ammonium iodide
{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 470456251
| Name = Ammonium iodide
| ImageFileL1 = Ammonium.svg
| ImageSizeL1 = 90px
| ImageNameL1 = The ammonium cation
| ImageFileR1 = I-.svg
| ImageSizeR1 = 20px
| ImageNameR1 = The iodide anion
| ImageFile2 = Ammonium-iodide-3D-balls.png
| ImageSize2 = 180px
| ImageName2 = ball-and-stick model of an ammonium cation (left) and an iodide anion (right)
| ImageName = Ammonium iodide
|Section1={{Chembox Identifiers
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = OZ8F027LDH
| InChI = 1/HI.H3N/h1H;1H3
| SMILES = [I-].[NH4+]
| InChIKey = UKFWSNCTAHXBQN-UHFFFAOYAU
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/HI.H3N/h1H;1H3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = UKFWSNCTAHXBQN-UHFFFAOYSA-N
| CASNo = 12027-06-4
| CASNo_Ref = {{cascite|correct|CAS}}
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID =23785
| PubChem = 25487
}}
|Section2={{Chembox Properties
| Formula = NH4I
| MolarMass = 144.94 g/mol
| Appearance = White crystalline powder
| Density = 2.51 g/cm3
| Solubility = 155 g/100 mL (0 °C)
172 g/100 mL (20 °C)
250 g/100 mL (100 °C)
| MeltingPtC = 551
| MeltingPt_notes = (sublimes)
| BoilingPtC = 235
| BoilingPt_notes = (in vacuum)
| MagSus = {{val|-66.0e-6|u=cm3/mol}}
}}
|Section7={{Chembox Hazards
| ExternalSDS =
| MainHazards =
| NFPA-H = 2
| NFPA-F = 0
| NFPA-R = 0
| FlashPt = Non-flammable
}}
|Section8={{Chembox Related
| OtherAnions = Ammonium fluoride
Ammonium chloride
Ammonium bromide
| OtherCations = Sodium iodide
Potassium iodide
Phosphonium iodide
| OtherCompounds =
}}
}}
Ammonium iodide is the inorganic compound with the formula NH4I. A white solid. It is an ionic compound, although impure samples appear yellow. This salt consists of ammonium cation and an iodide anion.Holleman, A. F.; Wiberg, E. Inorganic Chemistry Academic Press: San Diego, 2001. {{ISBN|0-12-352651-5}}. It can be prepared by the action of hydroiodic acid on ammonia. It is easily soluble in water, from which it crystallizes in cubes. It is also soluble in ethanol. Ammonium iodide in aqueous solutions are observed as acidic and display elevated vapor pressures at high temperatures{{Cite book |url=https://onlinelibrary.wiley.com/doi/book/10.1002/0471238961 |title=Kirk-Othmer Encyclopedia of Chemical Technology |date=2001-01-26 |publisher=Wiley |isbn=978-0-471-48494-3 |editor-last=Kirk-Othmer |edition=1 |language=en |doi=10.1002/0471238961.0113131523051920.a01.pub2}}
Preparation
Uses
Ammonium iodide is used as dietary supplement to treat iodine deficiency.{{Cite web |title=Ammonium Iodide: Benefits, Risks, and Safety in Dietary Supplements |url=https://www.digicomply.com/dietary-supplements-database/ammonium-iodide |access-date=2023-11-21 |website=www.digicomply.com |language=en}}
Properties and Reactions
Ammonium iodide has recently been used in many research studies and experiments.
Vinyl sulfones have been prepared using ammonium iodide,.{{Cite journal |last1=Gao |first1=Xiaofang |last2=Pan |first2=Xiaojun |last3=Gao |first3=Jian |last4=Huang |first4=Huawen |last5=Yuan |first5=Gaoqing |last6=Li |first6=Yingwei |date=2015 |title=Ammonium iodide-induced sulfonylation of alkenes with DMSO and water toward the synthesis of vinyl methyl sulfones |url=https://pubs.rsc.org/en/content/articlelanding/2015/cc/c4cc07606k |journal=Chemical Communications |language=en |volume=51 |issue=1 |pages=210–212 |doi=10.1039/C4CC07606K|pmid=25406694 |url-access=subscription }}
Organic reactions are not synthesized with organic solvents due to their increasing detrimental effects on the human body and ecosystem.{{Cite journal |last1=Kulkarni |first1=Pramod |last2=Kondhare |first2=Dasharath |last3=Varala |first3=Ravi |last4=Zubaidha |first4=Pudukulathan |date=2013 |title=Cyclization of 2′-hydroxychalcones to flavones using ammonium iodide as an iodine source: An eco-friendly approach |journal=Journal of the Serbian Chemical Society |volume=78 |issue=7 |pages=909–916 |doi=10.2298/jsc120901119k |issn=0352-5139|doi-access=free }} Many chemists have altered organic reactions to exclude solvents in order to have successful sustainable syntheses. A report was presented on an organic synthesis for the iodination of ketones and aromatic compounds using ammonium iodide and H2O2 (hydrogen peroxide). This resulted in the products' high yields, which were gathered more efficiently, in a shorter duration compared to the use of the abrasive compound: molecular iodine
References
{{reflist}}
{{Ammonium salts}}
{{iodides}}