duftite

{{short description|Arsenate mineral}}

{{Infobox mineral

| name = Duftite

| category = Arsenate minerals

| boxwidth =

| boxbgcolor =

| image = Anglesite-Duftite-174037.jpg

| alt =

| caption = Duftite from Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia

| formula = PbCuAsO4(OH)

| IMAsymbol = Dft{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}

| molweight = 426.67 g/mol

| strunz = 8.BH.35

| dana = 41.5.1.4

| system = Orthorhombic

| class = Disphenoidal (222)
H-M symbol: (2 2 2)

| symmetry = P212121

| unit cell = a = 7.768(1), b = 9.211(1)
c = 5.999(1) [Å]; Z = 4

| color = Green, olive green or grey green. Generally zoned due to compositional variations.

| habit = Tiny crystals elongated along [001] with curved and rough faces, aggregated into crusts. Crystals may be pseudo-octahedral.

| lattice =

| twinning =

| cleavage = Indistinct

| fracture = Uneven to conchoidal

| tenacity =

| mohs = 4.5

| luster = Vitreous on fracture surfaces and dull on crystal faces

| refractive = nα = 2.03–2.04, nβ = 2.06–2.08, nγ = 2.08–2.10

| opticalprop = Biaxial (-), faint apple-green color (transmitted light)

| birefringence = δ = 0.06

| pleochroism =

| 2V = Large

| dispersion = r > v, perceptible

| streak = Pale green or white

| gravity = 6.4 (measured), 6.60 (calculated)

| density =

| melt =

| fusibility =

| diagnostic =

| solubility = Readily soluble in acids

| diaphaneity = Crystals are transparent to translucent

| other = Decrepitates on heating. Not radioactive.

|references = [http://www.webmineral.com/data/Duftite.shtml Duftite]. Webmineral.com. Retrieved on 2011-10-10.[http://www.mindat.org/min-1325.html Duftite]. Mindat.org[http://rruff.geo.arizona.edu/doclib/hom/duftite.pdf Duftite]. (PDF) Handbook of Mineralogy

}}

Duftite is a relatively common arsenate mineral with the formula CuPb(AsO4)(OH), related to conichalcite. It is green and often forms botryoidal aggregates. It is a member of the adelite-descloizite Group, Conichalcite-Duftite Series. Duftite and conichalcite specimens from Tsumeb are commonly zoned in color and composition. Microprobe analyses and X-ray powder-diffraction studies indicate extensive substitution of Zn for Cu, and Ca for Pb in the duftite structure. This indicates a solid solution among conichalcite, CaCu(AsO4 )(OH), austinite, CaZn(AsO4)(OH) and duftite PbCu(AsO4)(OH), all of them belonging to the adelite group of arsenates.{{cite journal|url=http://rruff.info/uploads/CM18_191.pdf|author=Jambor, J L, Owens, D R and Dutrizac, J E |year=1980|title= Solid solution in the adelite group of arsenates|journal= Canadian Mineralogist |volume=18|pages= 191–195}} It was named after Mining Councilor G Duft, Director of the Otavi Mine and Railroad Company, Tsumeb, Namibia.{{cite journal|vauthors=Wherry ET, Foshag WF|year=1921|title=New mineral names|journal= American Mineralogist |url=http://www.minsocam.org/ammin/AM6/AM6_140.pdf|volume=6|pages= 140–141}} The type locality is the Tsumeb Mine, Tsumeb, Otjikoto Region, Namibia.

Structure

The structure{{cite journal|year=1998|journal= Mineralogical Magazine|title=The crystal chemistry of duftite, PbCuAsO4(OH) and the beta-duftite problem|url=http://rruff.geo.arizona.edu/doclib/mm/vol62/MM62_121.pdf |author1=Kharisun|author2= Max R. Taylor|author3= D. J. M. Bevan|author4= Allan Pring |volume=62|issue= 1|pages=121–130 |doi=10.1180/002646198547413|bibcode= 1998MinM...62..121K|s2cid= 98680784}} is composed of chains of edge-sharing CuO6 distorted octahedra parallel to the c axis. The chains are linked by AsO4 tetrahedra and Pb atoms.

Environment

Duftite is an uncommon product of weathered sulfide ore deposits. It is associated with azurite at the type locality, and with bayldonite, segnitite, agardite and gartrellite at the Central Cobar Mines, New South Wales, Australia, where some pseudomorphs of duftite after mimetite have also found.{{cite journal|journal=Australian Journal of Mineralogy|volume= 11|issue=2 |page=79}} It occurs in association with olivenite, mottramite, azurite, malachite, wulfenite and calcite in the Tsumeb, Namibia deposit. It occurs with bayldonite, beudantite, mimetite and cerussite in the Cap Garonne mine, France.

File:Duftite-Cerussite-174182.jpg, Tsumeb mine, Namibia (size: 6 × 5 × 3 cm)]]

Distribution

Reported from Argentina, Australia, Austria, Chile, the Czech Republic, France, Germany, Greece, Italy, Japan, Mexico, Namibia, Poland, Portugal, Russia, South Africa, Spain, Switzerland, the UK, the US and Zimbabwe.

References

{{Reflist}}

Bibliography

  • Palache, P.; Berman H.; Frondel, C. (1960). "Dana's System of Mineralogy, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. (Seventh Edition)" John Wiley and Sons, Inc., New York, pp. 810-811.

{{Commons category|Duftite|position=left}}

Category:Arsenate minerals

Category:Copper(II) minerals

Category:Lead minerals

Category:Orthorhombic minerals

Category:Minerals in space group 19