borate nitrate

Borate nitrates are mixed anion compounds containing separate borate and nitrate anions.

List

class="wikitable"

!

!chem

!mw

!crystal system

!space group

!unit cell Å

!volume

!density

!comment

!references

|Na3(NO3)[B6O10]

|

|

|

|

|

|

|

|{{Cite journal|last1=Ortner|first1=Teresa S.|last2=Schildhammer|first2=Daniel|last3=Tribus|first3=Martina|last4=Joachim|first4=Bastian|last5=Huppertz|first5=Hubert|date=2017-03-01|title=Synthesis and characterization of the alkali borate-nitrates Na3–x Kx[B6O10]NO3 (x=0.5, 0.6, 0.7)|url=http://www.degruyter.com/view/j/znb.2017.72.issue-3/znb-2016-0242/znb-2016-0242.xml|journal=Zeitschrift für Naturforschung B|volume=72|issue=3|pages=215–223|doi=10.1515/znb-2016-0242|s2cid=99165997|issn=1865-7117}}

|K3B6O10NO3

|

|

|

|

|

|

|

|{{Cite journal|last1=Zhang|first1=Qiqi|last2=Zhang|first2=Fangfang|last3=Li|first3=Fuming|last4=Han|first4=Shujuan|last5=Yang|first5=Zhihua|last6=Pan|first6=Shilie|date=2021-02-13|title=M3B6O10NO3 (M = K, Rb): Two new alkali metal borate-nitrates with noncentrosymmetric structures|url=https://onlinelibrary.wiley.com/doi/10.1002/ejic.202001167|journal=European Journal of Inorganic Chemistry|volume=2021|issue=13|language=en|pages=1297–1304|doi=10.1002/ejic.202001167|s2cid=233784768|issn=1434-1948}}

|K3Na[B6O9(OH)3]NO3

|

|

|Pnnm

|a=13.208, b=9.107, c=12.325 Z=4

|

|

|

|{{Cite journal|last1=Ortner|first1=Teresa S.|last2=Wurst|first2=Klaus|last3=Perfler|first3=Lukas|last4=Tribus|first4=Martina|last5=Huppertz|first5=Hubert|date=January 2015|title=Hydrothermal synthesis and characterization of the first mixed alkali borate-nitrate K3Na[B6O9(OH)3]NO3 |journal=Journal of Solid State Chemistry|language=en|volume=221|pages=66–72|doi=10.1016/j.jssc.2014.09.016|bibcode=2015JSSCh.221...66O}}

|Co3B7O13NO3

|

|

|

|

|

|

|

|{{Cite journal|last1=Bither|first1=Tom A.|last2=Young|first2=Howard S.|date=1974-08-01|title=Nitrato- and fluoroboracites M3B7O13NO3 and M3B7O13F|url=https://dx.doi.org/10.1016%2F0022-4596%2874%2990039-5|journal=Journal of Solid State Chemistry|language=en|volume=10|issue=4|pages=302–311|doi=10.1016/0022-4596(74)90039-5|bibcode=1974JSSCh..10..302B|issn=0022-4596}}

|[Co(H2O)6](NO3)2·[Co{B3O3(OH)4}2(H2O)4]·2H2O

|

|

|

|

|

|

|

|{{Cite journal|last1=Liu|first1=Ying|last2=Deng|first2=Jun-Xia|last3=Pan|first3=Chun-Yang|date=2020-05-04|title=Synthesis and Structural Manipulation of a Polyanionic Zincoborate [Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O by the Molten Salt Method and its Potential Application as a Flame Retardant|url=http://link.springer.com/10.1007/s10876-020-01806-7|journal=Journal of Cluster Science|volume=32|issue=2|pages=469–477|language=en|doi=10.1007/s10876-020-01806-7|s2cid=218495402|issn=1040-7278}}

|[Ni(H2O)6](NO3)2·[Ni{B3O3(OH)4}2(H2O)4]·2H2O

|

|

|

|

|

|

|

|

|Ni3B7O13NO3

|

|

|

|

|

|

|

|

|K7Ni[B18O24(OH)9](NO3)6· (H3BO3)

|1497.96

|trigonal

|R{{overbar|3}}

|a=12.2229 c=54.784 Z=6

|7088

|2.11

|green

|{{Cite journal|last1=Zoller|first1=Michael|last2=Wurst|first2=Klaus|last3=Huppertz|first3=Hubert|date=2019-10-25|title=Synthesis of the first nickel borate nitrate K7Ni[B18O24(OH)9](NO3)6· (H3BO3)|journal=Zeitschrift für Naturforschung B|volume=74|issue=10|pages=757–764|doi=10.1515/znb-2019-0126|s2cid=202872565|issn=1865-7117|doi-access=free}}{{open access}} CC-BY can use images

