crocoite
{{Short description|Lead chromate mineral}}
{{Use dmy dates|date=January 2024}}
{{Infobox mineral
| name = Crocoite
| category = Chromate minerals
| boxwidth =
| boxbgcolor =
| image = Crocoite from the Dundas extended mine, Dundas, Tasmania, Australia.jpg
| imagesize = 260px
| caption = Crocoite from Dundas, Tasmania
| formula = Lead Chromate PbCrO4
| molweight =
| strunz = 7.FA.20
| system = Monoclinic
| class = Prismatic (2/m)
(same H-M symbol)
| symmetry = P21/n
| unit cell = a = 7.12 Å, b = 7.421 Å,
c = 6.8 Å; β = 102.41°; Z = 4
| color = Orange, red, yellow; orange-red in transmitted light.
| habit = Coarsely crystalline to acicular
| twinning =
| cleavage = Distinct on {110} indistinct on {001} and {100}
| fracture = Conchoidal to uneven
| tenacity = Sectile
| mohs = 2.5–3
| luster = Adamantine, Sub-Adamantine, Sub-Vitreous, Resinous, Waxy
| refractive = nα = 2.290(2) nβ = 2.360(2) nγ = 2.660(2)
| opticalprop = Biaxial (+)
| birefringence = δ = 0.370
| pleochroism = Weak
| streak = Yellowish orange
| gravity = 5.9–6.1
| melt =
| fusibility =
| diagnostic =
| solubility =
| diaphaneity = Transparent to translucent
| other =
| references = {{cite web |url=http://rruff.geo.arizona.edu/doclib/hom/crocoite.pdf |title=Crocoite (PbCrO4) |website=Rruff.geo.arizona.edu |access-date=19 December 2016}}{{cite web |url=http://www.mindat.org/min-1157.html |title=Crocoite: Crocoite mineral information and data |website=Mindat.org |date=15 December 2016 |access-date=19 December 2016}}{{cite web |url=http://webmineral.com/data/Crocoite.shtml |title=Crocoite Mineral Data |website=Webmineral.com |access-date=19 December 2016}}
}}
Crocoite is a mineral consisting of lead chromate, PbCrO4, and crystallizing in the monoclinic crystal system. It is identical in composition with the artificial product chrome yellow used as a paint pigment.{{sfn|Chisholm|1911}}
Description
Crocoite is commonly found as large, well-developed prismatic adamantine crystals, although in many cases are poorly terminated. Crystals are of a bright hyacinth-red color, translucent, and have an adamantine to vitreous lustre. On exposure to UV light some of the translucency and brilliancy is lost. The streak is orange-yellow; Mohs hardness is 2.5–3; and the specific gravity is 6.0.
File:Crocoite crystal structure.png
It was discovered at the Berezovskoe Au Deposit (Berezovsk Mines) near Ekaterinburg in the Urals in 1766;{{cite book |last=Lehmann |first=J.G. |title=De Nova Minerae Plumbi Specie Crystallina Rubra |year=1766 |url=https://books.google.com/books?id=UKtAAAAAcAAJ |language=la |access-date=9 November 2018 }} and named crocoise by F. S. Beudant in 1832, from the Greek κρόκος (krokos),{{cite book |author=Francois-Sulpice Beudant |title=Traite elementaire de Mineralogie. 2. ed |url=https://books.google.com/books?id=EVNOAAAAcAAJ |year=1832 |publisher=Verdiere |page=669}} saffron, in allusion to its color, a name first altered to crocoisite and afterwards to crocoite. In the type locality the crystals are found in gold-bearing quartz-veins traversing granite or gneiss and associated with crocoite are quartz, embreyite, phoenicochroite and vauquelinite. Phoenicochroite is a basic lead chromate, Pb2CrO5 with dark red crystals, and vauquelinite a lead and copper phosphate-chromate, Pb2CuCrO4PO4OH, with brown or green monoclinic crystals. Vauquelinite was named after Louis Nicolas Vauquelin, who in 1797 discovered (simultaneously with and independently of M. H. Klaproth) the element chromium in crocoite.{{sfn|Chisholm|1911}}
Abundant masses with exceptional examples of crocoite crystals have been found at Extended Mine, Adelaide Mine, Red Lead, West Comet, Platt and a few other Mines at Dundas, Tasmania.
The Adelaide Mine is described as "probably the prime source of crocoite in the world."Mindat.org - Adelaide Mine, Dundas mineral field, Zeehan mining district.The Adelaide Mining Company Pty. Ltd. has been actively mining crocoite from the Adelaide Mine since 2004. The website provides detailed information about the mine's history, operations, and the exceptional crocoite specimens it produces.The Adelaide Mining Company Pty. Ltd. - Crocoite from The Adelaide Mine
Crocoite is usually found in long slender prisms, usually about 10–20 mm but rarely up to 100 mm (4 inches) in length, with a brilliant lustre and color. Crocoite is also the official Tasmanian mineral emblem.{{cite journal |journal=The Mineralogical Record |volume=43 |url=https://mineralogicalrecord.com/pdfs/Tasmanian%20Crocoite%20Reduced.pdf |first1=Thomas P. |last1=Moore |first2=Wendell E. |last2=Wilson |pages=651–673 |title=Major Crocoite Discoveries}} Other localities which have yielded good crystallized specimens are Congonhas do Campo near Ouro Preto in Brazil, Luzon in the Philippines, Mutare in Mashonaland,{{sfn|Chisholm|1911}} near Menzies in Western Australia, plus Brazil, Germany and South Africa.
