dinickel boride
{{about|the crystalline compound|the catalyst improperly called "nickel boride" or "Ni2B"|nickel boride catalyst}}
{{Chembox
| verifiedrevid =
| Name = Dinickel boride
| ImageFile = Ni2B.png
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|Section1={{Chembox Identifiers
| ChemSpiderID_Ref =
| ChemSpiderID = 21170791
| EINECS = 234-494-6
| PubChem = 6336854
| StdInChI = 1S/B.2Ni
| StdInChIKey = WRLJWIVBUPYRTE-UHFFFAOYSA-N
| SMILES = [B].[Ni].[Ni]
| CASNo_Ref = US National Institutes of Health (2020): "[https://pubchem.ncbi.nlm.nih.gov/compound/6336854 Nickel boride (Ni2B)]". Compound page at the NCBI PubChem site. Accessed on 2020-07-18.
| CASNo = 12007-01-1
| RTECS =
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|Section2={{Chembox Properties
| Formula = Ni2B | Ni=2 | B=1
| MolarMass = 128.2 g/mol
| Appearance =
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|Section3={{Chembox Structure
| Coordination =
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|Section7={{Chembox Hazards
| ExternalSDS =
| GHSPictograms = {{GHS07}}{{GHS08}}{{GHS09}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|317|350i|372|410|}}
| PPhrases = {{P-phrases|}}
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Dinickel boride is a chemical compound of nickel and boron with formula {{chem|Ni|2|B}}.{{cite journal |first=T. |last=Bjurstrom |journal=Arkiv för kemi, mineralogi och geologi |title=Röntgenanalyse der Systeme Eisen-Bor, Kobalt-Bor und Nickel-Bor |trans-title=X-ray analysis of the iron-boron, cobalt-boron, and nickel-boron systems |volume=11A |issue=5 |date=March 1933}} It is one of the borides of nickel.
The formula "{{chem|Ni|2|B}}" and the name "nickel boride" are often used for a nickel-boron catalyst obtained by reacting nickel salts with sodium borohydride. However, that product is not a well-defined compound, and its bulk formula is closer to {{chem|Na|2.5|B}}(sic).{{Cite journal |last1=Hofer |first1=L. J. E. |last2=Shultz |first2=J. F. |last3=Panson |first3=R. D. |last4=Anderson |first4=R. B. |date=December 1964 |title=The Nature of the Nickel Boride Formed by the Action of Sodium Borohydride on Nickel Salts |url=https://pubs.acs.org/doi/abs/10.1021/ic50022a031 |journal=Inorganic Chemistry |language=en |volume=3 |issue=12 |pages=1783–1785 |doi=10.1021/ic50022a031 |issn=0020-1669}}
Synthesis
Dinickel boride can be obtained (together with other nickel borides) by heating sodium borohydride with powdered nickel metal up to 670 °C in a closed vessel, so that the released hydrogen creates a pressure of up to 3.4 MPa. The main reactions can be summarized as
: 2{{chem|NaBH|4}} ↔ 2NaH + {{chem|B|2|H|6}}
: 2Ni + 2{{chem|B|2|H|6}} + NaH ↔ {{chem|Ni|2|B}} + 3{{chem|BH|3}} + 2{{chem|H|2}} + Na
but other reactions occur, yielding other borides.{{Cite journal |last1=Shahbazi |first1=Mahboobeh |last2=Cathey |first2=Henrietta |last3=Danilova |first3=Natalia |last4=Mackinnon |first4=Ian |date=2018-07-22 |title=Single Step Process for Crystalline Ni-B Compounds |journal=Materials |language=en |volume=11 |issue=7 |pages=1259 |doi=10.3390/ma11071259 |issn=1996-1944 |pmc=6073427 |pmid=30037149 |bibcode=2018Mate...11.1259S |doi-access=free }}
See also
References
{{reflist}}
{{Nickel compounds}}
{{Borides}}
{{Inorganic-compound-stub}}