Selenium oxydichloride
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 438850594
| Name = Selenium oxydichloride
| ImageFile = Seleninyl chloride.png
| ImageFileL1 = SeOCl2pyramidal.png
| ImageNameL1 = Structure of the selenium oxydichloride molecule
| ImageFileR1 = Selenium-oxydichloride-3D-vdW.png
| ImageNameR1 = 3D model of the selenium oxydichloride molecule
| IUPACName = Selenium oxychloride
| OtherNames = Seleninyl chloride
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 7791-23-3
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 1G57T5401W
| PubChem = 24647
| RTECS = VS7000000
| EINECS = 232-244-0
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23049
| InChI = 1/Cl2OSe/c1-4(2)3
| InChIKey = LIRMPIXWGWLNND-UHFFFAOYAX
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/Cl2OSe/c1-4(2)3
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = LIRMPIXWGWLNND-UHFFFAOYSA-N
| SMILES = O=[Se](Cl)Cl
}}
|Section2={{Chembox Properties
| Formula = SeOCl2
| MolarMass = 165.87 g/mol
| Appearance = colorless liquid
| Density = 2.43 g/cm3, liquid
| Solubility =
| SolubleOther =
| MeltingPtC = 10.9
| BoilingPtC = 177.2
| Viscosity =
| RefractIndex = 1.651 (20 °C)
}}
|Section3={{Chembox Structure
| MolShape = trigonal pyramidal
| Dipole =
}}
|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards =
| GHSPictograms = {{GHS05}}{{GHS06}}{{GHS08}}{{GHS09}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|301|314|331|373|410}}
| PPhrases = {{P-phrases|260|261|264|270|271|273|280|301+310|301+330+331|303+361+353|304+340|305+351+338|310|311|314|321|330|363|391|403+233|405|501}}
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 1
| LDLo = 2 mg/kg (rabbit, dermal){{IDLH|7782492|Selenium compounds (as Se)}}
}}
|Section8={{Chembox Related
| OtherFunction_label = compounds
| OtherFunction = SOCl2, POCl3
}}
}}
Selenium oxydichloride is the inorganic compound with the formula SeOCl2. It is a colorless liquid. With a high dielectric constant (55) and high specific conductance, it is an attractive solvent. Structurally, it is a close chemical relative of thionyl chloride SOCl2, being a pyramidal molecule.
Preparation and reactions
Selenium oxydichloride can be prepared by several methods, and a common one involves the conversion of selenium dioxide to dichloroselenious acid followed by dehydration:{{cite book | last1 = Smith | first1 = G. B. L. | last2 = Jackson | first2 = Julius | title = Inorganic Syntheses | year = 1950 | chapter = Selenium(IV) Oxychloride | volume = 3 | pages = 130–137 | doi = 10.1002/9780470132340.ch34 | isbn = 9780470132340 }}
:SeO2 + 2 HCl → Se(OH)2Cl2
:Se(OH)2Cl2 → SeOCl2 + H2O
The original synthesis involved the redistribution reaction of selenium dioxide and selenium tetrachloride.
Pure selenium oxydichloride autoionizes to a dimer:{{sfn|Audrieth|Kleinberg|1953|p=237}}
:SeOCl2 ↔ (SeO)2Cl{{su|b=3|p=+}} + Cl−
The SeOCl2 is generally a labile Lewis acid and solutions of sulfur trioxide in SeOCl2 likely form [SeOCl]+[SO3Cl]− the same way.{{sfn|Audrieth|Kleinberg|1953|pp=239-242}}
The compound hydrolyzes readily to form hydrogen chloride and selenium dioxide,{{cn|date=May 2024}} and very few organic compounds dissolve in it without reaction. At elevated temperatures, it is a strong oxidizer, yielding a chloride, selenium dioxide, and diselenium dichloride.{{cite book|url=https://archive.org/details/cftri.2662nonaqueoussolven0000ludw/page/|pages=235–6|title=Non-aqueous solvents|first1=Ludwig F.|last1=Audrieth|first2=Jacob|last2=Kleinberg|publisher=John Wiley & Sons|location=New York|year=1953|lccn=52-12057}}
See also
- Selenium oxybromide SeOBr2
- Selenous acid H2SeO3