calcium monosilicide
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| verifiedrevid = 428831186
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|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo = 12013-55-7
| PubChem = 6336872
| ChemSpiderID = 4891865
| EINECS = 234-587-1
| UNNumber = 1405
| StdInChI=1S/Ca.Si
| StdInChIKey = OSMSIOKMMFKNIL-UHFFFAOYSA-N
| SMILES = [Si]=[Ca]
}}
|Section2={{Chembox Properties
| Formula = CaSi
| MolarMass = 68.164 g/mol{{RubberBible92nd|page=4.55}}
| Appearance =
| MeltingPtC = 1324
| BoilingPt =
| Solubility =
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| Section3 = {{Chembox Structure
| CrystalStruct = Orthorhombic, oS8,
| SpaceGroup = Cmcm, No. 63
| PointGroup =
| LattConst_a = 0.4545 nm
| LattConst_b = 1.0728 nm
| LattConst_c = 0.389 nm
| LattConst_alpha =
| LattConst_beta =
| LattConst_gamma =
| LattConst_ref =
| LattConst_Comment =
| UnitCellVolume =
| UnitCellFormulas = 4
| Coordination =
| MolShape =
| OrbitalHybridisation =
| Dipole =
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| Section4 = {{Chembox Hazards
| MainHazards = Flammable gas with water
| GHSPictograms = {{GHS02}}
| GHSSignalWord = Warning
| HPhrases = {{H-phrases|261}}
| PPhrases = {{P-phrases|231+232|280|370+378|402+404|501}}
}}
}}
Calcium monosilicide (CaSi) is an inorganic compound, a silicide of calcium. It can be prepared by reacting elemental calcium and silicon at temperatures above 1000 °C.Brauer, Georg (1975) Handbuch der Präparativen Anorganischen Chemie. Stuttgart. Vol. 1. p. 933. {{ISBN|3-432-02328-6}}. It is a Zintl phase, where silicon has oxidation state −2 and covalence 2.