Samarium(III) bromide

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| Name =Samarium(III) bromide

| IUPACName =samarium(III) bromide

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| OtherNames = samarium tribromide
tribromosamarium

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| CASNo = 13759-87-0

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| ChemSpiderID = 75528

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| EC_number = 237-347-4

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| InChI = InChI=1S/3BrH.6H2O.Sm/h3*1H;6*1H2;/q;;;;;;;;;+3/p-3

| InChIKey = LXJDCZVUWJNXRL-UHFFFAOYSA-K

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| PubChem = 24868613

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| SMILES = Br[Sm](Br)Br

| SMILES1 = [Br-].[Br-].[Br-].[Sm+3]

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| Appearance = Light yellow solid {{Cite book | date = 2016-06-24 | title = CRC Handbook of Chemistry and Physics 97th Edition | pages = 4–83 | language = en | isbn = 978-1-4987-5428-6 | last1 = Haynes | first1 = William M. | publisher = CRC Press }}

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| Density =

| Formula = SmBr3

| Sm=1 | Br=3

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| MeltingPtC = 700

| MeltingPt_ref = <{{cite web|title=Samarium(III) bromide anhydrous, beads, −10 mesh, 99.99% {{!}} Sigma-Aldrich|url=http://www.sigmaaldrich.com/catalog/product/aldrich/451231?lang=en®ion=US|website=www.sigmaaldrich.com|accessdate=21 December 2016}}

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| MagSus = +972.0·10−6 cm3/mol

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| GHSSignalWord = Warning

| HPhrases ={{H-phrases|315|319|335}}

| PPhrases ={{P-phrases|261|305+351+338}}

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| Section9 = {{Chembox Related

| OtherAnions = Samarium(III) fluoride
Samarium(III) chloride

| OtherCations = Samarium(II) bromide

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Samarium(III) bromide is a crystalline compound of one samarium and three bromine atoms with the chemical formula of SmBr3. Samarium(III) bromide is a dark brown powder at room temperature.{{cite web|last1=Elements|first1=American|title=Samarium(III) Bromide Hexahydrate|url=https://www.americanelements.com/samarium-iii-bromide-hexahydrate-13517-12-9|website=American Elements|accessdate=21 December 2016}} The compound has a crystal structure isotypic to that of plutonium(III) bromide.{{Cite book| author=Christoph Janiak, Hans-Jürgen Meyer, Dietrich Gudat, Ralf Alsfasser | title=Riedel Moderne Anorganische Chemie | publisher=Walter de Gruyter | isbn=978-3-11-024901-9 | year=2012 | url=https://books.google.com/books?id=bW7cxciPCv4C&pg=PA371}}{{ cite book | first1 = A. F. | last1 = Wells | title = Structural Inorganic Chemistry | edition = 5th | year = 1984 | publisher = Oxford University Press | isbn = 978-0-19-965763-6 | page = 421 }}

Preparation

SmBr3·6H2O can be crystallized by dissolving samarium oxide in 40% hydrobromic acid. The hydrate and ammonium bromide are heated in a vacuum to obtain the anhydrous form of samarium(III) bromide.林平娣, 吴国庆. [http://www.ixueshu.com/document/12ab93e1aee17e7b318947a18e7f9386.html 无水三溴化钐和三溴化镱的制备] {{Webarchive|url=https://web.archive.org/web/20220101151821/https://www.ixueshu.com/document/12ab93e1aee17e7b318947a18e7f9386.html |date=2022-01-01 }}[J]. 化学试剂, 1991(1):13-14.

Other compounds

Samarium(III) bromide forms some compounds with hydrazine, such as SmBr3·3N2H4·H2O which is a pale yellow needle-shaped crystal that is soluble in water and ethanol but insoluble in benzene, with d20 °C = 3.147 g/cm3.[https://books.google.com/books?id=GJ04AAAAIAAJ Uchenye zapiski: Serii︠a︡ khimicheskikh nauk] (SM Kirov adyna Azărbai̐jan Dȯvlăt Universiteti; 1977), page 37. Retrieved 14 March 2021.

References

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{{Samarium compounds}}

{{Inorganic bromides}}

{{Lanthanide halides}}

Category:Bromides

Category:Lanthanide halides

Category:Samarium(III) compounds

{{Inorganic-compound-stub}}