Phosphinous acids
Phosphinous acids are usually organophosphorus compounds with the formula R2POH. They are pyramidal in structure. Phosphorus is in the oxidation state III. Most phosphinous acids rapidly convert to the corresponding phosphine oxide, which is tetrahedral and is assigned oxidation state V.
Synthesis
Only one example is known, bis(trifluoromethyl)phosphinous acid, (CF3)2POH.{{cite journal|doi=10.1021/ja01491a062|title=The Phosphinous Acid (CF3)2POH and the Diphosphoxane (CF3)2POP(CF3)2|journal=Journal of the American Chemical Society|volume=82|pages=1507–1508|year=1960|last1=Griffiths|first1=James E.|last2=Burg|first2=Anton B.|issue=6}} It is prepared in several steps from phosphorus trichloride (Et = ethyl):
:PCl3 + 2 Et2NH → PCl2NEt2 + Et2NH2Cl
:2 P(NEt2)3 + PCl2NEt2 + 2 CF3Br → P(CF3)2NEt2 + 2 BrClP(NEt2)3
:P(CF3)2NEt2 + H2O → P(CF3)2OH + HNEt2
Reactions
With the lone exception of the bis(trifluoromethyl) derivative, the dominant reaction of phosphinous acids is tautomerization:
:PR2OH → OPR2H
Even the pentafluorophenyl compound P(C6F5)2OH is unstable with respect to the phosphine oxide.{{cite journal|doi=10.1016/j.jorganchem.2004.09.041|title=Stable Phosphinous Acids|journal=Journal of Organometallic Chemistry|volume=690|issue=10|pages=2382–2387|year=2005|last1=Hoge|first1=Berthold|last2=Neufeind|first2=Stefan|last3=Hettel|first3=Sonja|last4=Wiebe|first4=Waldemar|last5=Thösen|first5=Christoph}}
Although phosphinous acids are rare, their P-bonded coordination complexes are well established, e.g. Mo(CO)5P(OH)3.
Secondary and primary phosphine oxides
Tertiary phosphine oxides, compounds with the formula R3PO cannot tautomerize. The situation is different for the secondary and primary phosphine oxides, with the respective formulas R2(H)PO and R(H)2PO.{{cite journal|doi=10.1016/S0040-4039(00)88307-0|title=Preparation and characterization of sterically protected primary phosphine sulfide and oxide|journal=Tetrahedron Letters|volume=24|issue=39|pages=4227–4228|year=1983|last1=Yoshifuji|first1=Masaaki|last2=Shibayama|first2=Katsuhiro|last3=Toyota|first3=Kozo|last4=Inamoto|first4=Naoki}}
File:(EtO)2POH.png|diethylphosphite
File:Phosphonic-acid-2D-dimensions-vector.svg|phosphorous acid
File:Diphenylphosphine oxide.png|Diphenylphosphine oxide
File:Hypophosphorous-acid-2D.png|Hypophosphorous acid