{Cite journal |last1=Baumann |first1=Dominik |last2=Schnick |first2=Wolfgang |date=2014-12-22 |title=Pentacoordinate Phosphorus in a High-Pressure Polymorph of Phosphorus Nitride Imide P 4 N 6 (NH) |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201406086 |journal=Angewandte Chemie International Edition |language=en |volume=53 |issue=52 |pages=14490–14493 |doi=10.1002/anie.201406086 |pmid=25124527 |issn=1433-7851|url-access=subscription }}

LiPN2

|

|

|

|

|

|

|

Li7PN4

|cubic

|P43n

|a=9.3648 Z=8

|

|

|tetrahedra

|{{Cite journal |last1=Schnick |first1=Wolfgang |last2=Luecke |first2=Jan |date=July 1990 |title=Synthesis and crystal structure of lithium phosphorus nitride Li7PN4: The first compound containing isolated PN4-tetrahedra |url=https://linkinghub.elsevier.com/retrieve/pii/002245969090070E |journal=Journal of Solid State Chemistry |language=en |volume=87 |issue=1 |pages=101–106 |doi=10.1016/0022-4596(90)90070-E}}

β-Li10P4N10

|trigonal

|

|a=8.71929 c=21.4656 Z=6

|1413.3

|2.35015

|colourless; tetrahedron of 4 tetrahedra

|

α-Li10P4N10

|cubic

|

|

|

|

|>80°C

|

Li5P2N5

|monoclinic

|C2/c

|a=14.770 b=17.850 c=4.860 β =93.11°

|

|

|layered, high pressure

|{{Cite journal |last1=Bertschler |first1=Eva-Maria |last2=Niklaus |first2=Robin |last3=Schnick |first3=Wolfgang |date=2018-01-12 |title=Reversible Polymerization of Adamantane-type [P 4 N 10 ] 10− Anions to Honeycomb-type [P 2 N 5 ] 5− Layers under High-Pressure |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201704975 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=3 |pages=736–742 |doi=10.1002/chem.201704975 |pmid=29136304 |issn=0947-6539|url-access=subscription }}

Li4PN3

|orthorhombic

|Pccn

|a=9.6597 b=11.8392 c=4.8674

|

|

|chains

|{{Cite journal |last1=Bertschler |first1=Eva-Maria |last2=Niklaus |first2=Robin |last3=Schnick |first3=Wolfgang |date=2017-07-18 |title=Li 12 P 3 N 9 with Non-Condensed [P 3 N 9 ] 12− -Rings and its High-Pressure Polymorph Li 4 PN 3 with Infinite Chains of PN 4 -Tetrahedra |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201700979 |journal=Chemistry – A European Journal |language=en |volume=23 |issue=40 |pages=9592–9599 |doi=10.1002/chem.201700979 |pmid=28543928 |issn=0947-6539|url-access=subscription }}

Li12P3N9

|monoclinic

|Cc

|a=12.094 b=7.649 c=9.711 β=90.53°

|

|

|ring of 3 tetrahedra

|

Li18P6N16

|monoclinic

|P{{overbar|1}}

|a=5.4263 b=7.5354 c=9.8584 α=108.481° β=99.288° γ=104.996° Z=1

|355.8

|2.496

|tricyclic

|{{Cite journal |last1=Bertschler |first1=Eva-Maria |last2=Dietrich |first2=Christian |last3=Janek |first3=Jürgen |last4=Schnick |first4=Wolfgang |date=2017-02-10 |title=Li 18 P 6 N 16 —A Lithium Nitridophosphate with Unprecedented Tricyclic [P 6 N 16 ] 18− Ions |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201605316 |journal=Chemistry – A European Journal |language=en |volume=23 |issue=9 |pages=2185–2191 |doi=10.1002/chem.201605316 |pmid=27977044 |issn=0947-6539|url-access=subscription }}

Li13P4N10Cl3

|cubic

|Fm{{overbar|3}}m

|a=13.Z=8 Z=8

|2704.27

|2.2624

|colourless;

|

Li13P4N10Br3

|cubic

|Fm{{overbar|3}}m

|a=14.1096 Z=8

|2809.0

|2.8088

|colourless;

|

LiP4N7

|orthorhombic

|P212121

|a=4.5846 b=8.009 c=13.252 Z=4

|485.8

|3.130

|air stable; grey

|{{Cite journal |last1=Schneider |first1=Stefanie |last2=Klenk |first2=Sebastian |last3=Kloss |first3=Simon D. |last4=Schnick |first4=Wolfgang |date=2024-01-11 |title=Please Mind the Gap: Highly Condensed P–N Networks in LiP 4 N 7 and Li 3− x P 6 N 11− x (NH) x |journal=Chemistry – A European Journal |language=en |volume=30 |issue=3 |pages=e202303251 |doi=10.1002/chem.202303251 |pmid=37874966 |issn=0947-6539|doi-access=free }}

