lanthanum cobaltite

{{Chembox

| OtherNames = Lanthanum cobalt oxide

| Section1 = {{Chembox Identifiers

| CASNo = 12016-86-3

| EINECS = 807-340-6

| PubChem = 167713694

| SMILES = [Co+3].[La+3].[O-2].[O-2].[O-2]

| StdInChI=1S/Co.La.3O/q2*+3;3*-2

| StdInChIKey = YPEZFFYJJVDWJO-UHFFFAOYSA-N

}}

| Section2 = {{Chembox Properties

|Co=1|La=1|O=3

}}

| Section7 = {{Chembox Hazards

| GHSPictograms = {{GHS07}}{{GHS08}}

| GHSSignalWord = Warning

| HPhrases = {{H-phrases|319|335|302|317|351}}

| PPhrases = {{P-phrases|201|202|261|264|271|272|280|302+352|304+340|305+351+338|308+313|321|333+313|337+313|362|403+233|405|501}}

}}

}}

Lanthanum cobaltite is a perovskite with chemical formula LaCoO3. As a solid, the structure LaCoO3, will exist as rhombohedral material at room temperature with ferroelastic properties; though at temperatures above ~900 °C a phase transition to a cubic lattice occurs.{{cite journal|last1=Kleveland|first1=Kjersti|title=Ferroeleastic Behavior of LaCoO3|journal=Journal of the American Ceramic Society|date=2001|volume=84|issue=9|pages=2029–2033|doi=10.1111/j.1151-2916.2001.tb00953.x }}{{Cite journal|last1=Petrov|first1=A. N.|last2=Kononchuk|first2=O. F.|last3=Andreev|first3=A. V.|last4=Cherepanov|first4=V. A.|last5=Kofstad|first5=P.|date=1995-09-01|title=Crystal structure, electrical and magnetic properties of La1−xSrxCoO3−y|journal=Solid State Ionics|volume=80|issue=3|pages=189–199|doi=10.1016/0167-2738(95)00114-L}}

It is also common of LaCoO3 to be utilized with either dopants or exhibit oxygen non-stoichometry where it may assume the structure La1−xA'xCo1−yB'yO3±𝛿 where 𝛿 is some small quantity{{cite journal|last1=Orlovskaya|first1=Nina|title=Mechanical properties of LaCoO3 based ceramics |journal=Journal of the European Ceramic Society|date=2000|volume=20|issue=1|pages=51–56|doi=10.1016/S0955-2219(99)00084-9|citeseerx=10.1.1.516.9621}} making this class of perovskites extremely versatile for catalysis, one such commonly utilized material is lanthanum strontium cobalt ferrite otherwise known as LSCF.

References