Samarium(II) chloride

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| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 464386601

| Name = Samarium(II) chloride

| ImageFile = Cotunnite structure.png

| ImageFile2 = Anode_precipitate_of_SmCl2.jpg

| ImageName = Samarium(I) chloride

| IUPACName = Samarium(I) chloride

| OtherNames = Samarium dichloride

|Section1={{Chembox Identifiers

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 4908199

| EINECS = 237-631-8

| PubChem = 6393953

| InChI = 1/2ClH.Sm/h2*1H;/q;;+2/p-2

| InChIKey = VPRJMFJPKMESHB-NUQVWONBAS

| SMILES = Cl[Sm]Cl

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/2ClH.Sm/h2*1H;/q;;+2/p-2

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = VPRJMFJPKMESHB-UHFFFAOYSA-L

| CASNo_Ref = {{cascite|changed|??}}

| CASNo = 13874-75-4

}}

|Section2={{Chembox Properties

| Formula = SmCl2

| MolarMass = 221.27 g/mol

| Appearance = dark brown crystals{{Cite book|last1=Brauer|first1=Georg|title=Handbuch der Präparativen Anorganischen Chemie, Band I.|last2=Baudler|first2=Marianne|publisher=Ferdinand Enke|year=1975|isbn=3-432-02328-6|edition=3rd|location=Stuttgart|pages=}}

| Density = 3.69 g/cm3, solid

| Solubility = ?

| MeltingPtC = 855

| BoilingPtC = 1310

}}

|Section3={{Chembox Structure

| CrystalStruct = Orthorhombic

| SpaceGroup = Pbnm, No. 62{{cite journal |last1=Meyer|first1=Gerd|last2=Schleid|first2=Thomas|date=1986-02-01|title=The metallothermic reduction of several rare-earth trichlorides with lithium and sodium|journal=Journal of the Less Common Metals|volume=116|issue=1|pages=187–197|doi=10.1016/0022-5088(86)90228-6}}

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|Section7={{Chembox Hazards

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|Section8={{Chembox Related

| OtherAnions = Samarium(II) bromide
Samarium(II) iodide

| OtherCations = Samarium(III) chloride

}}

}}

Samarium(II) chloride (SmCl2) is a chemical compound, used as a radical generating agent in the ketone-mediated intraannulation reaction.

Preparation

Reduction of samarium(III) chloride with samarium metal in a vacuum at a temperature of 800 °C to 900 °C, or with hydrogen gas at 350 °C yields samarium(II) chloride:

:2 SmCl3 + Sm → 3 SmCl2

:2 SmCl3 + H2 → 2 SmCl2 + 2 HCl

Samarium(II) chloride can also be prepared by reducing samarium(III) chloride with lithium metal/naphthalene in THF:{{cite journal |last1=Rossmainth|first1=Kurt|date=1979-01-01|title=Herstellung der klassischen Seltenerd(II)-chloride in Lösung|trans-title=Preparation of the classical rare earth(II) chlorides in solution|url= |journal= Anorganische, Struktur- und Physikalische Chemie|volume=110|issue=4|pages=109–114|doi=10.1007/BF00903752|s2cid=91731356 |access-date=}}

: SmCl3 + Li → SmCl2 + LiCl

A similar reaction has been observed with sodium.

Structure

Samarium(II) chloride adopts the PbCl2 (cotunnite) structure.

References

{{reflist}}

{{Samarium compounds}}

{{Chlorides}}

{{Lanthanide halides}}

Category:Chlorides

Category:Lanthanide halides

Category:Samarium(II) compounds

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