chromium(III) sulfide
{{chembox
|ImageFile = Cr2S3 structure.jpg
|Watchedfields = changed
|verifiedrevid = 428768903
|Name = Chromium(III) sulfide
|Section1={{Chembox Identifiers
|CASNo_Ref = {{cascite|correct|??}}
|CASNo = 12018-22-3
| ChemSpiderID = 140177
|PubChem = 159397
|EINECS = 234-638-8
| StdInChI=1S/2Cr.3S/q2*+3;3*-2
| StdInChIKey = DBULDCSVZCUQIR-UHFFFAOYSA-N
| SMILES = [S-2].[S-2].[S-2].[Cr+3].[Cr+3]
}}
|Section2={{Chembox Properties
|Formula = Cr2S3
|MolarMass = 200.19 g/mol
|Appearance = Brown to black powder
|Odor = odorless
|Solubility = insoluble
|MeltingPt = 1350 °C
|Density = 3.77 g/cm3
|MagSus = +2390.0·10−6 cm3/mol
}}
|Section7={{Chembox Hazards
|ExternalSDS = [http://www.espi-metals.com/msds's/chromiumsulfide.pdf]
|NFPA-H = 1
|NFPA-F = 0
|NFPA-R = 0
|PEL = TWA 1 mg/m3{{PGCH|0141}}
}}
|Section8={{Chembox Related
|OtherAnions = Chromium(III) oxide
Chromium(III) selenide
Chromium(III) telluride}}
}}
Chromium(III) sulfide is the inorganic compound with the formula Cr2S3. It is a brown-black solid. Chromium sulfides are usually nonstoichiometric compounds, with formulas ranging from CrS to Cr0.67S (corresponding to Cr2S3).
Preparation
Chromium(III) sulfide can be prepared through the reaction of a stoichiometric mixture of the elements at 1000 °CGeorg Brauer: Handbuch der präparativen anorganischen Chemie. 3., umgearb. Auflage. Band III. Enke, Stuttgart 1981, {{ISBN|3-432-87823-0}}, S. 1493
:
It is a solid that is insoluble in water. According to X-ray crystallography, its structure is a combination of that of nickel arsenide (1:1 stoichiometry) and Cd(OH)2 (1:2 stoichiometry). Some metal-metal bonding is indicated by the short Cr-Cr distance of 2.78 Å. Jellinek, F. "The structures of the Chromium Sulphides" Acta Crystallographica 1957, volume 10, p620-p628 {{doi|10.1107/S0365110X57002200}}
See also
- Brezinaite, a mineral with the formula Cr3S4
References
{{reflist}}
{{Chromium compounds}}
{{Sulfides}}
Category:Chromium(III) compounds
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