calcium permanganate
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| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 472234763
| Name = Calcium permanganate
| ImageFile = CalciumPermanganate.jpg
| ImageSize =
| IUPACName = Calcium dipermanganate{{Cite web|url=http://www.chemindustry.com/chemicals/1005888.html|title=CALCIUM PERMANGANATE, CAS Number: 10118-76-0|access-date=2009-03-11|archive-date=2017-12-22|archive-url=https://web.archive.org/web/20171222052058/http://www.chemindustry.com/chemicals/1005888.html|url-status=dead}}
| OtherNames =
|Section1={{Chembox Identifiers
| CASNo = 10118-76-0
| CASNo_Ref = {{cascite|correct|??}}
| UNII_Ref = {{fdacite|changed|FDA}}
| UNII = 720Y4E8F5H
| PubChem = 24959
| RTECS = EW3860000
| KEGG_Ref = {{keggcite|correct|kegg}}
| KEGG =
| UNNumber =
| EINECS = 233-322-7
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 23333
| SMILES = [Ca+2].O=[Mn](=O)(=O)[O-].[O-] [Mn](=O)(=O)=O
| InChI = 1/Ca.2Mn.8O/q+2;;;;;;;;;2*-1/rCa.2MnO4/c;2*2-1(3,4)5/q+2;2*-1
| InChIKey = HYSMCTNXSYZEHS-KTXORSEZAZ
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/Ca.2Mn.8O/q+2;;;;;;;;;2*-1
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = HYSMCTNXSYZEHS-UHFFFAOYSA-N
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|Section2={{Chembox Properties
| Formula = Ca(MnO4)2
| MolarMass = 277.9493 g/mol
| Appearance = purple crystals
deliquesent
| Density = 2.49 g/cm3
| MeltingPtC = 140
| MeltingPt_notes = (decomposes, tetrahydrate)
| Solubility = tetrahydrate:
331 g/100 mL (14 °C)
338 g/100 mL (25 °C)
| SolubleOther = soluble in ammonium hydroxide
decomposes in alcohol
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|Section3={{Chembox Structure
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|Section4={{Chembox Thermochemistry
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|Section7={{Chembox Hazards
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|Section8={{Chembox Related
| OtherAnions =
| OtherCations = Sodium permanganate
Ammonium permanganate
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Calcium permanganate is an oxidizing agent and chemical compound with the chemical formula Ca(MnO4)2. This salt consists of the metal calcium and two permanganate ions.
Preparation
The salt is prepared from the reaction of potassium permanganate with calcium chloride{{Cite book|last=Perry|first=Dale L.|title=Handbook of Inorganic Compounds|publisher=Taylor & Francis|year=2011|isbn=978-1-4398-1461-1|edition=2nd|location=Boca Raton|pages=94–95}} or from the reaction of aluminium permanganate with calcium oxide. It can also be prepared by reacting manganese dioxide with a solution of calcium hypochlorite and a little bit of calcium hydroxide to increase the pH level.{{Citation needed|date=August 2020}}
Uses
Calcium permanganate is used in the textile industry, for sterilization of water, and as a deodorizer. It is believed to help whiten teeth.{{Cite patent|country=EP|number=1786352A1|title=Permanganate containing whitening compositions and methods of their use|status=|pubdate=|gdate=2005-08-23|invent1=|inventor1-first=|url=https://patents.google.com/patent/EP1786352A1/en}} It was formerly used as a component of rocket fuel by the Luftwaffe.{{cite book |last1=Van Pelt |first1=Michel |title=Rocketing into the future : the history and technology of rocket planes |date=2012 |publisher=Springer |location=New York |isbn=978-1-4614-3200-5 |page=60}}
Safety
It is noncombustible, but being a strong oxidizing agent, it will accelerate the burning of combustible material. If the combustible material is finely divided, the resulting mixture may be explosive. Contact with liquid combustible materials may result in spontaneous ignition. Contact with sulfuric acid may cause fires or explosions. Mixtures with acetic acid or acetic anhydride can explode if not kept cold. Explosions can occur when mixtures of calcium permanganate and sulfuric acid come into contact with benzene, carbon disulfide, diethyl ether, ethyl alcohol, petroleum, or other organic matter.{{cite web |title=Calcium permanganate Safety Data Sheet|url=https://www.echemi.com/sds/calcium-permanganate-pd180727113398.html |website=www.echemi.com}}
See also
References
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{{Calcium compounds}}
{{Permanganates}}
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