Perbromyl fluoride
{{Chembox
| Name = Perbromyl fluoride
| ImageFile1 = Perbromyl fluoride.png
| PIN =
| OtherNames = Bromine fluoride trioxide
|Section1={{Chembox Identifiers
| CASNo = 25251-03-0
| CASNo_Ref = {{cascite|correct|CAS}}
| ChemSpiderID =
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| PubChem = 44233513
| StdInChI= 1S/BrFO3/c2-1(3,4)5
| StdInChIKey = FHRGMUIQMATFDZ-UHFFFAOYSA-N
| SMILES = F[Br](=O)(=O)=O
}}
|Section2={{Chembox Properties
| Formula = {{chem2|BrO3F}}
| F=1 | O=3 | Br=1
| Appearance = colorless gas
| Density =
| MeltingPtC = -110
| MeltingPt_notes = (approx. temperature of solidification)
| BoilingPtC =
| Solubility = reacts with water}}
|Section3={{Chembox Hazards
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|Section6={{Chembox Related
| OtherCompounds = Periodyl fluoride
Perchloryl fluoride
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Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula {{chem2|BrO3F|auto=1}}.{{cite journal |last1=Appleman |first1=Evan H. |last2=Studier |first2=Martin H. |title=Perbromyl fluoride |journal=Journal of the American Chemical Society |date=July 1969 |volume=91 |issue=16 |pages=4561–4562 |doi=10.1021/ja01044a049 |bibcode=1969JAChS..91.4561A |language=en |issn=0002-7863}}
Synthesis
Synthesis of perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid:{{cite book |last1=Steudel |first1=Ralf |title=Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding |date=20 April 2011 |publisher=Walter de Gruyter |isbn=978-3-11-083082-8 |page=265 |url=https://books.google.com/books?id=Z7_-lFZbxi0C&dq=perBromyl+fluoride&pg=PA265 |access-date=5 June 2023 |language=en}}
:{{chem2|KBrO4 + 2 SbF5 + 3 HF -> BrO3F + K[SbF6] + H[SbF6]*H2O}}
Physical properties
Perbromyl fluoride is a colorless gas at room temperature that is stable in the absence of moisture.{{cite book |title=U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management |date=1970 |publisher=U.S. Government Printing Office |page=10 |url=https://books.google.com/books?id=mYvvAAAAMAAJ&dq=perBromyl+fluoride&pg=RA1-PA10 |access-date=5 June 2023 |language=en}}
Chemical properties
Perbromyl fluoride reacts with water to produce perbromic acid and hydrogen fluoride:
:{{chem2|BrO3F + H2O -> HBrO4 + HF}}
References
{{Reflist}}
{{Bromine compounds}}
{{Oxygen compounds}}
{{Fluorine compounds}}
{{Authority control}}