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Oxalate chloride

An oxalate chloride or oxalato chloride is a mixed anion compound contains both oxalate and chloride anions.

Related compounds include oxalate fluorides and oxalate bromides.{{Cite journal |last1=Lugwisha |first1=E. H. J. |last2=Mulokozi |first2=A. M. |last3=Masabo |first3=M. K. J. |date=November 1991 |title=Activation energy of thermal decomposition of LaC2O4Br |url=http://link.springer.com/10.1007/BF01912801 |journal=Journal of Thermal Analysis |language=en |volume=37 |issue=11–12 |pages=2567–2572 |doi=10.1007/BF01912801 |s2cid=95356620 |issn=0368-4466}}

Production

Oxalate chlorides may be produced by treating an oxalate salt with concentrated hydrochloric acid, or with a metal oxide dissolved in oxalic acid and hydrochloric acid solutions that are evaporated.{{Cite journal |last=Mulokozi |first=A.M. |date=June 1972 |title=The nature of products obtained from the reaction of hydrogen halides with some rare-earth metal oxalate hydrates |url=https://linkinghub.elsevier.com/retrieve/pii/0022508872900756 |journal=Journal of the Less Common Metals |language=en |volume=27 |issue=3 |pages=419–422 |doi=10.1016/0022-5088(72)90075-6}}

List

class="wikitable"

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!formula

!crystal

!space group

!cell

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Novgorodovaite

|Ca2(C2O4)Cl2•2H2O

|monoclinic

|I2/m

|a=6.936 b=7.382 c=7.443 β=94.3°

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|

|loses water over 205°C; refract: α=1.500 β=1.545 γ=1.568 2V=71° (−)

|{{Cite journal |last1=Jones |first1=Francis T. |last2=White |first2=Lawrence M. |date=July 1946 |title=The Composition, Optical and Crystallographic Properties of Two Calcium Oxalate-Chloride Double Salts |url=https://pubs.acs.org/doi/abs/10.1021/ja01211a075 |journal=Journal of the American Chemical Society |language=en |volume=68 |issue=7 |pages=1339–1342 |doi=10.1021/ja01211a075 |pmid=20991004 |issn=0002-7863}}{{Cite journal |last=Baran |first=Enrique J. |date=2014-12-17 |title=Review: Natural oxalates and their analogous synthetic complexes |url=https://www.tandfonline.com/doi/full/10.1080/00958972.2014.937340 |journal=Journal of Coordination Chemistry |language=en |volume=67 |issue=23–24 |pages=3734–3768 |doi=10.1080/00958972.2014.937340 |s2cid=96163581 |issn=0095-8972}}{{Cite journal |last1=Rastsvetaeva |first1=R. K. |last2=Chukanov |first2=N. V. |last3=Nekrasov |first3=Yu. V. |date=2001 |title=[No title found] |url=http://link.springer.com/10.1023/A:1012984825792 |journal=Doklady Chemistry |volume=381 |issue=1/3 |pages=329–331 |doi=10.1023/A:1012984825792|s2cid=91571345 }}

|Ca2(C2O4)Cl2•7H2O

|triclinic

|P{{overbar|1}}

|a = 7.3928 b = 8.9925 c = 10.484 α = 84.070 β = 70.95 γ = 88.545°

|655.3

|

|looses water at 25°C to 2H2O; refract: α=1.571 β=1.648 γ=1.718 2V=87° (−)

|{{Cite journal |last1=Piro |first1=Oscar E. |last2=Echeverría |first2=Gustavo A. |last3=González-Baró |first3=Ana C. |last4=Baran |first4=Enrique J. |date=February 2018 |title=Crystal structure and spectroscopic behavior of synthetic novgorodovaite Ca2(C2O4)Cl2·2H2O and its twinned triclinic heptahydrate analog |url=http://link.springer.com/10.1007/s00269-017-0907-0 |journal=Physics and Chemistry of Minerals |language=en |volume=45 |issue=2 |pages=185–195 |doi=10.1007/s00269-017-0907-0 |s2cid=103745968 |issn=0342-1791|hdl=11336/87551 |hdl-access=free }}

|Ca4(C2O4)3Cl2•8H2O

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|dubious

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octakis(ethyl(dimethyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese

|[NH(CH3)2(C2H5)]8[Mn4Cl4Cr4(C2O4)12]

|monoclinic

|P21

|a=13.8321 b=17.1042 c=20.4209 β=91.874°

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|{{Cite journal |last1=Lozančić |first1=Ana |last2=Renka |first2=Sanja |last3=Barišić |first3=Dario |last4=Burazer |first4=Sanja |last5=Molčanov |first5=Krešimir |last6=Pajić |first6=Damir |last7=Jurić |first7=Marijana |date=2023-06-19 |title=High Proton Conductivity of Magnetically Ordered 2D Oxalate-Bridged [Mn II Cr III ] Coordination Polymers with Irregular Topology |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c00443 |journal=Inorganic Chemistry |language=en |volume=62 |issue=24 |pages=9418–9428 |doi=10.1021/acs.inorgchem.3c00443 |pmid=37290133 |s2cid=259118281 |issn=0020-1669}}

octakis(diethyl(methyl)ammonium) dodecakis(μ-oxalato)-tetrachloro-tetra-chromium-tetra-manganese

|[NH(CH3)(C2H5)2]8[Mn4Cl4Cr4(C2O4)12]

