Propanethiol
{{chembox
| Reference=[https://www.cdc.gov/niosh/ipcsneng/neng1492.html International Chemical Safety Card 0317]
| ImageFile = 1-Propanethiol.svg
| Name = Propanethiol
| PIN = Propane-1-thiol
| OtherNames = n-Propylthiol
1-Propanethiol
Propan-1-thiol
Propyl mercaptan
Mercaptan C3
|Section1={{Chembox Identifiers
| CASNo = 107-03-9
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 4AB0N08V2H
| ChEBI = 8473
| ChEBI_Ref = [http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:8473 ChEBI 8473]
| SMILES = CCCS
| ChemSpiderID = 7560
| ChemSpiderID_Ref = [http://www.chemspider.com/Chemical-Structure.7560.html CSID:7560], accessed 19:05, Feb 10, 2013
| PubChem = 7848
}}
|Section2={{Chembox Properties
| C=3 | H=8 | S=1
| Appearance = Colorless to pale yellow liquid
| Density = 0.84 g/mL
| pKa = ~10.5{{citation needed|date=November 2014}}
| MeltingPtC = -113
| BoilingPtC = 67 to 68
| MagSus = −58.5·10−6 cm3/mol
}}
|Section3={{Chembox Hazards
| IDLH = N.D.{{PGCH|0526}}
| REL = C 0.5 ppm (1.6 mg/m3) [15-minute]
| FlashPtF= -5
}}
}}
Propanethiol is an organic compound with the molecular formula C3H8S. It belongs to the group of thiols. It is a colorless liquid with a strong, offensive odor. It is moderately toxic and is less dense than water and slightly soluble in water. It is used as a feedstock for insecticides.[http://www.chemicalbook.com/ChemicalProductProperty_EN_CB6852694.htm 1-Propanethiol] {{Webarchive|url=https://web.archive.org/web/20150620091405/http://www.chemicalbook.com/ChemicalProductProperty_EN_CB6852694.htm |date=2015-06-20 }}, chemicalbook.com It is highly flammable and it gives off irritating or toxic fumes (or gases) in a fire. Heating it will cause rise in pressure with risk of bursting.[http://www.inchem.org/documents/icsc/icsc/eics1492.htm 1-Propanethiol], inchem.org[https://www.cdc.gov/niosh/ipcsneng/neng1492.html 1-Propanethiol], International Chemical Safety Card
Chemistry
Propanethiol is chemically classified among the thiols, which are organic compounds with molecular formulas and structural formulas similar to alcohols, except that sulfur-containing sulfhydryl group (-SH) replaces the oxygen-containing hydroxyl group in the molecule. Propanethiol's basic molecular formula is C3H7SH, and its structural formula is similar to that of the alcohol n-propanol.
Propanethiol is manufactured commercially by the reaction of propene with hydrogen sulfide with ultraviolet light initiation in an anti-Markovnikov addition.Rector P.Louthan, United States Patent 3,050,452, Aug. 21, 1962, Preparation of Organic Sulfur Compounds It can also be prepared by the reaction of sodium hydrosulfide with 1-chloropropane.
See also
- Isopropyl mercaptan (2-propanethiol)