Potassium peroxide

{{Chembox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 443287436

| Name = Potassium peroxide

| ImageFile = K2O2-structure.jpg

| ImageSize =

| ImageName =

| IUPACName = Potassium peroxide

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 17014-71-0

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = ZHB4ZOE9PU

| RTECS =

| PubChem = 28202

| EINECS = 241-089-8

| SMILES = [O-][O-].[K+].[K+]

| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}

| ChemSpiderID = 26237

| InChI = 1/2K.O2/c;;1-2/q2*+1;-2

| InChIKey = XXQBEVHPUKOQEO-UHFFFAOYAV

| StdInChI_Ref = {{stdinchicite|changed|chemspider}}

| StdInChI = 1S/2K.O2/c;;1-2/q2*+1;-2

| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}

| StdInChIKey = XXQBEVHPUKOQEO-UHFFFAOYSA-N

}}

|Section2={{Chembox Properties

| Formula = K2O2

| MolarMass = 110.196 g/mol

| Appearance = yellow amorphous solid

| Density =

| Solubility = reacts with water

{{cite book | last = Lide | first = David R. | year = 1998

| title = Handbook of Chemistry and Physics

| edition = 87 | location = Boca Raton, Florida | publisher = CRC Press

| isbn = 0-8493-0594-2 | pages = 477; 520}}

| MeltingPtC = 490

| BoilingPt =

}}

|Section3={{Chembox Structure

| CrystalStruct = Orthorhombic

| SpaceGroup = Cmca, oS16

| Coordination =

}}

|Section4={{Chembox Thermochemistry

| DeltaHf = −496 kJ·mol−1{{cite book| author = Zumdahl, Steven S.|title =Chemical Principles 6th Ed.| publisher = Houghton Mifflin Company| year = 2009| isbn = 978-0-618-94690-7|page=A22}}

| Entropy = 113 J·mol−1·K−1

}}

|Section7={{Chembox Hazards

| GHSPictograms = {{GHS03}} {{GHS07}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|272|315|319}}

| PPhrases = {{P-phrases|210| 220| 221| 264| 280| 302+352| 305+351+338| 321| 332+313| 337+313| 362| 370+378| 501}}

| GHS_ref =

| NFPA-H = 3

| NFPA-F = 0

| NFPA-R = 2

| NFPA-S = W+OX

| FlashPt =

}}

|Section8={{Chembox Related

| OtherAnions = Potassium chloride

| OtherCations = Lithium peroxide
Sodium peroxide
Rubidium peroxide
Caesium peroxide

| OtherFunction = Potassium oxide
Potassium superoxide
Potassium ozonide

| OtherFunction_label = potassium oxides

}}

}}

Potassium peroxide is an inorganic compound with the molecular formula K2O2. It is formed as potassium reacts with oxygen in the air, along with potassium oxide (K2O) and potassium superoxide (KO2).

File:Kristallstruktur Kaliumperoxid.png

Potassium peroxide reacts with water to form potassium hydroxide and oxygen:

:{{chem2 | 2 K2O2 + 2 H2O -> 4 KOH + O2 ↑}}

Properties

Potassium peroxide is a highly reactive, oxidizing white to yellowish solid which, while not flammable itself, reacts violently with flammable materials. It decomposes violently on contact with water.

The standard enthalpy of formation of potassium peroxide is ΔH f 0 = −496 kJ/mol.

==Usage==

Potassium peroxide is used as an oxidizing agent and bleach (due to the peroxide), and to purify air.

References

{{reflist}}

{{Potassium compounds}}

{{oxygen compounds}}

{{DEFAULTSORT:Potassium Peroxide}}

Category:Peroxides

Category:Potassium compounds

Category:Oxidizing agents