diclofenamide

{{Short description|Chemical compound}}

{{Drugbox

| Verifiedfields = changed

| Watchedfields = changed

| verifiedrevid = 460783591

| IUPAC_name = 4,5-Dichlorobenzene-1,3-disulfonamide

| image = Diclofenamide.svg

| alt = Skeletal formula of diclofenamide

| image2 = Diclofenamide-3D-spacefill.png

| alt2 = Space-filling model of diclofenamide

| tradename =

| Drugs.com = {{drugs.com|international|diclofenamide}}

| MedlinePlus = a601233

| pregnancy_AU =

| pregnancy_US =

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| legal_AU =

| legal_UK =

| legal_US =

| legal_status =

| routes_of_administration =

| bioavailability =

| protein_bound = 55%

| metabolism =

| elimination_half-life =

| excretion =

| IUPHAR_ligand = 6807

| CAS_number_Ref = {{cascite|correct|??}}

| CAS_number = 120-97-8

| ATC_prefix = S01

| ATC_suffix = EC02

| ATC_supplemental =

| PubChem = 3038

| DrugBank_Ref = {{drugbankcite|changed|drugbank}}

| DrugBank = DB01144

| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}

| ChemSpiderID = 2930

| UNII_Ref = {{fdacite|correct|FDA}}

| UNII = VVJ6673MHY

| KEGG_Ref = {{keggcite|correct|kegg}}

| KEGG = D00518

| ChEBI_Ref = {{ebicite|correct|EBI}}

| ChEBI = 101085

| ChEMBL_Ref = {{ebicite|correct|EBI}}

| ChEMBL = 17

| C=6 | H=6 | Cl=2 | N=2 | O=4 | S=2

| smiles = Clc1c(cc(cc1Cl)S(=O)(=O)N)S(=O)(=O)N

| StdInChI_Ref = {{stdinchicite|correct|chemspider}}

| StdInChI = 1S/C6H6Cl2N2O4S2/c7-4-1-3(15(9,11)12)2-5(6(4)8)16(10,13)14/h1-2H,(H2,9,11,12)(H2,10,13,14)

| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}

| StdInChIKey = GJQPMPFPNINLKP-UHFFFAOYSA-N

| melting_point = 228.5

}}

Diclofenamide (or dichlorphenamide) is a sulfonamide and a carbonic anhydrase inhibitor of the meta-disulfamoylbenzene class. Dichlorphenamide as a carbonic anhydrase inhibitor is used for the treatment of acute angle closure glaucoma. While Dichlorphenamide does contain two sulfate groups within the structure, it falls under the class of a first generation carbonic anhydrase Inhibitor.

Uses

Diclofenamide was approved in the United States in 1958 as Daranide to treat glaucoma,{{cite news |url=https://secure.medicalletter.org/article-share?a=1492d&p=tml&title=Dichlorphenamide%20(Keveyis)%20for%20Periodic%20Paralysis&cannotaccesstitle=1 |title=Dichlorphenaide (Keveyis) for Periodic Paralysis |publisher=The Medical Letter |date=April 16, 2016 |access-date=December 19, 2017}}{{drugs.com|international|diclofenamide.html}}: Diclofenamide{{cite journal | vauthors = Kanski JJ | title = Carbonic anhydrase inhibitors and osmotic agents in glaucoma. Carbonic anhydrase inhibitors | journal = The British Journal of Ophthalmology | volume = 52 | issue = 8 | pages = 642–3 | date = August 1968 | pmid = 5724852 | pmc = 506660 | doi = 10.1136/bjo.52.8.642 }} Subsequently, it was found effective in cases of therapy-resistant epilepsy.{{cite journal | vauthors = Rucquoy M, Sorel L | title = Diclofenamide in the treatment of therapy-resistant epilepsy | journal = Acta Neurologica Belgica | volume = 78 | issue = 3 | pages = 174–82 | year = 1978 | pmid = 352085 }} In 2015, the medication was approved in the US under the name Keveyis as an orphan drug for the treatment of primary hypokalemic and hyperkalemic periodic paralysis.

Cost

In 2001, diclofenamide had a U.S. list price of $50 for a bottle of 100 pills, and was approved for glaucoma. Merck discontinued diclofenamide when better glaucoma drugs were developed. In 2010, Sun Pharmaceutical Industries bought the rights.{{Citation needed|date=April 2023}} In 2015, the F.D.A. approved it as an orphan drug, with 7-year exclusive marketing rights, for periodic paralysis, which the company estimates affects 5,000 people in the U.S. In 2016, Strongbridge Biopharma acquired Sun, which raised the price to $15,001 for 100 pills. The cost of treatment would range from $109,500 to $219,000 a year. Sun gives the drug free to patients who don't have insurance.{{cite news | url = https://www.washingtonpost.com/news/wonk/wp/2017/12/18/this-old-drug-was-free-now-its-109500-a-year/ | title = This old drug was free. Now it's $109,500 a year. | first = Carolyn Y. | last = Johnson | name-list-style = vanc | newspaper = Washington Post | date = December 18, 2017 }}

References