europium(II) fluoride
{{Chembox
| Name = Europium(II) fluoride
| ImageFile =
| ImageSize =
| ImageAlt =
| IUPACName = Europium(II) fluoride
| OtherNames = Europium difluoride
| Section1 = {{Chembox Identifiers
| CASNo = 14077-39-5
| CASNo_Ref = {{cascite|correct|CAS}}
| PubChem = 21225127
| ChemSpiderID = 13834724
| DTXSID = DTXSID00611473
| StdInChI=1S/Eu.2FH/h;2*1H/q+2;;/p-2
| StdInChIKey = YLDGIMHVWSTRML-UHFFFAOYSA-L
| SMILES = F[Eu]F
| SMILES2 = [F-].[F-].[Eu+2]
}}
| Section2 = {{Chembox Properties
| Formula = EuF2
| MolarMass = 189.96
| Appearance = dark yellowish solid
| Density = 6.495 g·cm−3
| MeltingPt =
| BoilingPt =
| Solubility = }}
|Section3 = {{Chembox Structure
|CrystalStruct = Fluorite structure
|SpaceGroup = Fm{{overline|3}}m (No. 225)
|LattConst_a =584.23 pm
|UnitCellFormulas = 4
|Coordination =
}}
| Section4 = {{Chembox Hazards
| GHSPictograms = {{GHS06}}
| GHSSignalWord = Danger
| HPhrases = {{H-phrases|301}}
| PPhrases = {{P-phrases|264|270|301+310|321|330|405|501}}
| MainHazards =
| FlashPt =
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| Section5 = {{Chembox Related
| OtherAnions = Europium(II) bromide
Europium(II) chloride
Europium(II) iodide
| OtherCations = Samarium(II) fluoride
Thulium(II) fluoride
Ytterbium(II) fluoride
| OtherCompounds = Europium(III) fluoride
| OtherFunction = }}
}}
Europium(II) fluoride is an inorganic compound with a chemical formula EuF2. It was first synthesized in 1937.Zhao Yongzhi, Ma Ying, Hou Shaochun, Zhang Wenjuan, Wang Jingjing, Ding Yanrong, Hao Yifan. [http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201705017.htm 氟化亚铕研究现状] {{Webarchive|url=https://web.archive.org/web/20220114021402/http://www.cnki.com.cn/Article/CJFDTOTAL-XTZZ201705017.htm |date=2022-01-14 }} (lit. Research Progress of Europium(II) Fluoride). Chinese Rare Earths, 2017. 38 (5): 134-140. (in Chinese)
Production
Europium(II) fluoride can be produced by reducing europium(III) fluoride with metallic europium or hydrogen gas.Georg Brauer: Handbuch der Präparativen Anorganischen Chemie. 3., umgearb. Auflage. Band I. Enke, Stuttgart 1975, {{ISBN|3-432-02328-6}}, S. 255.
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Properties
Europium(II) fluoride is a bright yellowish solid with a fluorite structure.
EuF2 can be used to dope a trivalent rare-earth fluoride, such as LaF3, to create a vacancy-filled structure with increased conductivity over a pure crystal. Such a crystal can be used as a fluoride-specific semipermeable membrane in a fluoride selective electrode to detect trace quantities of fluoride.{{cite journal |last1=Light |first1=Truman S. |last2=Cappuccino |first2=Carleton C. |title=Determination of fluoride in toothpaste using an ion-selective electrode |journal=Journal of Chemical Education |date=April 1975 |volume=52 |issue=4 |pages=247–250 |doi=10.1021/ed052p247|pmid=1133123 |bibcode=1975JChEd..52..247L }}{{cite journal |last1=Frant |first1=Martin S. |last2=Ross |first2=James W. |title=Electrode for Sensing Fluoride Ion Activity in Solution |journal=Science |date=23 December 1966 |volume=154 |issue=3756 |pages=1553–1555 |doi=10.1126/science.154.3756.1553 |jstor=1720460 |pmid=5924922 |bibcode=1966Sci...154.1553F |s2cid=11042445 |url=https://www.jstor.org/stable/pdf/1720460.pdf}}
References
{{reflist}}
{{Europium compounds}}
{{fluorides}}
{{Lanthanide halides}}
Category:Europium(II) compounds