Strongly correlated material

{{Short description|Materials with electrical properties that cannot be explained by non-interacting entities

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{{Use American English|date=January 2019}}

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Image:Bi2212 Unit Cell.png of BSCCO, a high-temperature superconductor and a strongly correlated material.]]

Strongly correlated materials are a wide class of compounds that include insulators and electronic materials, and show unusual (often technologically useful) electronic and magnetic properties, such as metal-insulator transitions, heavy fermion behavior, half-metallicity, and spin-charge separation. The essential feature that defines these materials is that the behavior of their electrons or spinons cannot be described effectively in terms of non-interacting entities.{{cite journal | last1=Quintanilla | first1=Jorge | last2=Hooley | first2=Chris | title=The strong-correlations puzzle | journal=Physics World | publisher=IOP Publishing | volume=22 | issue=6 | year=2009 | issn=0953-8585 | doi=10.1088/2058-7058/22/06/38 | pages=32–37| url=http://purl.org/net/epubs/manifestation/3667/2009-Quintanilla-Hooley.pdf | bibcode=2009PhyW...22f..32Q }} Theoretical models of the electronic (fermionic) structure of strongly correlated materials must include electronic (fermionic) correlation to be accurate. As of recently, the label quantum materials is also used to refer to strongly correlated materials, among others.

Transition metal oxides

Many transition metal oxides belong to this class{{cite web|last=Millis|first=A. J.|title=Lecture notes on "Strongly Correlated" Transition Metal Oxides|url=http://www.phys.columbia.edu/~millis/Cargeselecturenotes.pdf|publisher=Columbia University|accessdate=20 June 2012}} which may be subdivided according to their behavior, e.g. high-Tc, spintronic materials, multiferroics, Mott insulators, spin Peierls materials, heavy fermion materials, quasi-low-dimensional materials, etc. The single most intensively studied effect is probably high-temperature superconductivity in doped cuprates, e.g. La2−xSrxCuO4. Other ordering or magnetic phenomena and temperature-induced phase transitions in many transition-metal oxides are also gathered under the term "strongly correlated materials."

Electronic structures

Typically, strongly correlated materials have incompletely filled d- or f-electron shells with narrow energy bands. One can no longer consider any electron in the material as being in a "sea" of the averaged motion of the others (also known as mean field theory). Each single electron has a complex influence on its neighbors.

The term strong correlation refers to behavior of electrons in solids that is not well-described (often not even in a qualitatively correct manner) by simple one-electron theories such as the local-density approximation (LDA) of density-functional theory or Hartree–Fock theory. For instance, the seemingly simple material NiO has a partially filled 3d band (the Ni atom has 8 of 10 possible 3d-electrons) and therefore would be expected to be a good conductor. However, strong Coulomb repulsion (a correlation effect) between d electrons makes NiO instead a wide-band gap insulator. Thus, strongly correlated materials have electronic structures that are neither simply free-electron-like nor completely ionic, but a mixture of both.

Theories

Extensions to the LDA (LDA+U, GGA, SIC, GW, etc.) as well as simplified models Hamiltonians (e.g. Hubbard-like models) have been proposed and developed in order to describe phenomena that are due to strong electron correlation. Among them, dynamical mean field theory (DMFT) successfully captures the main features of correlated materials. Schemes that use both LDA and DMFT explain many experimental results in the field of correlated electrons.

Structural studies

Experimentally, optical spectroscopy, high-energy electron spectroscopies, [http://www.uksaf.org/tech/ups.html resonant photoemission], and more recently resonant inelastic (hard and soft) X-ray scattering (RIXS) and neutron spectroscopy have been used to study the electronic and magnetic structure of strongly correlated materials. Spectral signatures seen by these techniques that are not explained by one-electron density of states are often related to strong correlation effects. The experimentally obtained spectra can be compared to predictions of certain models or may be used to establish constraints on the parameter sets. One has for instance established a classification scheme of transition metal oxides within the so-called Zaanen–Sawatzky–Allen diagram.

{{cite journal

|author1=J. Zaanen |author2=G. A. Sawatzky |author3=J. W. Allen | year = 1985

| title = Band Gaps and Electronic Structure of Transition-Metal Compounds

| journal = Physical Review Letters | volume = 55 |issue=4 | pages = 418–421 | doi = 10.1103/PhysRevLett.55.418

|pmid=10032345 | url=http://www.lorentz.leidenuniv.nl/~jan/zsa.pdf |bibcode = 1985PhRvL..55..418Z |hdl=1887/5216 |hdl-access=free }}

Applications

The manipulation and use of correlated phenomena has applications like superconducting magnets and in magnetic storage (CMR){{Citation needed|date=February 2013}} technologies. Other phenomena like the metal-insulator transition in VO2 have been explored as a means to make smart windows to reduce the heating/cooling requirements of a room.

