barium thiocyanate

{{short description|Water-soluble salt}}

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| Reference = {{cite web|url=https://www.sigmaaldrich.com/catalog/product/aldrich/339156?lang=en®ion=US |title=Barium thiocyanate | 336879-43-7 |publisher=Sigma-Aldrich |date=2012-09-14 |accessdate=2021-01-20}}{{cite web|url=https://www.chemicalbook.com/ChemicalProductProperty_EN_CB6489843.htm |title=BARIUM THIOCYANATE | 2092-17-3 |publisher=Chemicalbook.com |date=2020-07-03 |accessdate=2021-01-20}}

| Name = Barium thiocyanate

| IUPACName = Barium thiocyanate

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| OtherNames = {{Unbulleted list

| Barium sulfur cyanide

| Barium(II) thiocyanate

| Barium sulfocyanide

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| Section1 = {{Chembox Identifiers

| index1_label=trihydrate

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| CASNo1 = 68016-36-4

| CASNo = 2092-17-3

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| ChemSpiderID = 144591

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| EC_number = 218-245-9

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| PubChem = 164928

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| UNII = 3412AZ8I1A

| StdInChI=1S/2CHNS.Ba/c2*2-1-3;/h2*3H;/q;;+2/p-2

| StdInChIKey = LKZCRGABYQYUFX-UHFFFAOYSA-L

| SMILES = C(#N)[S-].C(#N)[S-].[Ba+2]

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| Appearance = White crystals

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| Formula = Ba(SCN)2

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| MolarMass = 253.49 g/mol

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| Solubility = 62.63 g/100 ml (25°C)

| SolubleOther = Soluble in acetone, methanol, and ethanol

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| HPhrases = {{H-phrases|301|312|315|319|332|335}}

| PPhrases = {{P-phrases|261|280|302+352|304+340}}

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Barium thiocyanate refers to salts of the formula {{chem2|Ba(SCN)2.xH2O}}. Both an anhydrous salt and a trihydrate are known. The anhydrous salt is hygroscopic. The trihydrate is soluble in most alcohols but insoluble in simple alkanes. Barium thiocyanate is used in dyeing textiles and in some photographic solutions. But because of its toxicity, it has limited uses.{{cite web|url=http://cameo.mfa.org/wiki/Barium_thiocyanate |title=Barium thiocyanate - CAMEO |publisher=Cameo.mfa.org |date=2016-04-29 |accessdate=2021-01-20}}

Preparation and structure

Barium thiocyanate is prepared by mixing barium hydroxide and ammonium thiocyanate in water. {{cite book |last1=Herstein |first1=Karl M. |title=Inorganic Syntheses |volume=3 |date=1950 |pages=24–26 |chapter-url=https://onlinelibrary.wiley.com/doi=10.1002/9780470132340.ch5|chapter=Barium Thiocyanate|doi=10.1002/9780470132340.ch5 |isbn=978-0-470-13162-6 }}

:2 NH4SCN + Ba(OH)2 → Ba(SCN)2 + 2 NH3 + 2 H2O

According to X-ray crystallography, the anhydrous salt is a coordination polymer. The Ba2+ ions are each bonded to eight thiocyanate anions, with four Ba-S and four Ba-N bonds. The motif is reminiscent of the fluorite structure.{{cite journal |doi=10.1021/acs.inorgchem.4c00920 |title=Inorganic Metal Thiocyanates |date=2024 |last1=Cliffe |first1=Matthew J. |journal=Inorganic Chemistry |volume=63 |issue=29 |pages=13137–13156 |pmid=38980309 |pmc=11271006 }} Strontium thiocyanate, calcium thiocyanate, and lead thiocyanate adopt the same structure.

References

{{reflist}}

{{Barium compounds}}

Category:Thiocyanates

Category:Barium compounds

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