Tetraethylgermanium
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 470603839
| ImageFileL1 = Tetraethylgermanium.svg
| ImageFileL1_Ref = {{Chemboximage|correct|??}}
| ImageSizeL1 = 125
| ImageAltL1 = Structural formula of tetraethylgermanium
| ImageFileR1 = Tetraethylgermanium-3D-balls.png
| ImageSizeR1 = 135
| ImageAltR1 = Ball-and-stick model of the tetraethylgermanium molecule
| PIN = Tetraethylgermane
| SystematicName =
| OtherNames =
|Section1={{Chembox Identifiers
| Abbreviations = TEG
| CASNo = 597-63-7
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 11703
| ChemSpiderID = 11211
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| EINECS = 209-905-7
| UNNumber = 1993
| RTECS = LY5290000
| SMILES = CC[Ge](CC)(CC)CC
| StdInChI = 1S/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| InChI = 1/C8H20Ge/c1-5-9(6-2,7-3)8-4/h5-8H2,1-4H3
| StdInChIKey = QQXSEZVCKAEYQJ-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| InChIKey = QQXSEZVCKAEYQJ-UHFFFAOYAH}}
|Section2={{Chembox Properties
| C = 8
| H = 20
| Ge = 1
| Appearance = Colourless liquid
| Density = 0.998 g cm−3
| BoilingPtC = 163 to 165}}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS02}}{{GHS07}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|226|302|315|319|335}}
| PPhrases = {{P-phrases|210|233|240|241|242|243|261|264|270|271|280|301+312|302+352|303+361+353|304+340|305+351+338|312|321|330|332+313|337+313|362|370+378|403+233|403+235|405|501}}
| NFPA-H = 2
| NFPA-F = 3
| NFPA-R = 2
| FlashPtC = 35}}
|Section4={{Chembox Related
| OtherCompounds = {{unbulleted list|Tetraethylmethane|Tetraethylsilane|Tetraethyltin|Tetraethyllead}}
}}
}}
Tetraethylgermanium (IUPAC name: tetraethylgermane), abbreviated TEG, is an organogermanium compound with the formula (CH3CH2)4Ge. Tetraethylgermanium is an important chemical compound used in vapour deposition of germanium which is in a tetrahedral shape.
Synthesis
Clemens Winkler first reported the compound in 1887 from diethylzinc and germanium tetrachloride, shortly after germanium was discovered in 1887. {{cite journal | author = Clemens Winkler | journal = J. Prak. Chemie | volume = 36 | year = 1887 |pages = 177–209 | title = Mittheilungen über des Germanium. Zweite Abhandlung |doi = 10.1002/prac.18870360119 | url = http://gallica.bnf.fr/ark:/12148/bpt6k90799n/f183.table| accessdate = 2008-08-20}}
References
{{Reflist}}
External links
- Tetraethylgermanium [http://www.sigmaaldrich.com/catalog/search/ProductDetail?ProdNo=401706&Brand=ALDRICH Datasheet commercial supplier]