Samarium(II) chloride
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 464386601
| Name = Samarium(II) chloride
| ImageFile = Cotunnite structure.png
| ImageFile2 = Anode_precipitate_of_SmCl2.jpg
| ImageName = Samarium(I) chloride
| IUPACName = Samarium(I) chloride
| OtherNames = Samarium dichloride
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 4908199
| EINECS = 237-631-8
| PubChem = 6393953
| InChI = 1/2ClH.Sm/h2*1H;/q;;+2/p-2
| InChIKey = VPRJMFJPKMESHB-NUQVWONBAS
| SMILES = Cl[Sm]Cl
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2ClH.Sm/h2*1H;/q;;+2/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = VPRJMFJPKMESHB-UHFFFAOYSA-L
| CASNo_Ref = {{cascite|changed|??}}
| CASNo = 13874-75-4
}}
|Section2={{Chembox Properties
| Formula = SmCl2
| MolarMass = 221.27 g/mol
| Appearance = dark brown crystals{{Cite book|last1=Brauer|first1=Georg|title=Handbuch der Präparativen Anorganischen Chemie, Band I.|last2=Baudler|first2=Marianne|publisher=Ferdinand Enke|year=1975|isbn=3-432-02328-6|edition=3rd|location=Stuttgart|pages=}}
| Density = 3.69 g/cm3, solid
| Solubility = ?
| MeltingPtC = 855
| BoilingPtC = 1310
}}
|Section3={{Chembox Structure
| CrystalStruct = Orthorhombic
}}
|Section7={{Chembox Hazards
}}
|Section8={{Chembox Related
| OtherAnions = Samarium(II) bromide
Samarium(II) iodide
| OtherCations = Samarium(III) chloride
}}
}}
Samarium(II) chloride (SmCl2) is a chemical compound, used as a radical generating agent in the ketone-mediated intraannulation reaction.
Preparation
Reduction of samarium(III) chloride with samarium metal in a vacuum at a temperature of 800 °C to 900 °C, or with hydrogen gas at 350 °C yields samarium(II) chloride:
:2 SmCl3 + Sm → 3 SmCl2
:2 SmCl3 + H2 → 2 SmCl2 + 2 HCl
Samarium(II) chloride can also be prepared by reducing samarium(III) chloride with lithium metal/naphthalene in THF:{{cite journal |last1=Rossmainth|first1=Kurt|date=1979-01-01|title=Herstellung der klassischen Seltenerd(II)-chloride in Lösung|trans-title=Preparation of the classical rare earth(II) chlorides in solution|url= |journal= Anorganische, Struktur- und Physikalische Chemie|volume=110|issue=4|pages=109–114|doi=10.1007/BF00903752|s2cid=91731356 |access-date=}}
: SmCl3 + Li → SmCl2 + LiCl
Structure
References
{{reflist}}
{{Samarium compounds}}
{{Chlorides}}
{{Lanthanide halides}}
Category:Samarium(II) compounds
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