beryllium carbide

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| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 486406637

|ImageFile=Sodium-oxide-unit-cell-3D-balls-B.png

| IUPACName = Beryllium carbide

| SystematicName =

| OtherNames = Beryllium methanide

| Section1 = {{Chembox Identifiers

| CASNo = 506-66-1

| CASNo_Ref = {{cascite|correct|CAS}}

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = F5D2F26ONX

| PubChem = 68173

| ChemSpiderID = 61480

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| EINECS = 208-050-7

| SMILES = [Be]=C=[Be]

| StdInChI = 1S/C.2Be

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = UQVOJETYKFAIRZ-UHFFFAOYSA-N

| StdInChIKey_Ref = {{stdinchicite|correct|??}}

}}

| Section2 = {{Chembox Properties

| Formula = {{chem2|Be2C}}

| C=1 | Be=2

| Appearance = Yellow to red crystals

| Odor = odorless

| Density = 1.90 g/cm3 (at 15 °C)

| MeltingPtC = 2100

| MeltingPt_notes = (decomposes)

| Solubility = decomposes

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| Section7 = {{Chembox Structure

| Coordination =

| CrystalStruct = cubic

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| Section8 = {{Chembox Hazards

| NFPA-H =

| NFPA-F =

| NFPA-R =

| NFPA-S =

| REL = Ca C 0.0005 mg/m3 (as Be){{PGCH|0054}}

| PEL = TWA 0.002 mg/m3
C 0.005 mg/m3 (30 minutes), with a maximum peak of 0.025 mg/m3 (as Be)

| IDLH = Ca [4 mg/m3 (as Be)]

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| Section9 = {{Chembox Related

| OtherCompounds = {{ubl|Boron carbide|Aluminium carbide|Silicon carbide|Carbon dioxide|Carbon diselenide|Carbon disulfide}}

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Beryllium carbide is a chemical compound with the chemical formula {{chem2|Be2C|auto=1}}. It is a metal carbide.{{cite web |title=Beryllium Carbide |url=https://www.americanelements.com/beryllium-carbide-506-66-1 |website=American Elements |access-date=25 June 2023}} Similar to diamond, it is a very hard compound. It is used in nuclear reactors as a core material.

Preparation

Beryllium carbide is prepared by heating the elements beryllium and carbon at elevated temperatures (above 950°C). It also may be prepared by reduction of beryllium oxide with carbon at a temperature above 1,500°C:

:{{chem2|2 BeO + 3 C → Be2C + 2 CO}}

Beryllium carbide decomposes very slowly in water and forms methane gas:

:{{chem2|Be2C + 2 H2O → 2 BeO + CH4}}

The rate of decomposition is faster in mineral acids with evolution of methane.

:{{chem2|Be2C + 4 H+ → 2 Be(2+) + CH4}}

In hot concentrated alkali the reaction is very rapid, forming alkali metal beryllates and methane:

:{{chem2|Be2C + 4 OH− → 2 BeO2(2−) + CH4}}

See also

References

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