|monoclinic

|P21

|a=14.1863 b=17.3479 c=20.4140 β=91.937°

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DABCO=1,4-diazabicyclo[2.2.2]octane;

|(DABCO-H+)2(DABCO-2H2+)[MnII(CH3OH)(Cl−)CrIII(oxalate)3]2−2(CH3OH)

|triclinic

|P{{overbar|1}}

|a=8.093 b=9.070 c=19.574 α=83.471° β=89.875° γ=86.765°

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|{{Cite journal |last1=Yoshitake |first1=Masashi |last2=Kubo |first2=Kazuya |last3=Endo |first3=Toru |last4=Noro |first4=Shin-ichiro |last5=Akutagawa |first5=Tomoyuki |last6=Nakamura |first6=Takayoshi |date=2016-03-15 |title=Structural Design of Coordination Polymers Based on Manganese and Chromium Ions Bridged by Oxalate Ligands |url=https://academic.oup.com/bcsj/article/89/3/354/7344617 |journal=Bulletin of the Chemical Society of Japan |language=en |volume=89 |issue=3 |pages=354–360 |doi=10.1246/bcsj.20150373 |issn=0009-2673}}

tetrakis(methylammonium) tetrakis(μ-oxalato)-octachloro-tetra-iron(iii) pentahydrate

|(MeNH3)2[Fe2(ox)2Cl4]·2.5H2O

|monoclinic

|P21/c

|a 10.7832 b 13.913 c 13.0578 β 104.060°

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|{{Cite journal |last1=Mastropietro |first1=Teresa F. |last2=Marino |first2=Nadia |last3=Munno |first3=Giovanni De |last4=Lloret |first4=Francesc |last5=Julve |first5=Miguel |last6=Pardo |first6=Emilio |last7=Armentano |first7=Donatella |date=2016-11-07 |title=Selective Guest Inclusion in Oxalate-Based Iron(III) Magnetic Coordination Polymers |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.6b01769 |journal=Inorganic Chemistry |language=en |volume=55 |issue=21 |pages=11160–11169 |doi=10.1021/acs.inorgchem.6b01769 |pmid=27749048 |issn=0020-1669}}

methylammonium (μ-hydroxo)-bis(μ-oxalato)-dichloro-di-iron(iii) trihydrate

|MeNH3[Fe2(OH)(ox)2Cl2]·2H2O

|monoclinic

|Cc

|a=8.945 b=14.936 c=12.408 β=108.531°

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methylammonium oxonium bis(μ-oxalato)-(μ-oxo)-dichloro-di-iron(iii) dihydrate

|(H3O)(MeNH3)[Fe2O(ox)2Cl2]·3H2O

|orthorhombic

|Fdd2

|a=14.914 b=23.507 c=9.261

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DMF = dimethylformamide

|Fe2(C2O4)Cl4(DMF)4

|triclinic

|P{{overbar|1}}

|a=8.3919 b=8.7834 c=11.2881 α=70.248° β=71.993° γ=64.423°

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|{{Cite journal |last1=Zhang |first1=Bin |last2=Zhang |first2=Yan |last3=Kurmoo |first3=Mohamedally |date=May 2007 |title=Preparation, crystal structure and magnetic property of a binuclear oxalate-bridged iron(III) compound: Fe2(C2O4)Cl4(DMF)4 (DMF=dimethylformamide) |url=https://linkinghub.elsevier.com/retrieve/pii/S0020169306006815 |journal=Inorganica Chimica Acta |language=en |volume=360 |issue=7 |pages=2513–2517 |doi=10.1016/j.ica.2006.10.028}}

|(dimim)2[Fe2Cl4(μ-ox)]

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|ionic liquid

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|{{Cite journal |last1=Cot |first1=Sergi |last2=Leu |first2=Meike K. |last3=Kalamiotis |first3=Alexis |last4=Dimitrakis |first4=Georgios |last5=Sans |first5=Victor |last6=de Pedro |first6=Imanol |last7=Cano |first7=Israel |date=July 2019 |title=An Oxalate-Bridged Binuclear Iron(III) Ionic Liquid for the Highly Efficient Glycolysis of Polyethylene Terephthalate under Microwave Irradiation |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cplu.201900075 |journal=ChemPlusChem |language=en |volume=84 |issue=7 |pages=786–793 |doi=10.1002/cplu.201900075 |pmid=31943995 |hdl=10234/185443 |s2cid=196896383 |issn=2192-6506|hdl-access=free }}

L2=1,4-bis(imidazol-1-ylmethyl)benzene

bis(1,1'-(1,4-Phenylenebis(methylene))bis-1H-imidazol-3-ium) (μ2-oxalato)-tetrachloro-bis(oxalato)-di-iron(iii)

|(H2-L2)2{Fe2(C2O4)3Cl4}

|triclinic

|P{{overbar|1}}

|a=10.6758 b=10.7457 c=10.8774 α=113.219° β=109.138° γ=99.294° Z=1

|1020.8

|1.624

|emerald

|{{Cite journal |last1=Wang |first1=Lei |last2=Wang |first2=Wenqiang |last3=Guo |first3=Dong |last4=Zhang |first4=Ao |last5=Song |first5=Yaoguang |last6=Zhang |first6=Yiheng |last7=Huang |first7=Keke |date=2014 |title=Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations |url=http://xlink.rsc.org/?DOI=C4CE00357H |journal=CrystEngComm |language=en |volume=16 |issue=24 |pages=5437–5449 |doi=10.1039/C4CE00357H |issn=1466-8033}}

