Thorin (chemistry)
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 470609258
| ImageFile = Thorin.svg
| ImageSize = 244
| ImageName = Structural formula of ((4E)-4-hydrazin-1-ylidene)-thorin
| Name = Thorin
| PIN = Disodium 3-hydroxy-4-[(2-arsonophenyl)diazenyl]naphthalene-2,7-disulfonate
| SystematicName = Disodium 4-[2-(2-arsonophenyl)hydrazin-1-ylidene]-3-oxo-3,4-dihydronaphthalene-2,7-disulfonate
| OtherNames = Disodium 4-[2-(2-arsonophenyl)hydrazin-1-ylidene]-3-oxonaphthalene-2,7-disulfonate
2-(3,6-Disulfo-2-hydroxy-1-naphthylazo)benzenearsonic acid disodium salt
Thoron
Thoronol
|Section1={{Chembox Identifiers
| CASNo = 3688-92-4
| CASNo_Comment = (4E)-4-hydrazin-1-ylidene
| CASNo_Ref = {{cascite|changed|??}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = LFP7CNK4M5
| PubChem = 77269
| PubChem1 = 6537679
| PubChem1_Comment = (4E)-4-hydrazin-1-ylidene
| ChemSpiderID2_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID2 = 4895471
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 5020708
| ChemSpiderID_Comment = (4E)-4-hydrazin-1-ylidene
| EINECS = 222-993-1
| UNNumber = 1557
| Beilstein = 2957648
| SMILES = [Na+].[Na+].O[As](O)(=O)c3ccccc3/N=N/c1c2ccc(cc2cc(c1O)S([O-])(=O)=O)S([O-])(=O)=O
| SMILES1 = [Na+].[Na+].O[As](O)(=O)C1=CC=CC=C1NN=C1C(=O)C(=CC2=C1C=CC(=C2)S([O-])(=O)=O)S([O-])(=O)=O
| StdInChI = 1S/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,18H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| InChI1 = 1/C16H13AsN2O10S2.2Na/c20-16-14(31(27,28)29)8-9-7-10(30(24,25)26)5-6-11(9)15(16)19-18-13-4-2-1-3-12(13)17(21,22)23;;/h1-8,20H,(H2,21,22,23)(H,24,25,26)(H,27,28,29);;/q;2*+1/p-2/b19-18+;;
| StdInChIKey = ZQMPNLOZJUWHSA-UHFFFAOYSA-L
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| InChIKey = DCSRPHQBFSYJNN-GJLVVKPQBS}}
|Section2={{Chembox Properties
| C=16 | H=11 | As=1 | N=2 | O=10 | S=2
| Appearance = Orange-yellow crystals
| MeltingPtC = 300}}
|Section3={{Chembox Hazards
| GHSPictograms = {{GHS06}}{{GHS09}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|301|331|410}}
| PPhrases = {{P-phrases|261|264|270|271|273|301+310|304+340|311|321|330|391|403+233|405|501}}
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0}}
}}
Thorin (also called thoron or thoronol) is an indicator used in the determination of barium, beryllium, lithium, uranium and thorium compounds. Being a compound of arsenic, it is highly toxic.{{cite journal |last1=Haartz |first1=J. C. |last2=Eller |first2=Peter M. |last3=Hornung |first3=Richard W. |title=Critical parameters in the barium perchlorate/Thorin titration of sulfate |journal=Analytical Chemistry |date=1 November 1979 |volume=51 |issue=13 |pages=2293–2295 |doi=10.1021/ac50049a056}}
References
{{Reflist}}
External links
- [http://physchem.ox.ac.uk/MSDS/TH/thorin.html MSDS at Oxford University]
Category:Naphthalenesulfonates
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