dichloromethyl methyl ether
{{Chembox
| ImageFile = Dichloromethyl methyl ether.svg
| ImageSize = 150px
| PIN = Dichloro(methoxy)methane
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|Section1={{Chembox Identifiers
| CASNo = 4885-02-3
| PubChem = 21004
| ChemSpiderID = 19757
| SMILES = ClC(Cl)OC
| InChI = InChI=1S/C2H4Cl2O/c1-5-2(3)4/h2H,1H3
}}
|Section2={{Chembox Properties
| C=2 | H=4 | Cl=2 | O=1
| Appearance =
| Density =
| MeltingPt =
| BoilingPt = 85°C
| Solubility =
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|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
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Dichloromethyl methyl ether (HCl2COCH3) is an organic compound that belongs to the class of ethers with a dichloromethyl group and a methyl group. It can be synthesized from methyl formate and a mixture of phosphorus pentachloride and phosphorus oxychlorideOrganic Syntheses, Coll. Vol. 5, p.365 (1973); Vol. 47, p.51 (1967). [http://www.orgsyn.org/demo.aspx?prep=cv5p0365 link] or by chlorination of chlorodimethyl ether.
The compound is used in the formylation of aromatic compounds (Rieche formylation) and as a chlorination agent in the formation of acid chlorides.Organic Syntheses, Coll. Vol. 7, p.467 (1990); Vol. 61, p.1 (1983). [http://www.orgsyn.org/demo.aspx?prep=cv7p0467 Link]