Propylamine
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 464217260
| ImageFile = PrNH2.svg
| ImageClass = skin-invert-image
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageSize = 200
| ImageName = Skeletal formula of propylamine
| ImageFile1 = N-Propylamine 3D ball.png
| ImageSize1 = 200
| ImageName1 = Ball and stick model of propylamine
| PIN = Propan-1-amine
| OtherNames = Propylamine
|Section1={{Chembox Identifiers
| CASNo = 107-10-8
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = I76F18D635
| PubChem = 7852
| ChemSpiderID = 7564
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| EINECS = 203-462-3
| UNNumber = 1277
| ChEBI = 39870
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 14409
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| RTECS = UH9100000
| Beilstein = 1098243
| Gmelin = 1529
| SMILES = CCCN
| StdInChI = 1S/C3H9N/c1-2-3-4/h2-4H2,1H3
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = WGYKZJWCGVVSQN-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| C = 3
| H = 9
| N = 1
| Appearance = Colorless liquid
| Odor = fishy, ammoniacal
| Density = 0.719 g mL−1
| MeltingPtK = 190.15
| BoilingPtK = 320 to 324
| Solubility = Miscible
| LogP = 0.547
| pKa = 10.71
| VaporPressure = 33.01 kPa (at 20 °C)
| HenryConstant = 660 μmol Pa−1 kg−1
| RefractIndex = 1.388
}}
|Section3={{Chembox Thermochemistry
| DeltaHf = −101.9–−101.1 kJ mol−1
| DeltaHc = −2.368–−2.362 MJ mol−1
| Entropy = 227.44 J K−1 mol−1
| HeatCapacity = 162.51 J K−1 mol−1
}}
|Section4={{Chembox Hazards
| GHSPictograms = {{GHS flame}} {{GHS corrosion}} {{GHS skull and crossbones}}
| GHSSignalWord = DANGER
| HPhrases = {{H-phrases|225|302|311|314|331}}
| PPhrases = {{P-phrases|210|261|280|305+351+338|310}}
| FlashPtC = −30
| ExploLimits = 2–10.4%
| LD50 = {{Unbulleted list|370 mg kg−1 (oral, rat)|402.6 mg kg−1 (dermal, rabbit)}}
}}
|Section5={{Chembox Related
| OtherFunction_label = alkanamines
| OtherFunction = {{Unbulleted list|Ethylamine|Ethylenediamine|Isopropylamine|1,2-Diaminopropane|1,3-Diaminopropane|Isobutylamine|tert-Butylamine|n-Butylamine|sec-Butylamine|Putrescine}}
}}
}}
Propylamine, also known as n-propylamine, is an amine with the chemical formula CH3(CH2)2NH2.{{Cite web|url=https://pubchem.ncbi.nlm.nih.gov/compound/Propylamine|title = Propylamine}} It is a colorless volatile liquid.Karsten Eller, Erhard Henkes, Roland Rossbacher, Hartmut Höke "Amines, Aliphatic" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2005. {{doi|10.1002/14356007.a02_001}}
Propylamine is a weak base. Its Kb (base dissociation constant) is 4.7 × 10−4.
Preparation
Propyl amine hydrochloride can be prepared by reacting 1-propanol with ammonium chloride at high temperature and pressure using a Lewis acid catalyst such as ferric chloride.
References
{{Reflist}}
External links
- [http://www.inchem.org/documents/icsc/icsc/eics0941.htm International Chemical Safety Card]