Palladium(II) perchlorate

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| SystematicName = Palladium(II) diperchlorate

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| Palladium diperchlorate

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| InChI = 1S/2ClHO4.Pd/c2*2-1(3,4)5;/h2*(H,2,3,4,5);/q;;+2/p-2

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| PubChem = 20221938

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| SMILES = [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Pd+2]

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| Appearance = Light-brown solid

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| Formula = Pd(ClO4)2

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| MolarMass = 305.32 g/mol

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| Solubility = Soluble

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Palladium(II) perchlorate is an inorganic chemical compound with the formula Pd(ClO4)2. It is a light-brown solid produced by the reaction of dichlorine hexoxide and palladium(II) chloride followed by heating at 60 °C in a vacuum:

:3 PdCl2 + 4 Cl2O6 → 3 Pd(ClO4)2 + 4 Cl2

Aqueous solutions of palladium(II) perchlorate can be produced by the addition of perchloric acid to a solution of palladium(II) nitrate.{{cite journal |author1=A. K. Sundaram |author2=E. B. Sandell |title=Chloro Complexes of Palladium(II) in Solution |journal=Journal of the American Chemical Society |date=1955 |volume=77 |issue=4 |pages=855–857 |doi=10.1021/ja01609a008 |language=en}}

Structure

Solid anhydrous palladium(II) perchlorate consists of a pair of bidentate perchlorate ligands attached to the central palladium atom.{{cite journal |author1=Frédérique Cunin |author2=Frédéric Favier |author3=Jean Louis Pascal |title=Anhydrous perchlorato complexes of palladium(II): Pd(ClO4)2, (ClO2)2Pd(ClO4)4, and (NO2)2Pd(ClO4)4. Syntheses and structural analyses |journal=Canadian Journal of Chemistry |date=2000 |volume=78 |issue=12 |pages=1544–1522 |doi=10.1139/v00-149 |language=en}}

References

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{{Palladium compounds}}

{{Perchlorates}}

Category:Palladium compounds

Category:Perchlorates