Nonane
{{Distinguish|nonene|nonyne}}
{{Chembox
| Watchedfields = changed
| verifiedrevid = 470622939
| ImageFile = Nonane-2D-Skeletal.svg
| ImageClass = skin-invert-image
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageSize = 245
| ImageAlt = Skeletal formula of nonane
| ImageFile1 = NonaneFull.png
| ImageClass1 = skin-invert-image
| ImageFile1_Ref = {{chemboximage|correct|??}}
| ImageSize1 = 245
| ImageAlt1 = Skeletal formula of nonane with all implicit carbons shown, and all explicit hydrogens added
| ImageFile2 = Nonane 3D ball.png
| ImageClass2 = bg-transparent
| ImageFile2_Ref = {{chemboximage|correct|??}}
| ImageSize2 = 245
| ImageAlt2 = Ball-and-stick model of the nonane molecule
|Section1={{Chembox Identifiers
| CASNo = 111-84-2
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = T9W3VH6G10
| PubChem = 8141
| ChemSpiderID = 7849
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| EINECS = 203-913-4
| UNNumber = 1920
| MeSHName = nonane
| ChEBI = 32892
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 335900
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| RTECS = RA6115000
| Beilstein = 1696917
| Gmelin = 240576
| SMILES = CCCCCCCCC
| StdInChI = 1S/C9H20/c1-3-5-7-9-8-6-4-2/h3-9H2,1-2H3
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = BKIMMITUMNQMOS-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| C = 9
| H = 20
| Appearance = Colorless liquid
| Odor = Gasoline-like
| Density = 0.718 g/mL
| MeltingPtK = 219.0 to 220.0
| BoilingPtK = 423.5 to 424.1
| LogP = 5.293
| VaporPressure = 0.59 kPa (at 25.0 °C)
| HenryConstant = 1.7 nmol Pa−1 kg−1
| RefractIndex = 1.405
| MagSus = −108.13·10−6 cm3/mol
}}
|Section3={{Chembox Thermochemistry
| DeltaHf = −275.7 – −273.7 kJ mol−1
| DeltaHc = −6125.75 – −6124.67 kJ mol−1
| Entropy = 393.67 J K−1 mol−1
| HeatCapacity = 284.34 J K−1 mol−1
}}
|Section4={{Chembox Hazards
| GHSPictograms = {{GHS flame}} {{GHS exclamation mark}} {{GHS health hazard}}
| GHSSignalWord = DANGER
| HPhrases = {{H-phrases|226|304|315|319|332|336}}
| PPhrases = {{P-phrases|261|301+310|305+351+338|331}}
| NFPA-H = 0
| NFPA-F = 3
| NFPA-R = 0
| NFPA-S =
| FlashPtC = 31.0
| AutoignitionPtC = 205.0
| ExploLimits = 0.87–2.9%
| IDLH = N.D.{{PGCH|0466}}
| REL = TWA 200 ppm (1050 mg/m3)
|Section5={{Chembox Related
| OtherFunction_label = alkanes
| OtherFunction = {{Unbulleted list|Octane|Decane}}
}}
}}
Nonane is a linear alkane hydrocarbon with the chemical formula C9H20. It is a colorless, flammable liquid, occurring primarily in the component of the petroleum distillate fraction commonly called kerosene, which is used as a heating, tractor, and jet fuel.{{Cite web|title = Petroleum - Chemistry Encyclopedia - reaction, water, uses, elements, examples, gas, number, name|url = http://www.chemistryexplained.com/Ny-Pi/Petroleum.html|website = www.chemistryexplained.com|access-date = 2016-01-28}} Nonane is also used as a solvent, distillation chaser, fuel additive, and a component in biodegradable detergents.Health Council of the Netherlands: Committee on Updating of Occupational Exposure Limits. Nonane; Health-based Reassessment of Administrative Occupational Exposure Limits. The Hague: Health Council of the Netherlands, 2005; 2000/15OSH/155. http://www.gezondheidsraad.nl/sites/default/files/0015osh155.pdf {{Webarchive|url=https://web.archive.org/web/20180228161532/https://www.gezondheidsraad.nl/sites/default/files/0015osh155.pdf |date=2018-02-28 }} It is also a minor component of diesel fuel.{{Cite web |last=Simmons |first=Mark |date=2017-07-24 |title=Kerosene and Diesel Fuel Analysis By GCMS |url=https://www.smsanalytical.com/blog/kerosene-analysis-gcms |access-date=2024-10-19 |website=sms analytical |language=en-GB}}
Nonane has 35 structural isomers.
Its substituent form is nonyl. Its cycloalkane counterpart is cyclononane, (C9H18).
Unlike most alkanes, the numeric prefix in its name is from Latin, not Greek. (A name using a Greek prefix would be enneane.)
Combustion reactions
Nonane undergoes combustion reactions that are similar to other alkanes. In the presence of sufficient oxygen, nonane burns to form water and carbon dioxide.
When insufficient oxygen is available for complete combustion, the burning products include carbon monoxide.
:2C9H20 + 19O2 → 18CO + 20H2O
:
See also
References
{{Reflist}}
External links
- {{PGCH|0466}}
- [https://web.archive.org/web/20041208205355/http://physchem.ox.ac.uk/MSDS/NO/nonane.html MSDS at Oxford University]
- [http://www.3rd1000.com/chem301/nonane.htm List of isomers of nonane]
{{Alkanes}}
{{Hydrides by group}}