|Cu3B7O13NO3

|

|

|

|

|

|

|

|

|Zn3B7O13NO3

|

|

|

|

|

|

|

|

|[Zn(H2O)6](NO3)2·[Zn{B3O3(OH)4}2(H2O)4]·2H2O

|

|monoclinic

|P21/c

|a = 11.282, b = 6.5374, c = 17.668, β = 100.981°

|

|

|

|

|Rb3(NO3)[B6O10]

|

|

|

|

|

|

|

|

|Ag12(B9O18)(NO3)3

|

|hexagonal

|P63/m

|a = 11.2896 c = 11.6693

|

|

|

|{{Cite journal |last1=Volkov |first1=Sergey N. |last2=Charkin |first2=Dmitri O. |last3=Marsiy |first3=Ivan A. |last4=Banaru |first4=Daria A. |last5=Povolotskiy |first5=Alexey V. |last6=Gosteva |first6=Alevtina N. |last7=Yu. Arsent’ev |first7=Maxim |last8=Krzhizhanovskaya |first8=Maria G. |last9=Ugolkov |first9=Valery L. |last10=Savchenko |first10=Yevgeny E. |last11=Kireev |first11=Vadim E. |last12=Aksenov |first12=Sergey M. |last13=Bubnova |first13=Rimma S. |date=October 2024 |title=The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(–) |url=https://linkinghub.elsevier.com/retrieve/pii/S0022024824002720 |journal=Journal of Crystal Growth |language=en |volume=644 |pages=127837 |doi=10.1016/j.jcrysgro.2024.127837}}

|Cd3B7O13NO3

|

|

|

|

|

|

|

|

|La[B5O8(OH)]NO3

|

|

|

|

|

|

|

|

|La[B5O8(OH)]NO3·2H2O

|

|monoclinic

|P21/n

|a=6.540, b=15.550, c=10.672, β=90.44° and Z=4

|

|

|

|{{Cite journal|last1=Zhao|first1=Biao-Chun|last2=Sun|first2=Wei|last3=Ren|first3=Wei-Jian|last4=Huang|first4=Ya-Xi|last5=Li|first5=Zucheng|last6=Pan|first6=Yuanming|last7=Mi|first7=Jin-Xiao|date=October 2013|title=Hygroscopic La[B5O8(OH)]NO3·2H2O: Insight into the evolution of borate fundamental building blocks |journal=Journal of Solid State Chemistry|language=en|volume=206|pages=91–98|doi=10.1016/j.jssc.2013.07.032|bibcode=2013JSSCh.206...91Z}}

cerium(III) aquahydroxidooctaoxidopentaborate nitrate dihydrate

|Ce[B5O8(OH)(H2O)]NO3·2H2O

|455.24

|monoclinic

|P21/n

|a=6.444 b=15.572 c=10.745 β=90.395 Z=4

|1078.2

|2.904

|colourless

|{{Cite journal|last1=Sun|first1=Wei|last2=Zhu|first2=Teng-Teng|last3=Zhao|first3=Biao-Chun|last4=Huang|first4=Ya-Xi|last5=Mi|first5=Jin-Xiao|date=2012-05-15|title=Redetermination of Ce[B 5 O 8 (OH)(H 2 O)]NO 3 ·2H 2 O|url=http://scripts.iucr.org/cgi-bin/paper?S1600536812016169|journal=Acta Crystallographica Section E|volume=68|issue=5|pages=i33–i34|doi=10.1107/S1600536812016169|issn=1600-5368|pmc=3344287|pmid=22590053}}

|Pr[B5O8(OH)(H2O)x]NO3·2H2O

|

|monoclinic

|P21/n

|a=6.419, b=15.518, c=10.684, with β=90.54° Z=4

|1064.3

|

|

|{{Cite journal|last1=Ortner|first1=Teresa S.|last2=Huppertz|first2=Hubert|date=2017-09-26|title=Hydrothermal synthesis and characterization of the praseodymium borate-nitrate Pr[B5O8(OH)(H2O)0.87]NO3·2H2O|url=http://www.degruyter.com/view/j/znb.2017.72.issue-9/znb-2017-0121/znb-2017-0121.xml|journal=Zeitschrift für Naturforschung B|volume=72|issue=9|pages=677–685|doi=10.1515/znb-2017-0121|s2cid=103777780|issn=1865-7117}}