Li1.34P6N9.34(NH)1.66

|monoclinic

|P{{overbar|1}}

|a=4.691 b=7.024 c=12.736, α=87.73° β=80.28° γ=70.55° Z=2

|390.0

|2.988

|air stable; grey

|

BeP2N4

|cubic

|Fd{{overbar|3}}

|a=7.1948 Z=8

|372.44

|

|bulk modulus 325 GPa

|{{Cite journal |last1=Vogel |first1=Sebastian |last2=Bykov |first2=Maxim |last3=Bykova |first3=Elena |last4=Wendl |first4=Sebastian |last5=Kloß |first5=Simon D. |last6=Pakhomova |first6=Anna |last7=Dubrovinskaia |first7=Natalia |last8=Dubrovinsky |first8=Leonid |last9=Schnick |first9=Wolfgang |date=2020-02-10 |title=Nitride Spinel: An Ultraincompressible High-Pressure Form of BeP 2 N 4 |journal=Angewandte Chemie |language=en |volume=132 |issue=7 |pages=2752–2756 |doi=10.1002/ange.201910998 |bibcode=2020AngCh.132.2752V |issn=0044-8249|doi-access=free }}

BP3N6

|monoclinic

|P21/c

|a=5.027 b=4.5306 c=17.332 β=106.387° Z=4

|378.7

|3.293

|

|{{Cite journal |last1=Vogel |first1=Sebastian |last2=Buda |first2=Amalina T. |last3=Schnick |first3=Wolfgang |date=October 2018 |title=United in Nitride: The Highly Condensed Boron Phosphorus Nitride BP 3 N 6 |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201808111 |journal=Angewandte Chemie International Edition |language=en |volume=57 |issue=40 |pages=13202–13205 |doi=10.1002/anie.201808111 |pmid=30088854 |s2cid=51934156 |issn=1433-7851|url-access=subscription }}

Li47B3P14N42

|trigonal

|P3c1

|a=19.3036 c=18.0200

|

|

|

|{{Cite journal |last1=Bertschler |first1=Eva-Maria |last2=Bräuniger |first2=Thomas |last3=Dietrich |first3=Christian |last4=Janek |first4=Jürgen |last5=Schnick |first5=Wolfgang |date=2017-04-18 |title=Li 47 B 3 P 14 N 42 —A Lithium Nitridoborophosphate with [P 3 N 9 ] 12− , [P 4 N 10 ] 10− , and the Unprecedented [B 3 P 3 N 13 ] 15− Ion |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201701084 |journal=Angewandte Chemie International Edition |language=en |volume=56 |issue=17 |pages=4806–4809 |doi=10.1002/anie.201701084 |pmid=28370871 |issn=1433-7851|url-access=subscription }}

NaPN2

|

|

|

|

|

|

|{{Cite journal |last1=Pucher |first1=Florian J. |last2=Hummel |first2=Franziska |last3=Schnick |first3=Wolfgang |date=April 2015 |title=CuPN 2 : Synthesis, Crystal Structure, and Electronic Properties |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500009 |journal=European Journal of Inorganic Chemistry |language=en |volume=2015 |issue=11 |pages=1886–1891 |doi=10.1002/ejic.201500009 |issn=1434-1948|url-access=subscription }}

NaP4N7

|

|

|

|

|

|

|

Na3P6N11

|

|

|

|

|

|

|

Mg2PN3

|orthorhombic

|Cmc21

|a=9.723 b=5.6562 c=4.7083

|

|

|band gap 5.0 eV

|{{Cite journal |last1=Mallmann |first1=Mathias |last2=Maak |first2=Christian |last3=Niklaus |first3=Robin |last4=Schnick |first4=Wolfgang |date=2018-09-18 |title=Ammonothermal Synthesis, Optical Properties, and DFT Calculations of Mg 2 PN 3 and Zn 2 PN 3 |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/chem.201803293 |journal=Chemistry – A European Journal |language=en |volume=24 |issue=52 |pages=13963–13970 |doi=10.1002/chem.201803293 |pmid=30044518 |s2cid=51715277 |issn=0947-6539|url-access=subscription }}

