ammonium oxalate

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| verifiedrevid = 457442161

| ImageFile = Ammonium oxalate.svg

| ImageSize = 200px

| IUPACName = Ammonium oxalate

| OtherNames = Diammonium oxalate

| SystematicName = Ammonium ethanedioate

| Section1 = {{Chembox Identifiers

| CASNo = 1113-38-8

| CASNo_Ref = {{cascite|correct|CAS}}

| CASNo1 = 6009-70-7

| CASNo1_Ref = {{cascite|correct|CAS}}

| CASNo1_Comment = (monohydrate)

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = 0PB8MO5U0H

| UNII1_Ref = {{fdacite|correct|FDA}}

| UNII1 = L4MP14OB48

| UNII1_Comment = (monohydrate)

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = VBIXEXWLHSRNKB-UHFFFAOYSA-N

| PubChem = 14213

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 13577

| ChEBI_Ref = {{ebicite|changed|EBI}}

| ChEBI = 91241

| SMILES = [O-]C(=O)C([O-])=O.[NH4+].[NH4+]

| InChI = InChI=1S/C2H2O4.2H3N/c3-1(4)2(5)6;;/h(H,3,4)(H,5,6);2*1H3

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| Section2 = {{Chembox Properties

| Formula = {{chem2|[NH4]2C2O4}}

| C=2|H=8|N=2|O=4

| Appearance = Colorless or white crystalline solid

| Density = 1.5 g/cm3{{cite book |author1=John Rumble |title=CRC Handbook of Chemistry and Physics |date=June 18, 2018 |publisher=CRC Press |isbn=978-1138561632 |pages=4–41|edition=99th |language=English}}

| MeltingPt = 70 C (158 F, 343.15 K)

| BoilingPt =

| Solubility = 5.20 g/(100 ml) (25 °C)

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| HPhrases = {{H-phrases|302|312|319}}

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Ammonium oxalate is a chemical compound with the chemical formula {{chem2|[NH4]2C2O4|auto=1}}. Its formula is often written as {{chem2|(NH4)2C2O4}} or {{chem2|(COONH4)2}}. It is an ammonium salt of oxalic acid. It consists of ammonium cations ({{chem2|[NH4]+}}) and oxalate anions ({{chem2|C2O4(2−)}}). The structure of ammonium oxalate is {{chem2|([NH4]+)2[C2O4](2−)}}. Ammonium oxalate sometimes comes as a monohydrate ({{chem2|[NH4]2C2O4*H2O}}). It is a colorless or white salt under standard conditions and is odorless and non-volatile. It occurs in many plants and vegetables.

Vertebrate

It is produced in the body of vertebrates by metabolism of glyoxylic acid or ascorbic acid. It is not metabolized but excreted in the urine.National Center for Biotechnology Information. PubChem Compound Database; [https://pubchem.ncbi.nlm.nih.gov/compound/14213 CID 14213] (accessed 15 November 2016). It is a constituent of some types of kidney stone.The International Pharmacopoeia, p.1292, Volume 1, World Health Organization, 2006 {{ISBN|92-4-156301-X}}.N G Coley, [https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1033981/ "The collateral sciences in the work of Golding Bird (1814–1854)"], Medical History, iss.4, vol.13, October 1969, pp.372. It is also found in guano.

Mineralogy

Oxammite is a natural mineral form of ammonium oxalate. This mineral is extremely rare. It is an organic mineral derived from guano.{{cite web |url=http://www.mindat.org/ |title=Home |website=mindat.org}}

Chemistry

Ammonium oxalate is used as an analytical reagent and general reducing agent. It and other oxalates are used as anticoagulants, to preserve blood outside the body.{{citation needed|date=January 2022}}

= Earth sciences =

Acid ammonium oxalate (ammonium oxalate acidified to pH 3 with oxalic acid) is commonly employed in soil chemical analysis to extract iron and aluminium from poorly-crystalline minerals (such as ferrihydrite), iron(II)-bearing minerals (such as magnetite) and organic matter.{{cite book |last1=Rayment |first1=George |last2=Lyons |first2=David |title=Soil Chemical Methods - Australasia |date=2011 |publisher=CSIRO Publishing |isbn=9780643101364}}{{page needed|date=January 2020}}

References

{{reflist}}

{{Ammonium salts}}

{{Oxalates}}

Category:Ammonium compounds

Category:Anticoagulants

Category:Oxalates