Tantalum arsenide
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| Name = Tantalum arsenide
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| ImageFile = File:TaAs Structure.png
| ImageAlt = Tantalum arsenide crystal structure.
| ImageCaption = {{Color box|#0000ff|border=silver}} Ta {{Color box|#ff0000|border=silver}} As
| ImageSize = 150px
| Section1 = {{Chembox Identifiers
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| SMILES = [As]#[Ta]
| StdInChI=1S/As.Ta
| StdInChIKey=WCMKFCQUZDOHAQ-UHFFFAOYSA-N
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| Section2 = {{Chembox Properties
| Formula = TaAs
| MolarMass = 255.869 g/mol
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| Section3 = {{Chembox Structure
| CrystalStruct = Body-centered tetragonal
| SpaceGroup = I41md, No. 109
| PointGroup = 4mm
| LattConst_a = 3.44 Å
| LattConst_c = 11.65 Å
| LattConst_ref ={{cite journal | vauthors=((Xu, S.-Y.)), ((Belopolski, I.)), ((Alidoust, N.)), ((Neupane, M.)), ((Bian, G.)), ((Zhang, C.)), ((Sankar, R.)), ((Chang, G.)), ((Yuan, Z.)), ((Lee, C.-C.)), ((Huang, S.-M.)), ((Zheng, H.)), ((Ma, J.)), ((Sanchez, D. S.)), ((Wang, B.)), ((Bansil, A.)), ((Chou, F.)), ((Shibayev, P. P.)), ((Lin, H.)), ((Jia, S.)), ((Hasan, M. Z.)) | journal=Science | title=Discovery of a Weyl fermion semimetal and topological Fermi arcs | volume=349 | issue=6248 | pages=613–617 | date=7 August 2015 | issn=1095-9203 | doi=10.1126/science.aaa9297| pmid=26184916 | arxiv=1502.03807 | bibcode=2015Sci...349..613X | s2cid=206636457 }}
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Tantalum arsenide is a compound of tantalum and arsenic with the formula TaAs. It is notable as being the first topological Weyl semimetal that was identified and characterized by ARPES. It exhibits an analogue of quantum vortices in momentum space.{{cite journal |last1=Figgemeier |first1=T. |last2=Ünzelmann |first2=M. |last3=Eck |first3=P. |last4=Schusser |first4=J. |last5=Crippa |first5=L. |last6=Neu |first6=J. N. |last7=Geldiyev |first7=B. |last8=Kagerer |first8=P. |last9=Buck |first9=J. |last10=Kalläne |first10=M. |last11=Hoesch |first11=M. |last12=Rossnagel |first12=K. |last13=Siegrist |first13=T. |last14=Lim |first14=L.-K. |last15=Moessner |first15=R. |last16=Sangiovanni |first16=G. |last17=Di Sante |first17=D. |last18=Reinert |first18=F. |last19=Bentmann |first19=H. |title=Imaging Orbital Vortex Lines in Three-Dimensional Momentum Space |journal=Physical Review X |date=13 February 2025 |volume=15 |issue=1 |doi=10.1103/PhysRevX.15.011032|doi-access=free }}
Structure
Tantalum arsenide crystallizes in a body-centered tetragonal unit cell with lattice parameters a = 3.44 Å and c = 11.65 Å. It belongs to the space group I41md.
Preparation
TaAs has been prepared by decomposing TaAs2 at 900 °C. A more recent preparation yielded large, single crystals of TaAs by chemical vapor transport with elemental precursors and iodine as the transport agent:
:TaI5 (g) + AsI3 (g) ↔ TaAs (s) + 4 I2 (g)
References
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{{Tantalum compounds}}
{{Arsenides}}