MgP8N14

|orthorhombic

|

|a=8.364 b=5.0214 c=23.196

|974.3

|3.192

|

|{{Cite journal |last1=Wendl |first1=Sebastian |last2=Seidl |first2=Lisa |last3=Schüler |first3=Patrick |last4=Schnick |first4=Wolfgang |date=2020-12-21 |title=Post-Synthetic Modification: Systematic Study on a Simple Access to Nitridophosphates |journal=Angewandte Chemie International Edition |language=en |volume=59 |issue=52 |pages=23579–23582 |doi=10.1002/anie.202011835 |issn=1433-7851 |pmc=7756662 |pmid=32941701}}

AlP6N11

|monoclinic

|Cm

|a=4.935 b=8.161 c=9.040 β=98.63°

|

|

|grey; layered; thermal expansion 16.0 ppm/K

|{{Cite journal |last1=Ambach |first1=Sebastian J. |last2=Pointner |first2=Monika |last3=Falkai |first3=Sophie |last4=Paulmann |first4=Carsten |last5=Oeckler |first5=Oliver |last6=Schnick |first6=Wolfgang |date=2023-06-12 |title=Combining M N 6 Octahedra and PN 5 Trigonal Bipyramids in the Mica-like Nitridophosphates M P 6 N 11 ( M =Al, In) |journal=Angewandte Chemie |language=en |volume=135 |issue=24 |doi=10.1002/ange.202303580 |bibcode=2023AngCh.135E3580A |issn=0044-8249|doi-access=free }}

Ca2PN3

|orthorhombic

|Cmca

|a = 5.1914 b =10.3160 c = 11.289 Z = 8

|

|

|beige; chains

|

CaP8N14

|

|

|

|

|

|

|

Sc5P12N23O3

|tetragonal

|I41/acd

|a=12.3598 c=24.0151 Z=8

|3668.6

|3.500

|grey

|{{Cite journal |last1=Eisenburger |first1=Lucien |last2=Weippert |first2=Valentin |last3=Oeckler |first3=Oliver |last4=Schnick |first4=Wolfgang |date=2021-10-13 |title=High-Pressure Synthesis of Sc 5 P 12 N 23 O 3 and Ti 5 P 12 N 24 O 2 by Activation of the Binary Nitrides ScN and TiN with NH 4 F |journal=Chemistry – A European Journal |language=en |volume=27 |issue=57 |pages=14184–14188 |doi=10.1002/chem.202101858 |pmid=34407247 |pmc=8596507 |issn=0947-6539}}

TiP4N8

|orthorhombic

|Pmn21

|a=7.6065 b=4.6332 c=7.8601 Z=2

|227.01

|3.403

|

|{{Cite journal |last1=Eisenburger |first1=Lucien |last2=Weippert |first2=Valentin |last3=Paulmann |first3=Carsten |last4=Johrendt |first4=Dirk |last5=Oeckler |first5=Oliver |last6=Schnick |first6=Wolfgang |date=2022-05-02 |title=Discovery of Two Polymorphs of TiP 4 N 8 Synthesized from Binary Nitrides |journal=Angewandte Chemie International Edition |language=en |volume=61 |issue=19 |pages=e202202014 |doi=10.1002/anie.202202014 |issn=1433-7851 |pmc=9310718 |pmid=35179291}}

TiP4N8

|orthorhombic

|Pmn21

|a=22.9196 b=4.5880 c=8.0970 Z=6

|851.44

|3.322

|

|

Ti5P12N24O2

|tetragonal

|I41/acd

|a=a=12.1214 c=23.8458 Z=8

|3503.6

|3.713

|black; Ti3+ & Ti4+

|

MnP2N4

|hexagonal

|P6322

|a = 16.5543 c = 7.5058

|1781.3

|

|

|{{Cite journal |last1=Pucher |first1=Florian J. |last2=Karau |first2=Friedrich W. |last3=Schmedt auf der Günne |first3=Jörn |last4=Schnick |first4=Wolfgang |date=April 2016 |title=CdP 2 N 4 and MnP 2 N 4 – Ternary Transition-Metal Nitridophosphates |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201600042 |journal=European Journal of Inorganic Chemistry |language=en |volume=2016 |issue=10 |pages=1497–1502 |doi=10.1002/ejic.201600042 |issn=1434-1948}}