tetramelaminium trioxalatoferrate(III) chloride dihydrate

|(C3H7N6)4{Fe(C2O4)3}Cl·2H2O

|monoclinic

|P21/c

|a=11.597 b=22.299 c=13.655 β=94.344° Z=4

|3521

|1.698

|green

|{{Cite journal |last1=Wang |first1=Lei |last2=Wang |first2=Wenqiang |last3=Guo |first3=Dong |last4=Zhang |first4=Ao |last5=Song |first5=Yaoguang |last6=Zhang |first6=Yiheng |last7=Huang |first7=Keke |date=2014 |title=Design and syntheses of hybrid supramolecular architectures: based on [Fe(C 2 O 4 ) 3 ] 3− metallotectons and diverse organic cations |url=http://xlink.rsc.org/?DOI=C4CE00357H |journal=CrystEngComm |language=en |volume=16 |issue=24 |pages=5437–5449 |doi=10.1039/C4CE00357H |issn=1466-8033}}

methylammonium (μ-aqua)-tris(μ-chloro)-(μ-oxalato)-iron(iii)-potassium

|K(MeNH3)[Fe(ox)Cl3(H2O)

|monoclinic

|P21/m

|a=8.725 b=7.508 c=9.026 β=112.421°

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diethylmethylammonium

|[NH(CH3)(C2H5)2][FeCl2(C2O4)]

|monoclinic

|P21/c

|a=8.5125 b=10.775 c=14.9703 β=104.798° Z=4

|1327.6

|1.516

|yellow; proton conductor

|{{Cite journal |last1=Burazer |first1=Sanja |last2=Molčanov |first2=Krešimir |last3=Šantić |first3=Ana |last4=Klaser |first4=Teodoro |last5=Wenger |first5=Emmanuel |last6=Pajić |first6=Damir |last7=Jagličić |first7=Zvonko |last8=Popović |first8=Jasminka |last9=Jurić |first9=Marijana |date=2021-09-24 |title=Humidity-Sensing Properties of an 1D Antiferromagnetic Oxalate-Bridged Coordination Polymer of Iron(III) and Its Temperature-Induced Structural Flexibility |journal=Materials |language=en |volume=14 |issue=19 |pages=5543 |doi=10.3390/ma14195543 |doi-access=free |pmid=34639934 |pmc=8509436 |bibcode=2021Mate...14.5543B |issn=1996-1944}}

bis(Tetramethylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii)

|Me4N[FeIII(ox)Cl2]

|monoclinic

|P21/c

|a=7.9441 b=8.6093 c=17.8251 β=91.869

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|{{Cite journal |last1=Xu |first1=Hong-Bin |last2=Wang |first2=Zhe-Ming |last3=Liu |first3=Tao |last4=Gao |first4=Song |date=2007-04-01 |title=Synthesis, Structure, and Magnetic Properties of (A)[Fe III (oxalate)Cl 2 ] (A = Alkyl Ammonium Cations) with Anionic 1D [Fe III (oxalate)Cl 2 ] - Chains |url=https://pubs.acs.org/doi/10.1021/ic0618854 |journal=Inorganic Chemistry |language=en |volume=46 |issue=8 |pages=3089–3096 |doi=10.1021/ic0618854 |pmid=17352466 |issn=0020-1669}}

hexakis(Triethylammonium) hexakis(μ2-oxalato)-dodecachloro-hexa-iron(iii)

|Et3NH[FeIII(ox)Cl2]

|triclinic

|P{{overbar|1}}

|a=10.9609 b=14.4602 c=14.5780 α=85.006° β=78.845° γ=83.0191

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Triethylammonium (μ2-oxalato)-dichloro-iron(iii)

|Et3NH[FeIII(ox)Cl2]

|orthorhombic

|Fdd2

|a=13.5878 b=37.972 c=10.8210

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bis(Tetra-n-butylammonium) bis(μ2-oxalato)-tetrachloro-di-iron(iii)

|n-Bu4N[FeIII(ox)Cl2]

|monoclinic

|P21/c

|a=8.8836 b=15.1939 c=17.968 β=91.556°

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|[Fe(oxalato)Cl2]3(3,5-dimethylpyrazole)2(3,5- dimethylpyrazolium)2

|monoclinic

|C2/c

|a=19.527 b=11.867 c=19.429 β=115.66° Z=4

|4058.20

|1.684

|green

|{{Cite journal |title=Oxalate-Bridged Binuclear Iron (III) Complexes of 3, 5-Dimethylpyrazole Ligands: Synthesis, Structure, Spectral and Electrochemical Properties |journal=International Journal of Chemical Engineering |volume=31 |issue=2 |pages=1179}}

BETS = Bis(ethylenedithio)tetraselenafulvalene

|κ-BETS2[FeIII(C2O4)Cl2]

