beryllium carbide
{{Refimprove|date=October 2010}}
{{Chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 486406637
|ImageFile=Sodium-oxide-unit-cell-3D-balls-B.png
| IUPACName = Beryllium carbide
| SystematicName =
| OtherNames = Beryllium methanide
| Section1 = {{Chembox Identifiers
| CASNo = 506-66-1
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = F5D2F26ONX
| PubChem = 68173
| ChemSpiderID = 61480
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| EINECS = 208-050-7
| SMILES = [Be]=C=[Be]
| StdInChI = 1S/C.2Be
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = UQVOJETYKFAIRZ-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|??}}
}}
| Section2 = {{Chembox Properties
| Formula = {{chem2|Be2C}}
| C=1 | Be=2
| Appearance = Yellow to red crystals
| Odor = odorless
| Density = 1.90 g/cm3 (at 15 °C)
| MeltingPtC = 2100
| MeltingPt_notes = (decomposes)
| Solubility = decomposes
}}
| Section7 = {{Chembox Structure
| Coordination =
| CrystalStruct = cubic
}}
| Section8 = {{Chembox Hazards
| NFPA-H =
| NFPA-F =
| NFPA-R =
| NFPA-S =
| REL = Ca C 0.0005 mg/m3 (as Be){{PGCH|0054}}
| PEL = TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)
}}
| Section9 = {{Chembox Related
| OtherCompounds = {{ubl|Boron carbide|Aluminium carbide|Silicon carbide|Carbon dioxide|Carbon diselenide|Carbon disulfide}}
}}
}}
Beryllium carbide is a chemical compound with the chemical formula {{chem2|Be2C|auto=1}}. It is a metal carbide.{{cite web |title=Beryllium Carbide |url=https://www.americanelements.com/beryllium-carbide-506-66-1 |website=American Elements |access-date=25 June 2023}} Similar to diamond, it is a very hard compound. It is used in nuclear reactors as a core material.
Preparation
Beryllium carbide is prepared by heating the elements beryllium and carbon at elevated temperatures (above 950°C). It also may be prepared by reduction of beryllium oxide with carbon at a temperature above 1,500°C:
:{{chem2|2 BeO + 3 C → Be2C + 2 CO}}
Beryllium carbide decomposes very slowly in water and forms methane gas:
:{{chem2|Be2C + 2 H2O → 2 BeO + CH4}}
The rate of decomposition is faster in mineral acids with evolution of methane.
:{{chem2|Be2C + 4 H+ → 2 Be(2+) + CH4}}
In hot concentrated alkali the reaction is very rapid, forming alkali metal beryllates and methane:
:{{chem2|Be2C + 4 OH− → 2 BeO2(2−) + CH4}}
See also
References
{{reflist}}
External links
- [https://web.archive.org/web/20110901040139/http://www.espimetals.com/index.php/msds/415-Beryllium%20Carbide MATERIAL SAFETY DATA SHEET]
- [http://www.britannica.com/EBchecked/topic/62944/beryllium-carbide Encyclopædia Britannica]
- [http://scitation.aip.org/getabs/servlet/GetabsServlet?prog=normal&id=JESOAN000099000003000115000001&idtype=cvips&gifs=yes Electrochemical Society article]
- [http://pubs.acs.org/doi/abs/10.1021/j150574a033 ASC website]
- [http://www.nature.com/nature/journal/v186/n4723/abs/186466a0.html article in Nature]
- [https://web.archive.org/web/20090814125009/http://nvl.nist.gov/pub/nistpubs/jres/048/3/V48.N03.A06.pdf NIST government website]
{{Beryllium compounds}}
{{Carbides}}
{{DEFAULTSORT:Beryllium Carbide}}
Category:Fluorite crystal structure
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