FeP8N14

|orthorhombic

|Cmca

|a=8.2693 = 5.10147 c=23.0776

|

|

|air stable

|{{Cite journal |last1=Kloß |first1=Simon D. |last2=Janka |first2=Oliver |last3=Block |first3=Theresa |last4=Pöttgen |first4=Rainer |last5=Glaum |first5=Robert |last6=Schnick |first6=Wolfgang |date=2019-03-26 |title=Open-Shell 3d Transition Metal Nitridophosphates M II P 8 N 14 ( M II =Fe, Co, Ni) by High-Pressure Metathesis |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201809146 |journal=Angewandte Chemie International Edition |language=en |volume=58 |issue=14 |pages=4685–4689 |doi=10.1002/anie.201809146 |pmid=30320436 |s2cid=52982994 |issn=1433-7851|url-access=subscription }}

CoP8N14

|orthorhombic

|Cmca

|a=8.25183 b=5.10337 c=22.9675

|

|

|air stable

|

NiP8N14

|orthorhombic

|Cmca

|a=8.23105 b=5.08252 c=22.8516

|

|

|air stable

|

CuPN2

|tetragonal

|I{{overbar|4}}2d

|a = 4.5029 c = 7.6157

|154.42

|

|band gap 1.67 eV

|

Zn2PN3

|orthorhombic

|Cmc21

|a = 9.37847 b = 5.47696 c = 4.92396 Z = 4

|

|

|colourless

|{{Cite journal |last1=Ambach |first1=Sebastian J. |last2=Pritzl |first2=Reinhard M. |last3=Bhat |first3=Shrikant |last4=Farla |first4=Robert |last5=Schnick |first5=Wolfgang |date=2024-02-07 |title=Nitride Synthesis under High-Pressure, High-Temperature Conditions: Unprecedented In Situ Insight into the Reaction |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c04433 |journal=Inorganic Chemistry |volume=63 |issue=7 |pages=3535–3543 |language=en |doi=10.1021/acs.inorgchem.3c04433 |pmid=38324917 |s2cid=267545137 |issn=0020-1669|url-access=subscription }}{{Cite journal |last1=Sedlmaier |first1=Stefan J. |last2=Eberspächer |first2=Moritz |last3=Schnick |first3=Wolfgang |date=March 2011 |title=High-Pressure Synthesis, Crystal Structure, and Characterization of Zn 2 PN 3 – A New catena -Polynitridophosphate |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.201000403 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=637 |issue=3–4 |pages=362–367 |doi=10.1002/zaac.201000403 |issn=0044-2313|url-access=subscription }}

Zn8P12N24O2

|tetragonal

|I{{overbar|4}}3m

|a=8.24239 c=8.24239

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|{{Cite journal |last1=Karau |first1=Friedrich |last2=Oeckler |first2=Oliver |last3=Schäfers |first3=Franz |last4=Niewa |first4=Rainer |last5=Schnick |first5=Wolfgang |date=August 2007 |title=Zn 8 [P 12 N 24 ]O 2 – ein Nitridophosphat-oxid mit Sodalith-Struktur |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200600322 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=633 |issue=9 |pages=1333–1338 |doi=10.1002/zaac.200600322 |issn=0044-2313|url-access=subscription }}

Zn8P12N24S2

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Zn8P12N24Se2

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Zn8P12N24Te2

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Zn7P12N24Cl2

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|sodalite structure

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GeP2N4

|orthorhombic

|Pna21

|a=9.547 b=7.542 c=4.6941 Z=4

|

|

|dark grey

|{{Cite journal |last1=Ambach |first1=Sebastian J. |last2=Somers |first2=Cody |last3=de Boer |first3=Tristan |last4=Eisenburger |first4=Lucien |last5=Moewes |first5=Alexander |last6=Schnick |first6=Wolfgang |date=2023-01-16 |title=Structural Influence of Lone Pairs in GeP 2 N 4 , a Germanium(II) Nitridophosphate |journal=Angewandte Chemie International Edition |language=en |volume=62 |issue=3 |pages=e202215393 |doi=10.1002/anie.202215393 |issn=1433-7851 |pmc=10107938 |pmid=36350660}}