|Pr7(BO3)3(NO3)N3O

|

|hexagonal

|P63

|a=10.6834 c=6.6752 Z=2

|

|6.457

|green; contains N(OBO3)3 clusters, oxide and nitride

|{{Cite journal|last1=Katrych|first1=Sergiy|last2=Arakcheeva|first2=Alla|last3=Sienkiewicz|first3=Andrzej|last4=Forró|first4=László|last5=Ivšić|first5=Trpimir|date=2020-12-15|title=High-Pressure Synthesis of Rare-Earth Borate-Nitrate Crystals for Second Harmonic Generation|url=https://pubs.acs.org/doi/10.1021/acs.inorgchem.0c02909|journal=Inorganic Chemistry|volume=60|issue=1|language=en|pages=286–291|doi=10.1021/acs.inorgchem.0c02909|pmid=33320648|s2cid=229283287|issn=0020-1669}}

|Nd7(BO3)3(NO3)N3O

|

|hexagonal

|P63

|a=10.6446 c=6.6339 Z=2

|

|6.664

|purplish-blue;contains N(OBO3)3 clusters oxide, and nitride;SHG

|

|Nd[B5O8(OH)(H2O)x]NO3·2H2O

|

|

|P21/n

|a = 6.4285, b = 15.5258, c = 10.7052, β = 90.39°

|1068.44

|

|

|{{Cite journal|last1=Ortner|first1=Teresa S.|last2=Wurst|first2=Klaus|last3=Joachim|first3=Bastian|last4=Huppertz|first4=Hubert|date=August 2016|title=Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]: Syntheses, Structure Elucidation, and Characterization of the Borate-Nitrates RE[B 5 O 8 (OH)(H 2 O) x ]NO 3 ·2H 2 O [RE = Nd ( x = 0.85), Sm ( x = 0)]|url=http://doi.wiley.com/10.1002/ejic.201600480|journal=European Journal of Inorganic Chemistry|language=en|volume=2016|issue=22|pages=3659–3665|doi=10.1002/ejic.201600480}}

|Sm[B5O8(OH)(H2O)x]NO3·2H2O

|

|

|P21/n

|a = 6.4409, b = 15.4199, c = 10.5097, β = 90.33°

|1043.79

|

|

|

|Lu2B2O5(NO3)2·2H2O

|

|triclinic

|P1

|a=7.8952, b=9.8862, c=14.6033, α=90.83, β=101.75, γ=110.02° Z=4

|

|

|

|{{Cite journal|last1=Ortner|first1=Teresa S.|last2=Wurst|first2=Klaus|last3=Hejny|first3=Clivia|last4=Huppertz|first4=Hubert|date=January 2016|title=Hydrothermal synthesis and characterization of the lutetium borate–nitrate Lu2B2O5(NO3)2·2H2O |journal=Journal of Solid State Chemistry|language=en|volume=233|pages=329–334|doi=10.1016/j.jssc.2015.11.005|bibcode=2016JSSCh.233..329O}}

|Pb2(BO3)(NO3)

|535.20

|hexagonal

|P63mc

|a=5.0731 c=13.040 Z=2

|290.64

|6.116

|colourless SHG 9×KDP

|{{Cite journal|last1=Song|first1=Jun-Ling|last2=Hu|first2=Chun-Li|last3=Xu|first3=Xiang|last4=Kong|first4=Fang|last5=Mao|first5=Jiang-Gao|date=2015-03-16|title=A Facile Synthetic Route to a New SHG Material with Two Types of Parallel π-Conjugated Planar Triangular Units|url=http://doi.wiley.com/10.1002/ange.201412344|journal=Angewandte Chemie|language=en|volume=127|issue=12|pages=3750–3753|doi=10.1002/ange.201412344|bibcode=2015AngCh.127.3750S}}

|[Pb3(B3O7)](NO3)

|828.01

|

|Pnma

|a=10.3481 b=7.8908 c=11.2123 Z=4

|914.54

|6.007

|colourless

|{{Cite journal|last1=Song|first1=Jun-Ling|last2=Hu|first2=Chun-Li|last3=Xu|first3=Xiang|last4=Kong|first4=Fang|last5=Mao|first5=Jiang-Gao|date=2013-08-05|title=Pb 2 B 3 O 5.5 (OH) 2 and [Pb 3 (B 3 O 7 )](NO 3 ): Facile Syntheses of New Lead(II) Borates by Simply Changing the pH Values of the Reaction Systems|url=https://pubs.acs.org/doi/10.1021/ic401175r|journal=Inorganic Chemistry|language=en|volume=52|issue=15|pages=8979–8986|doi=10.1021/ic401175r|pmid=23834222|issn=0020-1669}}

References