Palladium(II) nitrate
{{chembox
| Verifiedfields = changed
| verifiedrevid = 433052015
| Name = Palladium(II) nitrate
| ImageFile1 = Palladium nitrate.png
| ImageFile2 = Pd(NO3)2(ICD425998).png
| ImageName = Palladium(II) nitrate
| IUPACName = Palladium(II) nitrate
| OtherNames = Palladium nitrate
Palladous nitrate
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23306
| PubChem = 24932
| InChI = 1/2NO3.Pd/c2*2-1(3)4;/q2*-1;+2
| InChIKey = GPNDARIEYHPYAY-UHFFFAOYAP
| SMILES = [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2NO3.Pd/c2*2-1(3)4;/q2*-1;+2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = GPNDARIEYHPYAY-UHFFFAOYSA-N
| CASNo = 10102-05-3
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = 5G27LBZ05U
| RTECS =
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|Section2={{Chembox Properties
| Formula = Pd(NO3)2
| MolarMass = 230.43 g/mol
| Appearance = yellow solid
| Solubility = Soluble
| MeltingPt = Decomposes >100 °C
}}
|Section3={{Chembox Structure
| Coordination =
| CrystalStruct =
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|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards = Irritant, possibility of allergic reaction
| FlashPt = Non-flammable
| HPhrases = {{HPhrases|}}
| PPhrases = {{PPhrases|}}
| GHS_ref =
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|Section8={{Chembox Related
| OtherAnions = Palladium(II) chloride
| OtherCations = Nickel(II) nitrate
| OtherCompounds = Silver nitrate
}}
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Palladium(II) nitrate is the inorganic compound with the formula Pd(NO3)2.(H2O)x where x = 0 or 2. The anhydrous and dihydrate are deliquescent solids. According to X-ray crystallography, both compounds feature square planar Pd(II) with unidentate nitrate ligands. The anhydrous compound, which is a coordination polymer, is yellow.{{cite journal |doi=10.1002/chem.201405355|title=Oxoanionic Noble Metal Compounds from Fuming Nitric Acid: The Palladium Examples Pd(NO3)2 and Pd(CH3SO3)2|year=2015|last1=Bruns|first1=Jörn|last2=Klüner|first2=Thorsten|last3=Wickleder|first3=Mathias S.|journal=Chemistry - A European Journal|volume=21|issue=3|pages=1294–1301|pmid=25431333}}{{cite journal |doi=10.1016/0025-5408(91)90021-D|title=Crystal Structure of Pd(NO3)2(H2O)2|year=1991|last1=Laligant|first1=Y.|last2=Ferey|first2=G.|last3=Le Bail|first3=A.|journal=Materials Research Bulletin|volume=26|issue=4|pages=269–275}}
As a solution in nitric acid, Pd(NO3)2 catalyzes the conversion of alkenes to dinitrate esters. Its pyrolysis affords palladium oxide.Timothy T. Wenzel "Palladium(II) Nitrate" Encyclopedia of Reagents for Organic Synthesis 2001, John Wiley & Sons. {{doi| 10.1002/047084289X.rp013}}
Preparation
Hydrated palladium nitrate may be prepared by dissolving palladium oxide hydrate in dilute nitric acid followed by crystallization. The nitrate crystallizes as yellow-brown deliquescent prisms. The anhydrous material is obtained by treating palladium metal with fuming nitric acid.
References
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{{Palladium compounds}}
{{nitrates}}
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