Sr3P3N7

|monoclinic

|P2/c

|a=6.882 b=7.416 c=7.036 β=104.96° Z=2

|346.9

|4.345

|white; decompose in moist air; band gap 4.4 eV

|{{Cite journal |last1=Mallmann |first1=Mathias |last2=Wendl |first2=Sebastian |last3=Strobel |first3=Philipp |last4=Schmidt |first4=Peter J. |last5=Schnick |first5=Wolfgang |date=2020-05-15 |title=Sr 3 P 3 N 7 : Complementary Approach by Ammonothermal and High-Pressure Syntheses |journal=Chemistry – A European Journal |language=en |volume=26 |issue=28 |pages=6257–6263 |doi=10.1002/chem.202000297 |issn=0947-6539 |pmc=7318702 |pmid=32030819}}

Sr2SiP2N6

|orthorhombic

|C2221

|a = 6.0849 b = 8.8203 c = 10.2500

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|

|

|{{Cite journal |last1=Dialer |first1=Marwin |last2=Pointner |first2=Monika M. |last3=Wandelt |first3=Sophia L. |last4=Strobel |first4=Philipp |last5=Schmidt |first5=Peter J. |last6=Bayarjargal |first6=Lkhamsuren |last7=Winkler |first7=Björn |last8=Schnick |first8=Wolfgang |date=2023-12-03 |title=Order and Disorder in Mixed (Si, P)–N Networks Sr 2 SiP 2 N 6 :Eu 2+ and Sr 5 Si 2 P 6 N 16 :Eu 2+ |journal=Advanced Optical Materials |volume=12 |issue=13 |language=en |doi=10.1002/adom.202302668 |issn=2195-1071|doi-access=free }}

SrP8N14

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SrP3N5NH

|monoclinic

|P21/c

|a=5.01774 b=8.16912 c=12.70193 β=101.7848° Z=4

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SrH4P6N12

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Sr5Si2P6N16

|orthorhombic

|Pbam

|a = 9.9136 b = 17.5676 c = 8.3968

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SrAl5P4N10O2F3

|tetragonal

|I{{overbar|4}}m2

|a=11.1685 c=7.8485 Z=2

|978.99

|3.905

|

|{{Cite journal |last1=Pointner |first1=Monika M. |last2=Oeckler |first2=Oliver |last3=Schnick |first3=Wolfgang |date=2023-09-26 |title=Tetra-Face-Capped Octahedra in a Tetrahedra Network – Structure Determination and Scanning Transmission Electron Microscopy of SrAl 5 P 4 N 10 O 2 F 3 |journal=Chemistry – A European Journal |language=en |volume=29 |issue=54 |pages=e202301960 |doi=10.1002/chem.202301960 |pmid=37410334 |issn=0947-6539|doi-access=free }}

Sr3P5N10Cl

|orthorhombic

|Pnma

|a=12.240 b=12.953 c=13.427 Z=8

|

|

|

|{{Cite journal |last1=Wendl |first1=Sebastian |last2=Zipkat |first2=Mirjam |last3=Strobel |first3=Philipp |last4=Schmidt |first4=Peter J. |last5=Schnick |first5=Wolfgang |date=2021-02-23 |title=Synthesis of Nitride Zeolites in a Hot Isostatic Press |journal=Angewandte Chemie International Edition |language=en |volume=60 |issue=9 |pages=4470–4473 |doi=10.1002/anie.202012722 |issn=1433-7851 |pmc=7985876 |pmid=33201554}}

Sr3P5N10Br

|orthorhombic

|Pnma

|a=12.297 b=12.990 c=13.458 Z=8

|

|

|

|

AgPN2

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|

|

|

|

|

|{{Cite web |title=Электронное строение, химическая связь и некоторые физико-химические свойства кристаллов A1PN2(A1=H, Li, Na, Ag) - Пермина, Виктория Сергеевна - 02.00.04 - Физическая химия |url=https://freereferats.ru/product_info.php?products_id=4209 |access-date=2024-02-22 |website=freereferats.ru}}

