Tantalum(V) iodide
{{Chembox
| ImageFile = Ta2I10.svg
| ImageSize =
| ImageAlt =
| IUPACName =
| OtherNames = Tantalum pentaiodide
|Section1={{Chembox Identifiers
| CASNo1 = 14693-81-3
| CASNo1_Comment = TaI5
| CASNo1_Ref = {{Cascite|correct|CAS}}
| CASNo2 = 26814-38-0
| CASNo2_Comment = Ta2I10
| ChemSpiderID = 76319
| EC_number = 238-742-4
| PubChem = 84598
| StdInChI=1S/5HI.Ta/h5*1H;/q;;;;;+5/p-5
| StdInChIKey = MISXNQITXACHNJ-UHFFFAOYSA-I
| SMILES = [I-].[I-].[I-].[I-].[I-].[Ta+5]
}}
|Section2={{Chembox Properties
| Formula = {{chem2|Ta2I10}}
| Ta=2|I=10
| Appearance = black solid
| Density = 5.8 g/cm3
| MeltingPt_notes = sublimes
| BoilingPt =
| Solubility = }}
|Section7={{Chembox Hazards
| GHSPictograms = {{GHS05}}{{GHS06}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|314|331}}
| PPhrases = {{P-phrases|260|261|264|271|280|301+330+331|303+361+353|304+340|305+351+338|310|311|321|363|403+233|405|501}}
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
| Section9 = {{Chembox Related
| OtherAnions = {{ubl|Tantalum(V) fluoride|Tantalum(V) chloride|Tantalum(V) bromide}}
| OtherCations = {{ubl|Protactinium(V) iodide|Niobium(V) iodide}}
| OtherCompounds = {{ubl|Tantalum(IV) iodide}}
}}
}}
Tantalum(V) iodide is the inorganic compound with the formula Ta2I10. Its name comes from the compound's empirical formula, TaI5.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford: Butterworth-Heinemann. {{ISBN|0-7506-3365-4}}. It is a diamagnetic, black solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two TaI5 units are joined by a pair of iodide bridges. There is no bond between the Ta centres.{{cite journal|doi=10.1107/S0567740879009778|title=Die Kristallstruktur von Tantalpentajodid und ihre Fehlordnung|year=1979|last1=Müller|first1=U.|journal=Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry|volume=35|issue=11|pages=2502–2509|bibcode=1979AcCrB..35.2502M }} Niobium(V) chloride, niobium(V) bromide, niobium(V) iodide, tantalum(V) chloride, and tantalum(V) bromide all share this structural motif.
Synthesis and structure
Tantalum pentaiodide forms from the reaction of tantalum pentoxide with aluminium triiodide:{{cite book|author=G. Braurer|chapter=Niobium(V) and Tantalum(V) Bromides|title=Handbook of Preparative Inorganic Chemistry, 2nd Ed. |editor=G. Brauer|publisher=Academic Press|year=1963|place=NY, NY|volume=1|pages=1311}}
:{{chem2|3 Ta2O5 + 10 AlI3 → 6 TaI5 + 5 Al2O3}}