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|black; metallic;

|{{Cite journal |last1=Zhang |first1=Bin |last2=Wang |first2=Zheming |last3=Zhang |first3=Yan |last4=Takahashi |first4=Kazuyuki |last5=Okano |first5=Yoshinori |last6=Cui |first6=Hengbo |last7=Kobayashi |first7=Hayao |last8=Inoue |first8=Katsuya |last9=Kurmoo |first9=Mohamedally |last10=Pratt |first10=Francis L. |last11=Zhu |first11=Daoben |date=2006-04-17 |title=Hybrid Organic−Inorganic Conductor with a Magnetic Chain Anion: κ-BETS 2 [Fe III (C 2 O 4 )Cl 2 ] [BETS = Bis(ethylenedithio)tetraselenafulvalene] |url=https://pubs.acs.org/doi/10.1021/ic051870q |journal=Inorganic Chemistry |language=en |volume=45 |issue=8 |pages=3275–3280 |doi=10.1021/ic051870q |pmid=16602784 |issn=0020-1669}}

bis(2-(5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-ylidene)-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-1-ium) bis(μ-oxalato)-tetrachloro-di-iron(iii)

|[BEDT-TTF][Fe(C2O4)Cl2]

|triclinic

|P{{overbar|1}}

|a=8.896 b=11.401 c=11.427 α=112.062° β=103.775° γ=100.328°

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|{{Cite journal |last1=Zhang |first1=B. |last2=Zhang |first2=Y. |last3=Wang |first3=Z. |last4=Yang |first4=D. |last5=Gao |first5=Z. |last6=Wang |first6=D. |last7=Guo |first7=Y. |last8=Zhu |first8=D. |last9=Mori |first9=T. |date=2016 |title=[BEDT-TTF][Fe(C 2 O 4 )Cl 2 ]: an organic–inorganic hybrid semiconductive antiferromagnet |url=http://xlink.rsc.org/?DOI=C6DT01845A |journal=Dalton Transactions |language=en |volume=45 |issue=42 |pages=16561–16565 |doi=10.1039/C6DT01845A |pmid=27344978 |issn=1477-9226}}

BEDT-TTF = Bis(ethylenedithio)tetrathiafulvalene

|(BEDT-TTF)[Fe(C2O4)Cl2](CH2Cl2)

|monoclinic

|P21/c

|a=8.858 b=11.012 c=14.932 β=103.39°

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|{{Cite journal |last1=Zhang |first1=Bin |last2=Zhang |first2=Yan |last3=Gao |first3=Zengqiang |last4=Chang |first4=Guangcai |last5=Su |first5=Shaokui |last6=Wang |first6=Dongwei |last7=Guo |first7=Yanjun |last8=Zhu |first8=Daoben |date=August 2014 |title=Synthesis, Crystal Structure, and Characterization of the Charge-Transfer Salt (BEDT-TTF)[Fe(C 2 O 4 )Cl 2 ](CH 2 Cl 2 ), {BEDT‐TTF = Bis(ethylenedithio)tetrathiafulvalene} |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201402112 |journal=European Journal of Inorganic Chemistry |language=en |volume=2014 |issue=24 |pages=4028–4032 |doi=10.1002/ejic.201402112 |issn=1434-1948}}

tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate

|[Co(en)3]Cl(C2O4)·3H2O

|monoclinic

|C2/c

|a = 19.932 b = 9.3344 c = 19.088 β = 96.846° Z = 8

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|{{Cite journal |last1=Jone Kirubavathy |first1=S. |last2=Velmurugan |first2=R. |last3=Parameswari |first3=K. |last4=Chitra |first4=S. |date=November 2019 |title=Synthesis, characterization, single crystal XRD, in vitro antimicrobial and cytotoxicity study of tris(ethylenediamine)cobalt(III)chloride oxalate trihydrate |journal=Arabian Journal of Chemistry |language=en |volume=12 |issue=7 |pages=1581–1586 |doi=10.1016/j.arabjc.2014.10.013|doi-access=free }}

dpyam=di-2-pyridylamine; (μ2-Oxalato)-bis(di-2-pyridylamine)-dichloro-di-copper(ii)

|Cu2(dpyam)2(μ-C2O4)(Cl)2

|triclinic

|P{{overbar|1}}

|a=7.4122 b=8.6586 c=9.8002 α=87.900° β=72.022° γ=71.845°

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|{{Cite journal |last1=Youngme |first1=Sujittra |last2=Cheansirisomboon |first2=Achareeya |last3=Danvirutai |first3=Chanaiporn |last4=Chaichit |first4=Narongsak |last5=Pakawatchai |first5=Chaveng |last6=van Albada |first6=Gerard A. |last7=Reedijk |first7=Jan |date=September 2006 |title=Two new oxalato-bridged dinuclear copper(II) complexes with di-2-pyridylamine: crystal structures, spectroscopic and magnetic properties |url=https://linkinghub.elsevier.com/retrieve/pii/S1387700306001924 |journal=Inorganic Chemistry Communications |language=en |volume=9 |issue=9 |pages=973–977 |doi=10.1016/j.inoche.2006.05.022}}

