chromium(III) sulfide

{{chembox

|ImageFile = Cr2S3 structure.jpg

|Watchedfields = changed

|verifiedrevid = 428768903

|Name = Chromium(III) sulfide

|Section1={{Chembox Identifiers

|CASNo_Ref = {{cascite|correct|??}}

|CASNo = 12018-22-3

| ChemSpiderID = 140177

|PubChem = 159397

|EINECS = 234-638-8

| StdInChI=1S/2Cr.3S/q2*+3;3*-2

| StdInChIKey = DBULDCSVZCUQIR-UHFFFAOYSA-N

| SMILES = [S-2].[S-2].[S-2].[Cr+3].[Cr+3]

}}

|Section2={{Chembox Properties

|Formula = Cr2S3

|MolarMass = 200.19 g/mol

|Appearance = Brown to black powder

|Odor = odorless

|Solubility = insoluble

|MeltingPt = 1350 °C

|Density = 3.77 g/cm3

|MagSus = +2390.0·10−6 cm3/mol

}}

|Section7={{Chembox Hazards

|ExternalSDS = [http://www.espi-metals.com/msds's/chromiumsulfide.pdf]

|NFPA-H = 1

|NFPA-F = 0

|NFPA-R = 0

|PEL = TWA 1 mg/m3{{PGCH|0141}}

|REL = TWA 0.5 mg/m3

|IDLH = 250 mg/m3

}}

|Section8={{Chembox Related

|OtherAnions = Chromium(III) oxide
Chromium(III) selenide
Chromium(III) telluride}}

}}

Chromium(III) sulfide is the inorganic compound with the formula Cr2S3. It is a brown-black solid. Chromium sulfides are usually nonstoichiometric compounds, with formulas ranging from CrS to Cr0.67S (corresponding to Cr2S3).

Preparation

Chromium(III) sulfide can be prepared through the reaction of a stoichiometric mixture of the elements at 1000 °CGeorg Brauer: Handbuch der präparativen anorganischen Chemie. 3., umgearb. Auflage. Band III. Enke, Stuttgart 1981, {{ISBN|3-432-87823-0}}, S. 1493

:\mathrm{2 \ Cr + 3 \ S \longrightarrow Cr_2S_3}

It is a solid that is insoluble in water. According to X-ray crystallography, its structure is a combination of that of nickel arsenide (1:1 stoichiometry) and Cd(OH)2 (1:2 stoichiometry). Some metal-metal bonding is indicated by the short Cr-Cr distance of 2.78 Å. Jellinek, F. "The structures of the Chromium Sulphides" Acta Crystallographica 1957, volume 10, p620-p628 {{doi|10.1107/S0365110X57002200}}

See also

References

{{reflist}}

{{Chromium compounds}}

{{Sulfides}}

Category:Chromium(III) compounds

Category:Sesquisulfides

{{Inorganic-compound-stub}}