dichloramine

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| verifiedrevid = 437036929

| ImageFileL1 = Dichloramine-2D.png

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| ImageFileR1 = Dichloramine-3D-spacefill.png

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| IUPACName = Azonous dichloride

| OtherNames = Chlorimide

| Section1 = {{Chembox Identifiers

| InChI = 1/Cl2HN/c1-3-2/h3H

| InChIKey = JSYGRUBHOCKMGQ-UHFFFAOYAB

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/Cl2HN/c1-3-2/h3H

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = JSYGRUBHOCKMGQ-UHFFFAOYSA-N

| CASNo_Ref = {{cascite|correct|PubChem}}

| CASNo = 3400-09-7

| DTXSID = DTXSID4074936

| UNII_Ref = {{fdacite|changed|FDA}}

| UNII = KGU33GRT44

| PubChem = 76939

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 69389

| SMILES = ClNCl

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| Section2 = {{Chembox Properties

| Formula = {{chem2|NHCl2}}

| N=1 | Cl=2 | H=1

| Appearance = yellow gasHolleman-Wiberg: Lehrbuch der Anorganischen Chemie, 102. Auflage, Berlin 2007, {{ISBN|978-3-11-017770-1}}.

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| Section7 = {{Chembox Hazards

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| Section8 = {{Chembox Related

| OtherCompounds = {{ubl|Ammonia|Monochloramine|Nitrogen trichloride}}

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Dichloramine (IUPAC name: Azonous dichloride) is a reactive inorganic compound with the chemical formula {{chem2|auto=1|NHCl2}}. It is one of the three chloramines of ammonia, the others being monochloramine ({{chem2|NH2Cl}}) and nitrogen trichloride ({{chem2|NCl3}}). This yellow gas is unstable and reacts with many materials. It is formed by a reaction between ammonia and chlorine or sodium hypochlorite. It is a byproduct formed during the synthesis of monochloramine and nitrogen trichloride.

Synthesis

Dichloramine can be prepared by a reaction between monochloramine and chlorine or sodium hypochlorite:

:{{chem2|NH2Cl + Cl2 → NHCl2 + HCl}}

== Reactions ==

Dichloramine reacts with the hydroxide ion, which can be present in water or comes from water molecules, to yield nitroxyl and the chloride ion.{{cite book|last1=White|first1=George Clifford|title=The handbook of chlorination|date=1986|publisher=Van Nostrand Reinhold|location=New York|isbn=0-442-29285-6|pages=169|edition=2nd}}

References