Terbium(III) perchlorate

{{Chembox

| Name =

|ImageFile=

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| Section1 = {{Chembox Identifiers

| CASNo = 14014-09-6

| CASNo_Ref = {{cascite|correct|CAS}}

| index_label = anhydrous

| CASNo2 = 80398-56-7

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| index2_label = hexahydrate

| ChemSpiderID = 14653481

| ChemSpiderID2 = 2341282

| EC_number = 237-826-8

| PubChem2 = 3084176

| InChI2=1S/3ClHO4.6H2O.Tb/c3*2-1(3,4)5;;;;;;;/h3*(H,2,3,4,5);6*1H2;/q;;;;;;;;;+3/p-3

| InChIKey2 = NAPXFYQZNZUQDE-UHFFFAOYSA-K

| SMILES = [O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Tb+3]

| SMILES2 = O.O.O.O.O.O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[Tb+3]

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| Section2 = {{Chembox Properties

| Tb=1 | Cl=3 | O=12

| Appearance = light pink crystals (hexahydrate){{cite book | author = Jane E. Macintyre | date = 23 July 1992 | title = Dictionary of Inorganic Compounds | publisher = CRC Press | pages = 2930– | isbn = 978-0-412-30120-9 | url = https://books.google.com/books?id=9eJvoNCSCRMC&pg=PA2930}}

| Density = 2.21 g/cm³ (hexahydrate)Glaser J. Crystal structures of the isomorphous perchlorate hexahydrates of some trivalent metal ions (M= La, Tb, Er, Tl). Acta Chemica Scandinavica A. 1981. 35. 639-644

| MeltingPtC =

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| Solubility = soluble (anhydrous, hexahydrate) }}

| Section3 = {{Chembox Hazards

| GHS_ref={{cite web |title=Terbium(3+) perchlorate |url=https://pubchem.ncbi.nlm.nih.gov/compound/3084176#section=Safety-and-Hazards |website=pubchem.ncbi.nlm.nih.gov |language=en}}

| GHSPictograms = {{GHS03}}{{GHS07}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|272|315|319|335}}

| PPhrases = {{P-phrases|210|220|261|264|264+265|271|280|302+352|304+340|305+351+338|319|321|332+317|337+317|362+364|370+378|403+233|405|501}}

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Terbium perchlorate refers to an inorganic compound having chemical formula Tb(ClO₄)₃(H₂O)_x. Usually this salt is encountered as its hexahydrate. This terbium(III) compound can be obtained by treating terbium(III,IV) oxide with perchloric acid.{{cite journal|journal=Dyes and Pigments|volume=112|language=en|date=2015-01-01|pages=239–244|doi=10.1016/j.dyepig.2014.07.014|title=Conversion of Lewis acid–base interaction into readable emission outputs by novel terbium hybrid nanosphere|author1=Jintai Lin|author2=Yuhui Zheng|author3=Qianming Wang}} The perchlorates are non-coordinating anions, so this substance can be used as a starting material for forming Tb(III) complexes. For example, reaction with alanine forms a complex in which the carboxylate portion of four alanine units bridge between two terbium atoms.{{cite journal|journal=Acta Crystallographica Section E: Structure Reports Online|volume=66|issue=2|issn=1600-5368|date=2010-02-15|pages=m193–m194|doi=10.1107/S1600536810002448|title=Tetrakis-μ-L-alanine-κ⁸O:O′-bis[tetraaquaterbium(III)] hexaperchlorate|author1=Musa E. Mohamed|author2=Deepak Chopra|author3=K. N. Venugopal|author4=Thavendran Govender|author5=Hendrik G. Kruger|author6=Glenn E. M. Maguire|pmid=21579659 |pmc=2979733 }} It can be used to synthesize terbium-containing metal-organic framework materials.{{cite journal|journal=Crystal Growth & Design|volume=17|issue=6|language=en|issn=1528-7483|date=2017-06-07|pages=3128–3133|doi=10.1021/acs.cgd.7b00063|title=3d–4f Heterometal–Organic Frameworks for Efficient Capture and Conversion of CO₂|author1=Wan-Zhen Qiao|author2=Hang Xu|author3=Peng Cheng|author4=Bin Zhao|bibcode=2017CrGrD..17.3128Q }}{{cite journal|journal=Journal of Materials Chemistry C|volume=4|issue=22|language=en|issn=2050-7526|date=2016|pages=5038–5050|doi=10.1039/C6TC00919K|title=Antiferromagnetic single-chain magnet slow relaxation in the {{(}}Tb(α-fur)₃{{)}}_n polymer with non-Kramers ions|author1=E. Bartolomé|author2=J. Bartolomé|author3=A. Arauzo|author4=J. Luzón|author5=L. Badía|author6=R. Cases|author7=F. Luis|author8=S. Melnic|author9=D. Prodius|author10=S. Shova|author11=C. Turta}}