Platinum(II) bromide

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| Watchedfields = changed

| verifiedrevid = 446954753

| Name = Platinum(II) bromide

| ImageFile =

| ImageName =

| IUPACName = Platinum(II) bromide

| OtherNames = Platinous bromide
Platinum dibromide

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 13455-12-4

| ChemSpiderID = 75324

| RTECS =

| PubChem = 83486

| EINECS = 236-64-8

| UNII = 89VK2P9DEN

| SMILES = Br[Pt]Br

| StdInChI = 1S/2BrH.Pt/h2*1H;/q;;+2/p-2

| StdInChIKey = KGRJUMGAEQQVFK-UHFFFAOYSA-L

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|Section2={{Chembox Properties

| Formula = Br2Pt

| MolarMass = 354.886 g/mol

| Appearance = Dark green powder

| Density = 6.65 g/cm3, solid

| Solubility = insol.

| MeltingPtC = 250

| MeltingPt_notes = (decomposes)

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|Section3={{Chembox Structure

| Coordination = square planar

| CrystalStruct =

| Dipole = 0 D

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|Section7={{Chembox Hazards

| ExternalSDS =

| MainHazards = skin irritant

| FlashPt =

| Hazards_ref={{cite web |title=Platinum(II) bromide |url=https://pubchem.ncbi.nlm.nih.gov/compound/83486#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |language=en}}

| GHSPictograms = {{GHS07}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|315|319|335}}

| PPhrases = {{P-phrases|261|264|271|280|302+352|304+340|305+351+338|312|321|332+313|337+313|362|403+233|405|501}}

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|Section8={{Chembox Related

| OtherAnions = Platinum(II) chloride

| OtherCompounds = Platinum(IV) bromide

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Platinum bromide is the chemical compound with the formula PtBr2. This dark green powder is a common precursor to other platinum-bromide compounds. Like palladium chloride and palladium(II) bromide, it is a compound that dissolves only in coordinating solvents or in the presence of donor ligands.

Illustrative use

Transition metal carbene complexes of platinum can be prepared by heating platinum bromide with the imidazolium salt NHC precursors and sodium acetate in dimethyl sulfoxide.{{cite journal |author1=Muehlhofer M. |author2=Strassner T. |author3=Herdtweck E. |author4=Herrmann W.A. | title = Synthesis and structural characterization of novel bridged platinum(II) biscarbene complexes | journal = Journal of Organometallic Chemistry | volume = 660 | year = 2002 | issue = 2 | pages = 121–126 | doi = 10.1016/S0022-328X(02)01670-4}}

References

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{{Platinum compounds}}

{{bromine compounds}}

Bromides,2

Category:Bromides

Category:Platinum group halides

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