Uranium disulfide

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| Section1 = {{Chembox Identifiers

| CASNo = 12039-14-4

| PubChem = 131700999

| StdInChI=1S/2S.U/q2*-2;+4

| StdInChIKey = OYHHCKFHGQELGK-UHFFFAOYSA-N

| SMILES = [S-2].[S-2].[U+4]

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| Section2 = {{Chembox Properties

| Formula = US2

| MolarMass = 302.160 g/mol

| Appearance = Black crystals

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| Section3 = {{Chembox Structure

| Structure_ref =

| CrystalStruct = Tetragonal (α-US2)

| SpaceGroup = P4/ncc (No. 130)

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| LattConst_a = 1029.3 pm

| LattConst_b =

| LattConst_c = 637.4 pm

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Uranium disulfide is an inorganic chemical compound of uranium in oxidation state +4 and sulfur in oxidation state −2. It is radioactive and appears in the form of black crystals.

Uranium disulfide has two allotropic forms: α-uranium disulfide, which is stable above the transition temperature (about 1350 °C) and metastable below it, and β-uranium disulfide which is stable below this temperature. The tetragonal crystal structure of α-US2 is identical to α-USe2.

Uranium disulfide can be synthesized by reduction of gaseous hydrogen sulfide with uranium metal powder at elevated temperatures.

References

{{cite book|title=Handbuch der Anorganischen Chemie|trans-title=Inorganic Chemistry Handbook|lang=de|edition=8th|volume=U: Uran (Suppl. A3)|series=Gmelin|publisher=Springer|year=1981|location=Berlin|first1=Helmut|last1=Assmann|first2=Heinz|last2=Stehle|editor-first1=Karl-Christian|editor-last1=Buschbeck|editor-first2=Cornelius|editor-last2=Keller|number=55|orig-date=Mid-1979|lccn=25-1383|isbn=978-3-662-10276-3|doi=10.1007/978-3-662-10275-6|chapter=Weitere Uranverbindungen als Kernbrennstoffe|trans-chapter=Other uranium compounds as nuclear fuels|pages=210–211}}

{{cite journal|doi=10.1006/jssc.1999.8599|journal=Journal of Solid State Chemistry|volume=150|year=2000|title=Uranium's valency in U3S5|first1=H.|last1=Kohlmann|first2=H. P.|last2=Beck|issue=2 |orig-date=Oct 1, 1999|publisher=Academic|page=339|bibcode=2000JSSCh.150..336K }}

{{cite journal | last1=Noel | first1=H. | last2=Le Marouille | first2=J.Y. | title=Crystal structure and properties of the uranium chalcogenides α-US2 and α-USe2 | journal=Journal of Solid State Chemistry | publisher=Elsevier BV | volume=52 | issue=3 | year=1984 | issn=0022-4596 | doi=10.1016/0022-4596(84)90001-x | pages=197–202}}

{{cite journal | title = Dimorphism of the uranium disulfide, US2 | last1 = Picon | first1 = Marius | last2 = Flahaut | first2 = Jean | journal = Compt. Rend. | date = 1953 | volume = 237 | pages = 808–810 }}

{{Inorganic-compound-stub}}

{{Uranium compounds}}

{{Sulfides}}

Category:Uranium(IV) compounds

Category:Sulfides

Category:Dichalcogenides