calcium monosilicide

{{chembox

| Watchedfields = changed

| verifiedrevid = 428831186

| ImageFile =

| ImageSize =

| ImageCaption =

| IUPACName =

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo_Ref = {{cascite|correct|??}}

| CASNo = 12013-55-7

| PubChem = 6336872

| ChemSpiderID = 4891865

| EINECS = 234-587-1

| UNNumber = 1405

| StdInChI=1S/Ca.Si

| StdInChIKey = OSMSIOKMMFKNIL-UHFFFAOYSA-N

| SMILES = [Si]=[Ca]

}}

|Section2={{Chembox Properties

| Formula = CaSi

| MolarMass = 68.164 g/mol{{RubberBible92nd|page=4.55}}

| Appearance =

| Density = 2.39 g/cm3

| MeltingPtC = 1324

| MeltingPt_ref =

| BoilingPt =

| Solubility =

}}

| Section3 = {{Chembox Structure

| Structure_ref ={{cite journal|doi=10.1107/S0365110X67001793|title=Alkaline earth silicides, germanides and stannides with CrB structure type|journal=Acta Crystallographica|volume=22|issue=6|pages=919|year=1967|last1=Rieger|first1=W|last2=Parthé|first2=E|doi-access=free}}

| CrystalStruct = Orthorhombic, oS8,

| SpaceGroup = Cmcm, No. 63

| PointGroup =

| LattConst_a = 0.4545 nm

| LattConst_b = 1.0728 nm

| LattConst_c = 0.389 nm

| LattConst_alpha =

| LattConst_beta =

| LattConst_gamma =

| LattConst_ref =

| LattConst_Comment =

| UnitCellVolume =

| UnitCellFormulas = 4

| Coordination =

| MolShape =

| OrbitalHybridisation =

| Dipole =

}}

| Section4 = {{Chembox Hazards

| MainHazards = Flammable gas with water

| GHSPictograms = {{GHS02}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|261}}

| PPhrases = {{P-phrases|231+232|280|370+378|402+404|501}}

}}

}}

Calcium monosilicide (CaSi) is an inorganic compound, a silicide of calcium. It can be prepared by reacting elemental calcium and silicon at temperatures above 1000 °C.Brauer, Georg (1975) Handbuch der Präparativen Anorganischen Chemie. Stuttgart. Vol. 1. p. 933. {{ISBN|3-432-02328-6}}. It is a Zintl phase, where silicon has oxidation state −2 and covalence 2.

References