L = 3,5-dimethyl-1H-pyrazole

|Cu2(C2O4)(L)2Cl2(MeOH)2

|triclinic

|P{{overbar|1}}

|a=7.244 b=8.039 c=8.848 α=92.16° β=92.73° γ=96.21°

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|{{Cite journal |last1=Bahemmat |first1=Samira |last2=Neumüller |first2=Bernhard |last3=Ghassemzadeh |first3=Mitra |date=August 2015 |title=One-Pot Synthesis of an Oxalato-Bridged Cu II Coordination Polymer Containing an In Situ Produced Pyrazole Moiety: A Precursor for the Preparation of CuO Nanostructures |url=https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/ejic.201500255 |journal=European Journal of Inorganic Chemistry |language=en |volume=2015 |issue=24 |pages=4116–4124 |doi=10.1002/ejic.201500255 |issn=1434-1948}}

bpy=bipyridine

|[Fe(bpy)3]2[NbO(C2O4)3]Cl·11H2O

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|{{Cite journal |last1=Jurić |first1=Marijana |last2=Perić |first2=Berislav |last3=Brničević |first3=Nevenka |last4=Planinić |first4=Pavica |last5=Pajić |first5=Damir |last6=Zadro |first6=Krešo |last7=Giester |first7=Gerald |last8=Kaitner |first8=Branko |date=2008 |title=Supramolecular motifs and solvatomorphism within the compounds [M(bpy) 3 ] 2 [NbO(C 2 O 4 ) 3 ]Cl·nH 2 O (M = Fe 2+ , Co 2+ , Ni 2+ , Cu 2+ and Zn 2+ ; n = 11, 12). Syntheses, structures and magnetic properties |url=http://xlink.rsc.org/?DOI=B707937K |journal=Dalton Trans. |language=en |issue=6 |pages=742–754 |doi=10.1039/B707937K |pmid=18239829 |issn=1477-9226}}

|[Fe(bpy)3]2[NbO(2O4)3]Cl·12H2O

|orthorhombic

|P212121

|a=14.975 b=21.708 c=22.351 Z=4

|7266

|1.530

|dark red

|

|[Co(bpy)3]2[NbO(C2O4)3]Cl·11H2O

|monoclinic

|P21/c

|a=23.548 b=13.631 c=22.812 β=101.04

|7187

|1.536

|orange red

|

|[Co(bpy)3]2[NbO(C2O4)3]Cl·12H2O

|orthorhombic

|P212121

|a=15.103 b=22.075 c=22.386 Z=4

|7463

|1.495

|brown

|

|[Ni(bpy)3]2[NbO(C2O4)3]Cl·11H2O

|monoclinic

|P21/c

|a=23.875 b=13.265 c=23.115 β=101.69 Z=4

|7169

|1.539

|pink

|

|[Ni(bpy)3]2[NbO(C2O4)3]Cl·12H2O

|orthorhombic

|P212121

|15.058 b=22.039 c=22.398 Z=4

|7433

|1.500

|dark pink

|

|[Cu(bpy)3]2[NbO(C2O4)3]Cl·12H2O

|orthorhombic

|P212121

|a=15.035 b=22.267 c=22.538 Z=4

|7545

|1.487

|blue

|

|[Zn(bpy)3]2[NbO(C2O4)3]Cl·11H2O

|monoclinic

|P21/c

|24.070 b=13.332 c=23.168 β=102.19 Z=4

|7267

|1.530

|pink

|

|[Zn(bpy)3]2[NbO(C2O4)3]Cl·12H2O

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|

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|

|

tris(Tetraethylammonium) tetrakis(μ3-sulfido)-(oxalato-O,O')-trichloro-cyano-tri-iron-molybdenum

|(Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)}

|monoclinic

|P21/n

|a=10.331 b=22.580 c=19.083 β=91.97°

|

|

|double cubane structure

|{{Cite journal |last1=Demadis |first1=Konstantinos D. |last2=Chen |first2=Sue-Jane |last3=Coucouvanis |first3=Dimitri |date=November 1994 |title=The synthesis, and properties of Fe/Mo/S clusters with MoFe3S4 cubane subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} |url=https://linkinghub.elsevier.com/retrieve/pii/S0277538700836840 |journal=Polyhedron |language=en |volume=13 |issue=22 |pages=3147–3151 |doi=10.1016/S0277-5387(00)83684-0|hdl=2027.42/31244 |hdl-access=free }}

(μ2-Oxalato)-dichloro-bis(η6-p-cymene)-di-ruthenium

|[Ru2(μ-η4-C2O4)Cl2(η6-p-PriC6H4Me)2]

|monoclinic

|P21/n

|a=7.571 b=8.998 c=16.528 β=95.52° Z=2

|1120.73

|

|yellow

|{{Cite journal |last1=Yan |first1=Hong |last2=Süss-Fink |first2=Georg |last3=Neels |first3=Antonia |last4=Stoeckli-Evans |first4=Helen |date=1997 |title=Mono-, di- and tetra-nuclear p-cymeneruthenium complexes containing oxalato ligands |url=http://xlink.rsc.org/?DOI=a704658h |journal=Journal of the Chemical Society, Dalton Transactions |issue=22 |pages=4345–4350 |doi=10.1039/a704658h}}

chloro-(oxalato)-tris(pyridine)-rhodium

|mer-[Rh(C2O4)Cl(py)3]

|orthorhombic

|P212121

|a=9.9999 b=12.0930 c=14.9368 Z=4

|1806.2

|1.705

|yellow

|{{Cite journal |last1=Vasilchenko |first1=Danila |last2=Tkachev |first2=Sergey |last3=Baidina |first3=Iraida |last4=Korolkov |first4=Ilya |last5=Berdyugin |first5=Semen |last6=Kozlova |first6=Ekaterina |last7=Kozlov |first7=Denis |date=2018 |title=Preparation of a rhodium( iii ) cis -diaquacomplex by protic acid induced oxalate-release from mer -[Rh(C 2 O 4 )Cl(py) 3 ] |url=http://xlink.rsc.org/?DOI=C8NJ04264K |journal=New Journal of Chemistry |language=en |volume=42 |issue=24 |pages=19637–19643 |doi=10.1039/C8NJ04264K |issn=1144-0546}}

