Palladium(II) perchlorate
{{Chembox
| Reference =
| Name =
| IUPACName =
| PIN =
| SystematicName = Palladium(II) diperchlorate
| OtherNames = {{Unbulleted list
| Palladium diperchlorate
}}
| data page pagename =
| ImageFile = Pd(ClO4)2.svg
| ImageSize =
| ImageAlt =
| ImageName =
| ImageCaption =
| ImageFile1 =
| ImageSize1 =
| ImageAlt1 =
| ImageName1 =
| ImageCaption1 =
| ImageFileL1 =
| ImageSizeL1 =
| ImageAltL1 =
| ImageNameL1 =
| ImageFileR1 =
| ImageSizeR1 =
| ImageAltR1 =
| ImageNameR1 =
| Section1 = {{Chembox Identifiers
| 3DMet =
| Abbreviations =
| Beilstein =
| CASNo =
| CASNo_Comment =
| CASNoOther =
| ChEBI =
| ChemSpiderID =
| EINECS =
| EC_number =
| EC_number_Comment=
| Gmelin =
| InChI = 1S/2ClHO4.Pd/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2
| KEGG =
| MeSHName =
| PubChem = 20221938
| RTECS =
| SMILES = [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Pd+2]
| UNNumber =
}}
| Section2 = {{Chembox Properties
| AtmosphericOHRateConstant =
| Appearance = Light-brown solid
| BoilingPt =
| BoilingPtC =
| BoilingPt_ref =
| BoilingPt_notes=
| Density =
| Formula = Pd(ClO4)2
| HenryConstant =
| LogP =
| MolarMass = 305.32 g/mol
| MeltingPt =
| MeltingPtC =
| MeltingPt_ref =
| MeltingPt_notes=
| pKa =
| pKb =
| Solubility = Soluble
| SolubleOther =
| Solvent =
| VaporPressure =
}}
| Section3 = {{Chembox Structure
| Coordination =
| CrystalStruct =
| MolShape =
}}
| Section4 = {{Chembox Thermochemistry
| DeltaGf =
| DeltaHc =
| DeltaHf =
| Entropy =
| HeatCapacity =
}}
| Section5 = {{Chembox Explosive
| ShockSens =
| FrictionSens =
| DetonationV =
| REFactor =
}}
| Section7 = {{Chembox Hazards
| AutoignitionPt =
| ExploLimits =
| FlashPt =
| LD50 =
| LC50 =
| MainHazards =
| NFPA-H =
| NFPA-F =
| NFPA-I =
| NFPA-S =
| PEL =
| REL =
| ExternalSDS =
| GHSPictograms =
| GHSSignalWord =
| HPhrases =
| PPhrases =
}}
| Section9 = {{Chembox Related
| OtherAnions =
| OtherCations =
| OtherFunction =
| OtherFunction_label =
| OtherCompounds =
}}
}}
Palladium(II) perchlorate is an inorganic chemical compound with the formula Pd(ClO4)2. It is a light-brown solid produced by the reaction of dichlorine hexoxide and palladium(II) chloride followed by heating at 60 °C in a vacuum:
:3 PdCl2 + 4 Cl2O6 → 3 Pd(ClO4)2 + 4 Cl2
Aqueous solutions of palladium(II) perchlorate can be produced by the addition of perchloric acid to a solution of palladium(II) nitrate.{{cite journal |author1=A. K. Sundaram |author2=E. B. Sandell |title=Chloro Complexes of Palladium(II) in Solution |journal=Journal of the American Chemical Society |date=1955 |volume=77 |issue=4 |pages=855–857 |doi=10.1021/ja01609a008 |language=en}}
Structure
Solid anhydrous palladium(II) perchlorate consists of a pair of bidentate perchlorate ligands attached to the central palladium atom.{{cite journal |author1=Frédérique Cunin |author2=Frédéric Favier |author3=Jean Louis Pascal |title=Anhydrous perchlorato complexes of palladium(II): Pd(ClO4)2, (ClO2)2Pd(ClO4)4, and (NO2)2Pd(ClO4)4. Syntheses and structural analyses |journal=Canadian Journal of Chemistry |date=2000 |volume=78 |issue=12 |pages=1544–1522 |doi=10.1139/v00-149 |language=en}}
References
{{reflist}}
{{Palladium compounds}}
{{Perchlorates}}