CdP2N4

|hexagonal

|P6322

|a = 16.7197 c = 7.6428

|1850.3

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InP6N11

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|

|

|grey; layered

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BaP2N4

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Ba3P5N10Cl

|orthorhombic

|Pnma

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Ba3P5N10Br

|orthorhombic

|Pnma

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|

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BaSr2P6N12

|cubic

|Pa{{overbar|3}}

|a=10.0639 Z=4

|1019.3

|4.343

|

|

La2P3N7

|monoclinic

|C2/c

|

|

|

|

|{{Cite journal |last1=Kloß |first1=Simon D. |last2=Weidmann |first2=Niels |last3=Niklaus |first3=Robin |last4=Schnick |first4=Wolfgang |date=2016-09-19 |title=High-Pressure Synthesis of Melilite-type Rare-Earth Nitridophosphates RE 2 P 3 N 7 and a Ba 2 Cu[Si 2 O 7 ]-type Polymorph |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01611 |journal=Inorganic Chemistry |language=en |volume=55 |issue=18 |pages=9400–9409 |doi=10.1021/acs.inorgchem.6b01611 |pmid=27579899 |issn=0020-1669|url-access=subscription }}

Ce2P3N7

|monoclinic

|C2/c

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|

|

|

|

Ce4Li3P18N35

|hexagonal

|P63/m

|a=13.9318 c=8.1355

|

|

|

|{{Cite journal |last1=Kloß |first1=Simon D. |last2=Neudert |first2=Lukas |last3=Döblinger |first3=Markus |last4=Nentwig |first4=Markus |last5=Oeckler |first5=Oliver |last6=Schnick |first6=Wolfgang |date=2017-09-13 |title=Puzzling Intergrowth in Cerium Nitridophosphate Unraveled by Joint Venture of Aberration-Corrected Scanning Transmission Electron Microscopy and Synchrotron Diffraction |url=https://pubs.acs.org/doi/10.1021/jacs.7b07075 |journal=Journal of the American Chemical Society |language=en |volume=139 |issue=36 |pages=12724–12735 |doi=10.1021/jacs.7b07075 |pmid=28823161 |bibcode=2017JAChS.13912724K |issn=0002-7863|url-access=subscription }}

Pr2P3N7

|monoclinic

|C2/c

|a = 7.8006 b = 10.2221 c = 7.7798 β = 111.299° Z = 4

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Nd2P3N7

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|P{{overbar|4}}21m

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LiNdP4N8

|orthorhombic

|Pnma

|a=8.7305 b=7.8783 c=9.0881

|

|

|

|{{Cite journal |last1=Kloß |first1=Simon David |last2=Schnick |first2=Wolfgang |date=2015-09-14 |title=Rare-Earth-Metal Nitridophosphates through High-Pressure Metathesis |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201504844 |journal=Angewandte Chemie International Edition |language=en |volume=54 |issue=38 |pages=11250–11253 |doi=10.1002/anie.201504844 |pmid=26352033 |issn=1433-7851|url-access=subscription }}

Sm2P3N7

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|P{{overbar|4}}21m

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Eu2P3N7

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|P{{overbar|4}}21m

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|

|

Ho2P3N7

|

|P{{overbar|4}}21m

|a = 7.3589 c = 4.9986 Z = 2

|

|

|

|

Ho3[PN4]O

|tetragonal

|I4/mcm

|a = 6.36112 c = 10.5571 Z = 4

|

|

|

|{{Cite journal |last1=Kloß |first1=Simon D. |last2=Weidmann |first2=Niels |last3=Schnick |first3=Wolfgang |date=2017-04-03 |title=Antiperovskite Nitridophosphate Oxide Ho 3 [PN 4 ]O by High-Pressure Metathesis |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201601425 |journal=European Journal of Inorganic Chemistry |language=en |volume=2017 |issue=13 |pages=1930–1937 |doi=10.1002/ejic.201601425 |issn=1434-1948|url-access=subscription }}

Yb2P3N7

|

|P{{overbar|4}}21m

|

|

|

|

|

Hf9−xP24N52−4xO4x (x≈1.84)

|

|I41/acd

|a=12.4443 c=23.7674 Z=4

|3680.6

|

|

|{{Cite journal |last1=Kloß |first1=Simon D. |last2=Wandelt |first2=Sophia |last3=Weis |first3=Andreas |last4=Schnick |first4=Wolfgang |date=2018-03-12 |title=Accessing Tetravalent Transition-Metal Nitridophosphates through High-Pressure Metathesis |url=https://onlinelibrary.wiley.com/doi/10.1002/anie.201712006 |journal=Angewandte Chemie International Edition |language=en |volume=57 |issue=12 |pages=3192–3195 |doi=10.1002/anie.201712006 |pmid=29377432 |issn=1433-7851|url-access=subscription }}

References

{{Reflist}}

{{Nitrides}}

{{Phosphates}}

Category:Phosphorus(V) compounds

Category:Nitrides