CHLOROPENTAAMMINECHROMIUM(III) BIS(OXALATO)PALLADATE

|[Cr(NH3)5Cl][Pd(C2O4)2]

|triclinic

|

|a = 3.225 b = 10.290 c = 11.390 α = 116.5° β = 97.9° γ = 91.2°

|334.5

|

|

|{{Cite journal |last1=Lagunova |first1=V. I. |last2=Filatov |first2=E. Yu. |last3=Plyusnin |first3=P. E. |last4=Komarov |first4=V. Yu. |last5=Martynova |first5=S. A. |last6=Korenev |first6=S. V. |date=April 2021 |title=Synthesis and Thermal Properties of Double Complex Salt: Chloropentaamminechromium(III) Bis(Oxalato)Palladate |url=https://link.springer.com/10.1134/S0022476621040065 |journal=Journal of Structural Chemistry |language=en |volume=62 |issue=4 |pages=555–562 |doi=10.1134/S0022476621040065 |s2cid=235374161 |issn=0022-4766}}

|C(NH2)3Cd(C2O4)Cl(H2O)·H2O

|triclinic

|P{{overbar|1}}

|a=6.8136 b=7.4890 c=10.0515 α=84.082° β=77.806° γ=88.813°

|

|

|band gap 3.76 eV

|{{Cite journal |last1=Xu |first1=Wei |last2=Ma |first2=Liang |last3=Lv |first3=Yi-Lei |last4=Ma |first4=Si-Yu |last5=Liu |first5=Wenlong |last6=Guo |first6=Sheng-Ping |last7=Tang |first7=Ru-Ling |date=2023-12-19 |title=C(NH 2 ) 3 Cd(C 2 O 4 )Cl(H 2 O)·H 2 O and BaCd(C 2 O 4 ) 1.5 Cl(H 2 O) 2 : Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.3c04154 |journal=Inorganic Chemistry |volume=63 |issue=1 |pages=67–72 |language=en |doi=10.1021/acs.inorgchem.3c04154 |pmid=38112437 |s2cid=266373131 |issn=0020-1669}}

|SnC2O4Cl2

|

|

|

|

|

|

|{{Cite journal |last1=Allouch |first1=Hassan |last2=Diop |first2=Libasse |date=2012 |title=SYNTHESIS AND INFRARED STUDY OF SOME NEW SnC^sub 2^O^sub 4^Cl^sub 2^ ADDUCTS AND COMPLEXES |url=https://www.proquest.com/docview/1499908259 |journal=Scientific Study & Research. Chemistry & Chemical Engineering, Biotechnology, Food Industry |language=English |volume=13 |issue=3 |pages=317–323|id={{ProQuest|1499908259}} }}

|SnC2O4Cl2 . CuBr2 1/4EtOH

|

|

|

|

|

|green

|

|SnC2O4Cl2 . CuCl2 . H2O

|

|

|

|

|

|green

|

|SnC2O4Cl2 . CoBr2 1/8EtOH

|

|

|

|

|

|rose colour

|

|(Et4N)2C2O4 . SnCl2F2 . 2H2O:

|

|

|

|

|

|white

|

|(Me4N)2Sn(C2O4)Cl2

|

|

|

|

|

|white

|

|(Et4N)2Sn(C2O4)Cl2 .(Et4N)2C2O4(SnCl4)2 . EtOH

|

|

|

|

|

|white

|

|Sn(C2O4)2 . 2[SnCl4 . (Pyridine)2]

|

|

|

|

|

|white

|

|(Et4N)2SnCl6 . (Et4N)2C2O4 . 2SnC2O4(OH)2

|

|

|

|

|

|white

|

|(NH4)2Sb(C2O4)Cl3

|orthorhombic

|P212121

|a=8.6961 b=8.7844 c=13.5956 Z=4

|1038.57

|2.253

|

|{{Cite journal |last1=Zhang |first1=Die |last2=Wang |first2=Qiang |last3=Luo |first3=Han |last4=Cao |first4=Liling |last5=Dong |first5=Xuehua |last6=Huang |first6=Ling |last7=Gao |first7=Daojiang |last8=Zou |first8=Guohong |date=March 2023 |title=Deep Eutectic Solvents Synthesis of A 2 Sb(C 2 O 4 )Cl 3 (A = NH 4 , K, Rb) with Superior Optical Performance |url=https://onlinelibrary.wiley.com/doi/10.1002/adom.202202874 |journal=Advanced Optical Materials |language=en |volume=11 |issue=6 |doi=10.1002/adom.202202874 |s2cid=256156085 |issn=2195-1071}}

|K2Sb(C2O4)Cl3

|orthorhombic

|P212121

|a=8.3966 b=8.6023 c=13,6342 Z=4

|984.80

|2.660

|

|

|Rb2Sb(C2O4)Cl3

|orthorhombic

|P212121

|a=8.6769 b=8.8485 c=13.8014 Z=4

|1059.64

|3.053

|birefringence 0.22@546 nm;NLO 2.1 × KH2PO4

|

|Ba2Mn2Cl2(C2O4)3·4H2O

|monoclinic

|C2/c

|a=22.916 b=8.248 c=9.904 β=99.53°

|

|

|

|{{Cite journal |last1=Price |first1=Daniel J. |last2=Powell |first2=Annie K. |last3=Wood |first3=Paul T. |date=2003 |title=A new series of layered transition metal oxalates: hydrothermal synthesis, structural and magnetic studies |url=http://xlink.rsc.org/?DOI=b301658g |journal=Dalton Transactions |language=en |issue=12 |pages=2478–2482 |doi=10.1039/b301658g |issn=1477-9226}}

