chromium(II) fluoride
{{chembox
| Watchedfields = changed
| Name = Chromium(II) fluoride
| OtherNames = chromium difluoride, chromium fluouride, chromous fluoride
| ImageFile = Rutile structure.png
| ImageSize =
| ImageCaption = {{Color box|#999999|border=darkgray}} Cr2+ {{Color box|#ff2200|border=darkgray}} F−
|Section1={{Chembox Identifiers
| PubChem = 66229
| ChemSpiderID = 59614
| EINECS = 233-168-0
| SMILES = [F-].[F-].[Cr+2]
| StdInChI = 1S/Cr.2FH/h;2*1H/q+2;;/p-2
| StdInChIKey = RNFYGEKNFJULJY-UHFFFAOYSA-L
| CASNo = 10049-10-2
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 53XZY98IXY
}}
|Section2={{Chembox Properties
| Cr=1 | F=2
| Appearance = blue-green iridescent crystals{{cite book |last=Perry|first=Dale L.|date=2011|title=Handbook of Inorganic Compounds, Second Edition|page=120|url=https://books.google.com/books?id=SFD30BvPBhoC|location=Boca Raton, Florida|publisher=CRC Press|isbn=978-1-43981462-8|access-date=2014-01-10}}
hygroscopic, turns to Cr2O3 when heated in air
| MeltingPtC = 894
| BoilingPt= >
| BoilingPtC = 1300
| Solubility = 76.7 g/100 mL
}}
|Section3={{Chembox Structure
}}
|Section4={{Chembox Thermochemistry
| DeltaHf = −8.645 kJ/g (solid)
| DeltaHc =
| Entropy =
| HeatCapacity =
}}
|Section7={{Chembox Hazards
| GHSPictograms = {{GHS05}}{{GHS07}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|314}}
| PPhrases = {{P-phrases|260|264|280|301+330+331|303+361+353|304+340|305+351+338|310|321|363|405|501}}
}}
}}
Chromium(II) fluoride is an inorganic compound with the formula CrF2. It exists as a blue-green iridescent solid. Chromium(II) fluoride is sparingly soluble in water, almost insoluble in alcohol, and is soluble in boiling hydrochloric acid, but is not attacked by hot distilled sulfuric acid or nitric acid. Like other chromous compounds, chromium(II) fluoride is oxidized to chromium(III) oxide in air.Merck Index, 14 ed. entry 2245
Preparation and structure
The compound is prepared by passing anhydrous hydrogen fluoride over anhydrous chromium(II) chloride. The reaction will proceed at room temperature but is typically heated to 100-200 °C to ensure completion:{{cite book|editor1-first=Georg |editor1-last=Brauer |translator1=Scripta Technica, Inc. |translator2-first=Reed F. |translator2-last=Riley |title=Handbook of preparative inorganic chemistry. Volume 1|date=1963|publisher=Academic Press|location=New York, N.Y.|isbn=978-0121266011|page=256|edition=2nd}}
:CrCl2 + 2 HF → CrF2 + 2 HCl
Like many difluorides, CrF2 adopts a structure like rutile with octahedral molecular geometry about Cr(II) and trigonal geometry at F−. Two of the six Cr–F bonds are long at 2.43 Å, and four are short near 2.00 Å.Jack, K. H.; Maitland, R. "Crystal structures and interatomic bonding of chromous and chromic fluorides" Proceedings of the Chemical Society, London (1957), 232. {{doi|10.1039/PS9570000217}} This distortion is a consequence of the Jahn–Teller effect that arises from the d4 electron configuration of the chromium(II) ion.{{Greenwood&Earnshaw2nd|pages=1021–1022}}
See also
References
{{reflist}}
External links
- [http://www.webelements.com/_media/compounds/Cr/Cr1F2-10049102.jpg Crystal Structure]
{{Chromium compounds}}
{{fluorine compounds}}