{{cite journal

|author1=J. M. Tomczak |author2=S. Biermann | year= 2009

| title = Optical properties of correlated materials – Or why intelligent windows may look dirty

| journal = Physica Status Solidi B | volume = 246 |issue=9 | pages = 1996–2005 | doi = 10.1002/pssb.200945231

|arxiv = 0907.1575 |bibcode = 2009PSSBR.246.1996T |s2cid=6942417 }}

Furthermore, metal-insulator transitions in Mott insulating materials like LaTiO3 can be tuned through adjustments in band filling to potentially be used to make transistors that would use conventional field effect transistor configurations to take advantage of the material's sharp change in conductivity.{{cite journal |last1=Scheiderer |first1=Philipp |last2=Schmitt |first2=Matthias |last3=Gabel |first3=Judith |last4=Zapf |first4=Michael |last5=Stübinger |first5=Martin |last6=Schütz |first6=Philipp |last7=Dudy |first7=Lenart |last8=Schlueter |first8=Christoph |last9=Lee |first9=Tien-Lin |last10=Sing |first10=Michael |last11=Claessen |first11=Ralph |title=Tailoring Materials for Mottronics: Excess Oxygen Doping of a Prototypical Mott Insulator |journal=Advanced Materials |date=2018 |volume=30 |issue=25 |pages=1706708 |doi=10.1002/adma.201706708|pmid=29732633 |arxiv=1807.05724 |bibcode=2018AdM....3006708S |s2cid=19134593 }} Transistors using metal-insulator transitions in Mott insulators are often referred to as Mott transistors, and have been successfully fabricated using VO2 before, but they have required the larger electric fields induced by ionic liquids as a gate material to operate.{{cite journal |last1=Nakano |first1=M. |last2=Shibuya |first2=K. |last3=Okuyama |first3=D. |last4=Hatano |first4=T. |last5=Ono |first5=S. |last6=Kawasaki |first6=M. |last7=Iwasa |first7=Y. |last8=Tokura |first8=Y. |title=Collective bulk carrier delocalization driven by electrostatic surface charge accumulation |journal=Nature |date=July 2012 |volume=487 |issue=7408 |pages=459–462 |doi=10.1038/nature11296|pmid=22837001 |bibcode=2012Natur.487..459N |s2cid=4401622 }}

See also

References

{{Reflist}}

Further reading

  • {{Cite book |author1=Anisimov, Vladimir |author2=Yuri Izyumov | title=Electronic Structure of Strongly Correlated Materials | publisher=Springer | year=2010 | isbn= 978-3-642-04825-8}}
  • {{Cite book | author= Patrik Fazekas | title=Lecture Notes on Electron Correlation and Magnetism | publisher=World Scientific | year=1999 | isbn= 978-9810224745}}
  • {{Cite book |author1=de Groot, Frank |author2=Akio Kotani | title=Core Level Spectroscopy of Solids | publisher=CRC Press | year=2008 | isbn= 978-0-8493-9071-5}}
  • {{Cite book | author=Yamada, Kosaku | title=Electron Correlations in Metals | publisher=Cambridge University Press | year=2004 | isbn= 978-0-521-57232-3}}
  • {{Cite book | editor=Robert Z. Bachrach | title=Synchrotron radiation research : advances in surface and interface science | publisher=Plenum Press | year=1992 | isbn= 978-0-306-43872-1}}
  • {{Cite book | author=Pavarini, Eva; Koch Erik; Vollhardt, Dieter; Lichtenstein, Alexander; (eds.) | title=The LDA+DMFT approach to strongly correlated materials | url=http://www.cond-mat.de/events/correl11/manuscript | publisher=Forschungszentrum Jülich | year=2011 | isbn= 978-3-89336-734-4}}
  • {{Cite book | author=Amusia, M., Popov, K., Shaginyan, V., Stephanovich, V. | title=Theory of Heavy-Fermion Compounds - Theory of Strongly Correlated Fermi-Systems | volume=182 | publisher=Springer | year=2014 | isbn= 978-3-319-10825-4| doi=10.1007/978-3-319-10825-4 | series=Springer Series in Solid-State Sciences }}