|Ba2Fe2Cl2(C2O4)3·4H2O

|monoclinic

|C2/c

|a=22.798 b=8.297 c=9.849 β=99.90°

|

|

|

|

|Ba2Co2Cl2(C2O4)3·4H2O

|monoclinic

|C2/c

|a=22.675 b=8.230 c=9.757 β=100.00°

|

|

|purple

|{{Cite journal |last1=Song |first1=Yujie |last2=Niu |first2=Haoyu |last3=Zeng |first3=Zhuo |last4=Jiang |first4=Dequan |last5=Liang |first5=Youyuan |last6=Huang |first6=Hao |last7=Xiao |first7=Lixia |last8=Xia |first8=Zhengcai |date=September 2022 |title=The tuning of oxalato-bridge on magnetic interaction and field-induced phase transition in Ba2Co2Cl2(C2O4)3·4H2O |url=https://linkinghub.elsevier.com/retrieve/pii/S0304885322004048 |journal=Journal of Magnetism and Magnetic Materials |language=en |volume=557 |pages=169475 |doi=10.1016/j.jmmm.2022.169475|s2cid=248877927 }}

|BaCd(C2O4)1.5Cl(H2O)2

|monoclinic

|C2/c

|a=23.101 b=8.253 c=10.040 β 99.14°

|

|

|band gap 4.53 eV

|

|La(C2O4)Cl

|monoclinic

|P21/n

|a=8.489 b=16.19 c=5.880 β=104.14°

|

|

|

|{{Cite journal |last1=Hölsä |first1=Jorma |last2=Koriseva |first2=Eija |date=August 1991 |title=Thermal decomposition of LaC2O4Cl·3H2O : Eu3+: a high-resolution luminescence spectroscopy study |url=https://linkinghub.elsevier.com/retrieve/pii/004060319180114X |journal=Thermochimica Acta |language=en |volume=185 |issue=1 |pages=25–33 |doi=10.1016/0040-6031(91)80114-X}}{{Cite journal |last1=Baker |first1=P. |last2=Smith |first2=A. J. |date=1990-06-15 |title=Structure of lanthanum chloride oxalate trihydrate |url=https://scripts.iucr.org/cgi-bin/paper?S0108270189009248 |journal=Acta Crystallographica Section C Crystal Structure Communications |volume=46 |issue=6 |pages=984–985 |doi=10.1107/S0108270189009248|bibcode=1990AcCrC..46..984B |s2cid=98752634 }}

|La(C2O4)Cl·3H2O

|

|

|

|

|

|

|{{Cite journal |last1=Möbius |first1=R. |last2=Matthes |first2=F. |date=June 1964 |title=Über die Verhältnisse beim Austausch von Oxalationen gegen Chloridionen bei Oxalathydraten der Seltenen Erden und des Yttriums |url=https://onlinelibrary.wiley.com/doi/10.1002/zfch.19640040618 |journal=Zeitschrift für Chemie |language=en |volume=4 |issue=6 |pages=234–235 |doi=10.1002/zfch.19640040618 |issn=0044-2402}}

|Ce(C2O4)Cl

|

|

|

|

|

|

|{{Cite journal |last1=Mulokozi |first1=A.M. |last2=Weigel |first2=F. |date=May 1973 |title=Differential thermal analysis studies of some rare earth metal oxalato halide-hydrates |url=https://linkinghub.elsevier.com/retrieve/pii/0022190273802362 |journal=Journal of Inorganic and Nuclear Chemistry |language=en |volume=35 |issue=5 |pages=1487–1492 |doi=10.1016/0022-1902(73)80236-2}}

|Ce(C2O4)Cl·3H2O

|

|

|

|

|

|

|

|Pr(C2O4)Cl·3H2O

|

|

|

|

|

|stable to 163°C

|

|Nd(C2O4)Cl·3H2O

|

|

|

|

|

|stable to 167°C; dec 510° to NdOCl

|{{Cite journal |last1=Mulokozi |first1=A. M. |last2=Zuru |first2=A. A. |date=November 1989 |title=Activation energy of thermal decomposition of fully dehydrated NdC2O4Cl·3H2O to NdOCl |url=http://link.springer.com/10.1007/BF01911900 |journal=Journal of Thermal Analysis |language=en |volume=35 |issue=7 |pages=2359–2366 |doi=10.1007/BF01911900 |s2cid=95014944 |issn=0368-4466}}

|Sm(C2O4)Cl·3H2O

|

|

|

|

|

|stable to 174°C; dec at 347° to EuC2O4

|

|Eu(C2O4)Cl·3H2O

|

|

|

|

|

|stable to 178°C

|

|Gd(C2O4)Cl·3H2O

|

|

|

|

|

|

|{{Cite journal |last1=Mulokozi |first1=A. M. |last2=Weigel |first2=F. |date=April 1975 |title=Characeriztion of Rare-Earth Metal Oxalato Halide-Hydrates by thermal analytical methods |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.19754140108 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=en |volume=414 |issue=1 |pages=62–68 |doi=10.1002/zaac.19754140108 |issn=0044-2313}}