The relative rarity of crocoite is connected with the specific conditions required for its formation: an oxidation zone of lead ore bed and presence of ultramafic rocks serving as the source of chromium (in chromite). Oxidation of Cr3+ into CrO42− (from chromite) and decomposition of galena (or other primary lead minerals) are required for crocoite formation. These conditions are relatively unusual.
As crocoite is composed of lead(II) chromate, it is toxic, containing both lead and hexavalent chromium.{{cite web |url=http://www.kremer-pigmente.com/media/files_public/10850_SHD_ENG.pdf |title=Archived copy |website=www.kremer-pigmente.com |access-date=13 January 2022 |archive-url=https://web.archive.org/web/20140323092114/http://www.kremer-pigmente.com/media/files_public/10850_SHD_ENG.pdf |archive-date=23 March 2014 |url-status=dead}}
Mines
[https://theadelaidemine.com/ The Adelaide Mine],
Dundas, Tasmania, is famous for its world’s best crocoite. Adam Wright and his partners have been operating it for mineral specimen removal for a number of years and have had significant finds in recent years. In particular, the 2010 Pocket, and more recently, the Red River Pocket.https://crocoite.com/index.php/2018/03/adelaide-mine-dundas-tasmania/
The Mineralogical Record has documented major crocoite discoveries at the Adelaide Mine, including the significant "Red River Find" in 2012. This publication highlights the mine's ongoing importance in the mineral collecting community.https://mineralogicalrecord.com/wp-content/uploads/2020/10/pdfs/Tasmanian-Crocoite-Reduced.pdf
Of the mines in the Dundas field, the Adelaide mine is the most
prolific source of superb crocoite specimens, historically as well as currently. The mine is situated at the junction of Comet Creek and
Adelaide Creek, near the base of a spur of Stichtite Hill about 2 km
southeast of the original Dundas townsite.>https://mineralogicalrecord.com/wp-content/uploads/2020/10/pdfs/Tasmanian-Crocoite-Reduced.pdf
Of the numerous mines in the Dundas region, one has recently come back to life more than any other - The Adelaide Mine. The video titled "The Adelaide Mine" features Mineralogist Ralph Bottrill from Mineral Resources Tasmania, who provides an in-depth exploration of the renowned Adelaide Mine located in the Dundas region of Tasmania. In the video, viewers are taken underground to uncover the remarkable Red River find.{{cite web | url=https://www.youtube.com/watch?v=F9eMxl5ZAiw | title=The Adelaide Mine | website=YouTube | date=16 April 2021 }}
[https://redleadmine.com.au/ Red Lead Mine], The Red Lead Mine, located in the Dundas region near Zeehan on the west coast of Tasmania, Australia, is renowned for its stunning crocoite specimens. Shane Dohnt purchased the Red Lead Mine in 1986 and has been actively working it for crocoite ever since. Initially, he continued with open-cut mining, but more recently, he has reopened an 1890s collapsed adit to access the lodes below the surface. This approach reduces environmental impact and allows access to potentially rich areas too deep for open-cut mining.{{cite web | url=https://redleadmine.com.au/history/?form=MG0AV3&form=MG0AV3 | title=History }}
The Red Lead Mine has produced many fine specimens of crocoite over the years, and operations continue with the hope of discovering more exceptional specimens. The mine's crocoite specimens are highly sought after by collectors and have even been displayed at the Smithsonian Museum of Natural History in Washington D.C.{{cite web | url=https://redleadmine.com.au/?form=MG0AV3 | title=Australian Crocoite and Minerals for sale | Read Lead Mine Tasmania }}
[https://www.mindat.org/loc-213783.html Dundas Extended Mine]. Crocoite from Tasmania has also been mined from the Dundas Extended Mine by Mike and Eleanor Phelan since the mid-1980s, but the mine's origins date back to 1892 when it was used as a prospecting tunnel for silver lead. In April 2019, the mine was listed for sale,[https://www.abc.net.au/news/2019-04-26/a-hobby-mine-in-tasmanias-ghost-town-for-sale/11047052 For $300,000, you could own a hobby mine in a Tasmanian ghost town], Damian McIntyre, ABC News Online, 26 April 2019 however, it was not sold.
Gallery
Examples of crocoite
Crocoite from Tasmania.jpg|Specimen from the Red Lead Mine, Tasmania, Australia
Crocoite-360746.jpg|Crocoite from Adelaide Mine, Dundas mineral field, Zeehan District, Tasmania, Australia
crocoite09.jpg|Crystal intergrowth
Berezov-crocoite.jpg|On pyromorphite – Berezovsk – Deposit Topotype
See also
References
{{Reflist}}
- {{EB1911|wstitle=Crocoite|volume=7|page=479}}
- Bushmakin, A.F., 1996. Crocoite from the Berezovsk gold mines. World of Stones, 10, 28–31
- Bottrill, R.S., Williams, P., Dohnt, S., Sorrell, S. and Kemp, N.R. (2006). Crocoite and associated minerals from Dundas and other locations in Tasmania. Australian Journal of Mineralogy. 12, 59–90
External links
{{Commons category|Crocoite}}
- [http://www.parliament.tas.gov.au/tpl/InfoSheets/StateEmblems.htm List of Tasmanian state emblems] {{Webarchive|url=https://web.archive.org/web/20181225064058/http://www.parliament.tas.gov.au/tpl/InfoSheets/StateEmblems.htm |date=25 December 2018 }}
Category:Minerals in space group 14