Sugar acid
{{short description|Sugar molecule with an –OH group at the end(s) of the carbon chain}}
In organic chemistry, a sugar acid or acidic sugar is a monosaccharide with a carboxyl group at one end or both ends of its chain.{{cite book |title=Essentials of carbohydrate chemistry |author=Robyt, J.F. |publisher=Springer |location=New York |year= 1998
| url=https://books.google.com/books?id=l4NfU7_sAZoC&q=%22b.+Aldonic+acids%22&pg=PA366 |isbn=0-387-94951-8}}
Main classes of sugar acids include:
- Aldonic acids, in which the aldehyde group ({{chem2|\sCH\dO}}) located at the initial end (position 1) of an aldose is oxidized.
- Ulosonic acids, in which the hydroxymethyl group ({{chem2|\sCH2OH}}) at the initial end of a 2-ketose is oxidized creating an α-ketoacid.
- Uronic acids, in which the {{chem2|\sCH2OH}} group at the terminal end of an aldose or ketose is oxidized.
- Aldaric acids, in which both ends ({{chem2|\sCH\dO}} and {{chem2|\sCH2OH}}) of an aldose are oxidized.
File:D-Gluconsäure Keilstrich.svg]] | File:3-Deoxy-D-manno-oct-2-ulosonic acid linear.png]] | File:Beta D-Glucuronic acid.svg]] | File:Tartaric acid.svg]] |
Examples
Examples of sugar acids include:
- Aldonic acids
- Glyceric acid (3C)
- Xylonic acid (5C)
- Gluconic acid (6C)
- Ascorbic acid{{Cite book|author1=Davies Michael B.|author2=Austin John|author3=Partridge David A.| title=Vitamin C: Its Chemistry and Biochemistry| publisher=The Royal Society of Chemistry| year=1991| page=48 |isbn = 0-85186-333-7}} (6C, unsaturated lactone)
- Ulosonic acids
- Neuraminic acid (5-amino-3,5-dideoxy-D-glycero-D-galacto-non-2-ulosonic acid)
- Ketodeoxyoctulosonic acid (KDO or 3-deoxy-D-manno-oct-2-ulosonic acid)
- Uronic acids
- Glucuronic acid (6C)
- Galacturonic acid (6C)
- Iduronic acid (6C)
- Aldaric acids
- Tartaric acid (4C)
- meso-Galactaric acid (Mucic acid) (6C)
- D-Glucaric acid (Saccharic acid) (6C)
File:L-Ascorbic acid.svg (Vitamin C)]] |
References
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