|(Et4N)2Sn(C2O4)Cl2 . (Et4N)2C2O4(SnCl4)2 . EtOH

|

|

|

|

|

|

|

|[(Me4N)2C2O4SnCl4]2 . [(Me4N)2Sn(C2O4)2Cl2]2 . Sn(WO4)2

|

|

|

|

|

|

|

|[Pt(HC2O4)Cl3]2−

|

|

|

|

|

|

|{{Cite journal |last1=Dunham |first1=S. O. |last2=Larsen |first2=R. D. |last3=Abbott |first3=E. H. |date=November 1991 |title=Nuclear magnetic resonance investigation of the formation of oxalato, malonato, and 2-methylmalonato complexes of platinum(II). Crystal and molecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate |url=https://pubs.acs.org/doi/abs/10.1021/ic00023a009 |journal=Inorganic Chemistry |language=en |volume=30 |issue=23 |pages=4328–4335 |doi=10.1021/ic00023a009 |issn=0020-1669}}

|[Pt(HC2O4)(C2O4)Cl]2−

|

|

|

|

|

|

|

|K2[Pt(C2O4)Cl2]·H2O

|triclinic

|P{{overbar|1}}

|a=7.136 b=7.308 c=10.130 α=86.75° β=74.58° γ=54.28° Z=2

|457.7

|3.27

|

|{{Cite web |title=K2[Pt(C2O4)Cl2]·H2O (K2Pt[C2O4]Cl2[H2O]) Crystal Structure - SpringerMaterials |url=https://materials.springer.com/isp/crystallographic/docs/sd_1904131 |access-date=2024-02-08 |website=materials.springer.com}}

|[Pt(NH3)5Cl][Cr(C2O4)3] · 4H2O

|orthorhombic

|Pccn

|a=38.901 b=13.7267 c=14.9141

|

|

|

|{{Cite journal |last1=Yusenko |first1=K. V. |last2=Vasil’chenko |first2=D. B. |last3=Zadesenets |first3=A. V. |last4=Baidina |first4=I. A. |last5=Shubin |first5=Yu. V. |last6=Korenev |first6=S. V. |date=October 2007 |title=Double complex salts [Pt(NH3)5Cl][M(C2O4)3] · nH2O (M = Fe, Co, Cr): Synthesis and study |url=http://link.springer.com/10.1134/S0036023607100014 |journal=Russian Journal of Inorganic Chemistry |language=en |volume=52 |issue=10 |pages=1487–1491 |doi=10.1134/S0036023607100014 |s2cid=96549903 |issn=0036-0236}}

|[Pt(NH3)5Cl][Fe(C2O4)3] · 4H2O

|orthorhombic

|Pccn

|a=39.0123 b=13.7232 c=14.8990

|

|

|

|

|[Pt(NH3)5Cl][Co(C2O4)3] · 2H2O

|monoclinic

|P21

|a=8.5158 b=12.6409 c=8.5726 β=105.000°

|

|

|

|

lead chloride oxalate

|Pb2Cl2(C2O4)

|monoclinic

|C2/m

|a=5.9411 b=5.8714 c=9.4212 β=95.232° Z=2

|327.26

|5.82

|dec 350°C to Pb, Pb5O2Cl6 and Pb3O2Cl2

|{{Cite journal |last1=Boudaren |first1=Chaouki |last2=Auffrédic |first2=Jean-Paul |last3=Louër |first3=Michèle |last4=Louër |first4=Daniel |date=September 2003 |title=A powder X-ray diffraction study of lead chloride oxalate Pb 2 Cl 2 (C 2 O 4 ): ab initio structure determination and thermal behavior |url=https://www.cambridge.org/core/product/identifier/S0885715600006898/type/journal_article |journal=Powder Diffraction |language=en |volume=18 |issue=3 |pages=205–213 |doi=10.1154/1.1590352 |s2cid=98700786 |issn=0885-7156}}

|Th4Cl4(C2O4)6•20H2O

|

|

|

|

|

|

|

Plutonium(III) oxalato chloride

|?Pu(C2O4)Cl·3H2O

|

|

|

|

|

|blue; biaxial (−)

|{{Cite book |last=Staritzky |first=Eugene |url=http://www.sciencemadness.org/lanl2_a/lib-www/la-pubs/00349867.pdf |title=Optical and Morphological Crystallography of Plutonium Compounds |date=28 August 1949 |publisher=US Atomic Energy Commission |pages=34}}

|Am(C2O4)Cl·3H2O

|monoclinic

|P21/n

|a=5.852 b=15.823 c=8.351 β=104.243°

|

|

|

|{{Cite journal |last1=Arteaga |first1=Ana |last2=Nicholas |first2=Aaron D. |last3=Ducati |first3=Lucas C. |last4=Autschbach |first4=Jochen |last5=Surbella |first5=Robert G. |date=2023-03-27 |title=Americium Oxalate: An Experimental and Computational Investigation of Metal–Ligand Bonding |url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c03976 |journal=Inorganic Chemistry |language=en |volume=62 |issue=12 |pages=4814–4822 |doi=10.1021/acs.inorgchem.2c03976 |pmid=36920249 |osti=1968457 |s2cid=257534787 |issn=0020-1669}}

References

{{Reflist}}

{{Chlorides}}

{{Oxalates}}

Category:Oxalates

Category:Chlorides

Category:Mixed anion compounds