dodecane
{{Distinguish|Dodecahedrane}}
{{Chembox
| Watchedfields = changed
| verifiedrevid = 443707553
| ImageFile = Dodecane-2D-Skeletal.svg
| ImageFile_Ref = {{chemboximage|correct|??}}
| ImageSize = 260
| ImageAlt = Skeletal formula of dodecane
| ImageFile1 = DodecaneFull.png
| ImageFile1_Ref = {{chemboximage|correct|??}}
| ImageSize1 = 260
| ImageAlt1 = Skeletal formula of dodecane with all implicit carbons shown, and all explicit hydrogens added
| ImageFile2 = Dodecane 3D ball.png
| ImageFile2_Ref = {{chemboximage|correct|??}}
| ImageSize2 = 260
| ImageAlt2 = Ball and stick model of dodecane
|Section1={{Chembox Identifiers
| CASNo = 112-40-3
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 8182
| ChemSpiderID = 7890
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| UNII = 11A386X1QH
| UNII_Ref = {{fdacite|correct|FDA}}
| EINECS = 203-967-9
| DrugBank = DB02771
| DrugBank_Ref = {{drugbankcite|correct|drugbank}}
| KEGG = C08374
| KEGG_Ref = {{keggcite|correct|kegg}}
| MeSHName = n-dodecane
| ChEBI = 28817
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEMBL = 30959
| ChEMBL_Ref = {{ebicite|correct|EBI}}
| RTECS = JR2125000
| Beilstein = 1697175
| Gmelin = 201408
| SMILES = CCCCCCCCCCCC
| StdInChI = 1S/C12H26/c1-3-5-7-9-11-12-10-8-6-4-2/h3-12H2,1-2H3
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = SNRUBQQJIBEYMU-UHFFFAOYSA-N
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
}}
|Section2={{Chembox Properties
| C = 12
| H = 26
| Appearance = Colorless liquid
| Odor = Gasoline-like to odorless
| Density = 0.7495 g mL−1 at 20 °C{{Cite web|url=https://pubchem.ncbi.nlm.nih.gov/compound/dodecane#section=Solubility|title=Dodecane}}
| MeltingPtK = 263.2 to 263.8
| BoilingPtK = 487 to 491
| LogP = 6.821
| VaporPressure = 18 Pa (at 25 °C){{Cite web|url=https://pubchem.ncbi.nlm.nih.gov/summary/summary.cgi?cid=8182#x400|title=Dodecane}}
| HenryConstant = 1.4 nmol Pa−1 kg−1
| RefractIndex = 1.421
| Viscosity = 1.34 mPa s
}}
|Section3={{Chembox Thermochemistry
| DeltaHf = −353.5–−350.7 kJ mol−1
| DeltaHc = −7901.74 kJ mol−1
| Entropy = 490.66 J K−1 mol−1
| HeatCapacity = 376.00 J K−1 mol−1
}}
|Section4={{Chembox Hazards
| ExternalSDS = [http://hazard.com/msds/mf/baker/baker/files/d8752.htm hazard.com]
| GHSPictograms = {{GHS health hazard}}
| GHSSignalWord = DANGER
| HPhrases = {{H-phrases|304}}
| PPhrases = {{P-phrases|301+310|331}}
| NFPA-H = 1
| NFPA-F = 2
| NFPA-R = 0
| FlashPtC = 71
| AutoignitionPtC = 205
| ExploLimits = 0.6%
}}
|Section5={{Chembox Related
| OtherFunction_label = alkanes
| OtherFunction = {{Unbulleted list|Undecane|Tridecane}}
}}
}}
Dodecane (also known as dihexyl, bihexyl, adakane 12, or duodecane) is an oily liquid n-alkane hydrocarbon with the chemical formula C12H26 (which has 355 isomers).
It is used as a solvent, distillation chaser, and scintillator component. It is used as a diluent for tributyl phosphate (TBP) in nuclear reprocessing plants.{{cite book|last=Rydberg|first=Jan|title=Solvent Extraction Principles and Practice|year=2004|publisher=Marcel Dekker|isbn=0-8247-5063-2|page=524}}
Combustion reaction
Jet fuel surrogate
In recent years, n-dodecane has garnered attention as a possible surrogate for kerosene-based fuels such as Jet-A, S-8, and other conventional aviation fuels. It is considered a second-generation fuel surrogate designed to emulate the laminar flame speed, largely supplanting n-decane, primarily due to its higher molecular mass and lower hydrogen-to-carbon ratio which better reflect the n-alkane content of jet fuels.
See also
References
{{Reflist}}
External links
- {{cite web
|last = Caudwell
|first = D.R.
|author2 = Trusler, J.P.M.
|author3 = Vesovic, V.
|author4 = Wakeham, W.A.
|title = The Viscosity and Density of n-Dodecane and n-Octadecane at Pressures up to 200 mPa and Temperatures up to 473 K
|publisher = NIST
|date = 2003-06-16
|url = http://symp15.nist.gov/pdf/p175.pdf
|access-date = 2007-10-09
|url-status = dead
|archive-url = https://web.archive.org/web/20061009135831/http://symp15.nist.gov/pdf/p175.pdf
|archive-date = 2006-10-09
}}
- [https://web.archive.org/web/20070918222934/http://physchem.ox.ac.uk/MSDS/DO/dodecane.html Material Safety Data Sheet for Dodecane]
- [https://web.archive.org/web/20001118022500/http://www.ars-grin.gov/cgi-bin/duke/chemical.pl?DODECANE Dodecane], Dr. Duke's Phytochemical and Ethnobotanical Databases
{{Alkanes}}
{{Authority control}}