europium(II) fluoride

{{Chembox

| Name = Europium(II) fluoride

| ImageFile =

| ImageSize =

| ImageAlt =

| IUPACName = Europium(II) fluoride

| OtherNames = Europium difluoride

| Section1 = {{Chembox Identifiers

| CASNo = 14077-39-5

| CASNo_Ref = {{cascite|correct|CAS}}

| PubChem = 21225127

| ChemSpiderID = 13834724

| DTXSID = DTXSID00611473

| StdInChI=1S/Eu.2FH/h;2*1H/q+2;;/p-2

| StdInChIKey = YLDGIMHVWSTRML-UHFFFAOYSA-L

| SMILES = F[Eu]F

| SMILES2 = [F-].[F-].[Eu+2]

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| Section2 = {{Chembox Properties

| Formula = EuF2

| MolarMass = 189.96

| Appearance = dark yellowish solid

| Density = 6.495 g·cm−3

| MeltingPt =

| BoilingPt =

| Solubility = }}

|Section3 = {{Chembox Structure

|Structure_ref = {{cite book | last=Greis | first=Ortwin | last2=Haschke | first2=John M. | title=Handbook on the Physics and Chemistry of Rare Earths Volume 5 | chapter=Chapter 45 Rare earth fluorides | publisher=Elsevier | year=1982 | issn=0168-1273 | doi=10.1016/s0168-1273(82)05008-9 | pages=387–460}}

|CrystalStruct = Fluorite structure

|SpaceGroup = Fm{{overline|3}}m (No. 225)

|LattConst_a =584.23 pm

|UnitCellFormulas = 4

|Coordination =

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| Section4 = {{Chembox Hazards

| GHSPictograms = {{GHS06}}

| GHSSignalWord = Danger

| HPhrases = {{H-phrases|301}}

| PPhrases = {{P-phrases|264|270|301+310|321|330|405|501}}

| MainHazards =

| FlashPt =

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| Section5 = {{Chembox Related

| OtherAnions = Europium(II) bromide
Europium(II) chloride
Europium(II) iodide

| OtherCations = Samarium(II) fluoride
Thulium(II) fluoride
Ytterbium(II) fluoride

| OtherCompounds = Europium(III) fluoride

| OtherFunction = }}

}}

Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.Zhao Yongzhi, Ma Ying, Hou Shaochun, Zhang Wenjuan, Wang Jingjing, Ding Yanrong, Hao Yifan. [http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201705017.htm 氟化亚铕研究现状] {{Webarchive|url=https://web.archive.org/web/20220114021402/http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201705017.htm |date=2022-01-14 }} (lit. Research Progress of Europium(II) Fluoride). Chinese Rare Earths, 2017. 38 (5): 134-140. (in Chinese)

Production

Europium(II) fluoride can be produced by reducing europium(III) fluoride with metallic europium or hydrogen gas.Georg Brauer: Handbuch der Präparativen Anorganischen Chemie. 3., umgearb. Auflage. Band I. Enke, Stuttgart 1975, {{ISBN|3-432-02328-6}}, S. 255.

:\mathrm{2 \ EuF_3 + Eu \longrightarrow 3 \ EuF_2}

:\mathrm{2 \ EuF_3 + H_2 \longrightarrow 2 \ EuF_2 + 2 \ HF}

Properties

Europium(II) fluoride is a bright yellowish solid with a fluorite structure.

EuF2 can be used to dope a trivalent rare-earth fluoride, such as LaF3, to create a vacancy-filled structure with increased conductivity over a pure crystal. Such a crystal can be used as a fluoride-specific semipermeable membrane in a fluoride selective electrode to detect trace quantities of fluoride.{{cite journal |last1=Light |first1=Truman S. |last2=Cappuccino |first2=Carleton C. |title=Determination of fluoride in toothpaste using an ion-selective electrode |journal=Journal of Chemical Education |date=April 1975 |volume=52 |issue=4 |pages=247–250 |doi=10.1021/ed052p247|pmid=1133123 |bibcode=1975JChEd..52..247L }}{{cite journal |last1=Frant |first1=Martin S. |last2=Ross |first2=James W. |title=Electrode for Sensing Fluoride Ion Activity in Solution |journal=Science |date=23 December 1966 |volume=154 |issue=3756 |pages=1553–1555 |doi=10.1126/science.154.3756.1553 |jstor=1720460 |pmid=5924922 |bibcode=1966Sci...154.1553F |s2cid=11042445 |url=https://www.jstor.org/stable/pdf/1720460.pdf}}

References