magnesium fluoride
{{Short description|Chemical compound of magnesium and fluorine}}
{{chembox
| Watchedfields = changed
| verifiedrevid = 477000602
| Name = Magnesium fluoride
{{Citation
|chapter-url=https://archive.org/details/CRCHandbookOfChemistryAndPhysics97thEdition2016/page/n789
|chapter=Physical Constants of Inorganic Compounds
| year = 2016
| title = Handbook of Chemistry and Physics
| edition = 97th
|editor=W.M. Haynes
| publisher = CRC Press
| isbn = 978-1-4987-5429-3
| pages = 4–71 (789)}}
| ImageFile = Magnesium-fluoride-unit-cell-3D-bs-17.png
| ImageSize =
| ImageName = Magnesium fluoride
| OtherNames = Sellaite
Irtran-1
|Section1={{Chembox Identifiers
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID = 22952
| InChI = 1/2FH.Mg/h2*1H;/q;;+2/p-2
| InChIKey = ORUIBWPALBXDOA-NUQVWONBAK
| SMILES = F[Mg]F
| SMILES2 = [Mg+2].[F-].[F-]
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/2FH.Mg/h2*1H;/q;;+2/p-2
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = ORUIBWPALBXDOA-UHFFFAOYSA-L
| CASNo = 7783-40-6
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = 5N014C7IWU
| PubChem = 24546
| RTECS = OM3325000
| EINECS = 231-995-1
}}
|Section2={{Chembox Properties
| Formula = {{chem2|MgF2}}
| MolarMass = 62.3018 g/mol
| Appearance = Colorless to white tetragonal crystals
| Density = 3.148 g/cm3
| Solubility = 0.013 g/(100 mL)
| SolubilityProduct = 5.16⋅10−11
| SolubleOther = {{ubl|Soluble in nitric acid|Slightly soluble in acetone|Insoluble in ethanol}}
| MeltingPtC = 1263
| BoilingPtC = 2260
| RefractIndex = 1.37397
| MagSus = −22.7⋅10−6 cm3/mol
}}
|Section3={{Chembox Structure
| CrystalStruct = Rutile (tetragonal), tP6
| SpaceGroup = P42/mnm, No. 136
}}
|Section4={{Chembox Thermochemistry
| DeltaHf = −1124.2 kJ/mol
| DeltaHc =
| DeltaGf = −1071 kJ/mol
| Entropy = 57.2 J/(mol⋅K)
| HeatCapacity = 61.6 J/(mol⋅K)
}}
|Section7={{Chembox Hazards
| Hazards_ref = {{Cite web|url=http://www.sciencelab.com/msds.php?msdsId=9924548|title=Magnesium Fluoride Material Safety Data Sheet|date=May 21, 2013|website=Science Labs|access-date=October 13, 2017}}{{Cite web|url=http://www.chemicalbook.com/ChemicalProductProperty_EN_CB8716701.htm|title=Magnesium fluoride|website=CAS DataBase List|publisher=ChemicalBook|access-date=October 13, 2017}}
| ExternalSDS = [http://www.chemicalbook.com/ChemicalProductProperty_EN_CB8716701.htm ChemicalBook]
| GHSPictograms = {{GHS07|Irritant}}
| GHSSignalWord = WARNING
| HPhrases = {{H-phrases|303|315|319|335}}
| PPhrases = {{P-phrases|261|304+340|305+351+338|405}}
| LD50 = 2330{{clarify|What is the unit of measurement??? Miligram per kilogram? Gram per kilogram? Miligram per gram? Frogs per maa gramma???|date=February 2023}} (rat, oral)
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| NFPA-S =
}}
|Section8={{Chembox Related
| OtherAnions = {{ubl|Magnesium chloride|Magnesium bromide|Magnesium iodide}}
| OtherCations = {{ubl|Beryllium fluoride|Calcium fluoride|Strontium fluoride|Barium fluoride|Radium fluoride}}
| OtherCompounds = {{ubl|Hydrogen fluoride|Zinc fluoride|Aluminium fluoride}}
}}
}}
Magnesium fluoride is an ionically bonded inorganic compound with the formula {{chem2|MgF2|auto=1}}. The compound is a colorless to white crystalline salt and is transparent over a wide range of wavelengths, with commercial uses in optics that are also used in space telescopes. It occurs naturally as the rare mineral sellaite.
Production
Magnesium fluoride is prepared from magnesium oxide with sources of hydrogen fluoride such as ammonium bifluoride, by the breakdown of it:
:{{chem2|MgO + [NH4]HF2 → MgF2 + NH3 + H2O}}
Related metathesis reactions are also feasible:
Structure
The compound crystallizes as tetragonal birefringent crystals. The structure of the magnesium fluoride is similar to that of rutile,{{cite book | first1 = A. F. | last1 = Wells | title = Structural Inorganic Chemistry | edition = 5th | year = 1984 | publisher = Oxford University Press | isbn = 978-0-19-965763-6 | pages = 413, 441}}{{Greenwood&Earnshaw2nd|pages=117–119}} featuring octahedral {{chem2|Mg(2+)}} cations and 3-coordinate fluoride anions.{{Ullmann|doi=10.1002/14356007.a11_307|title=Fluorine Compounds, Inorganic|year=2000|last1=Aigueperse|first1=Jean|last2=Mollard|first2=Paul|last3=Devilliers|first3=Didier|last4=Chemla|first4=Marius|last5=Faron|first5=Robert|last6=Romano|first6=René|last7=Cuer|first7=Jean Pierre|isbn=3527306730}}
In the gas phase, monomeric {{chem2|MgF2}} molecules adopt a linear molecular geometry.
Uses
=Optics=
Magnesium fluoride is transparent over an extremely wide range of wavelengths. Windows, lenses, and prisms made of this material can be used over the entire range of wavelengths from 0.120 μm (vacuum ultraviolet) to 8.0 μm (infrared). High-quality, synthetic magnesium fluoride is one of two materials (the other being lithium fluoride) that will transmit in the vacuum ultraviolet range at 121 nm (Lyman alpha). Lower-grade magnesium fluoride is inferior to calcium fluoride in the infrared range.{{citation needed|date=January 2021}}
Magnesium fluoride is tough and polishes well but is slightly birefringent and should therefore be cut with the optic axis perpendicular to the plane of the window or lens. Due to its suitable refractive index of 1.37, magnesium fluoride is commonly applied in thin layers to the surfaces of optical elements as an inexpensive anti-reflective coating.{{citation needed|date=January 2021}} Its Verdet constant is 0.00810{{nbsp}}arcmin⋅G−1⋅cm−1 at 632.8 nm.J. Chem. Soc., Faraday Trans., 1996, 92, 2753 - 2757. {{doi|10.1039/FT9969202753}}
Safety
Chronic exposure to magnesium fluoride may affect the skeleton, kidneys, central nervous system, respiratory system, eyes and skin, and may cause or aggravate attacks of asthma.{{Cite web|url=http://www.espimetal.com/index.php/msds/658-Magnesium%20Fluoride|archive-url=https://web.archive.org/web/20171028013735/http://www.espimetal.com/index.php/msds/658-Magnesium%20Fluoride|url-status=dead|archive-date=2017-10-28|title=Magnesium Fluoride Material Safety Data Sheet|date=August 2004|website=ESPI Metals|access-date=October 13, 2017}}
References
{{reflist}}
External links
- [https://web.archive.org/web/20060519173812/http://infrared.als.lbl.gov/IRwindows.html Infrared windows] at Lawrence Berkeley National Laboratory
- [https://web.archive.org/web/20060116134617/http://www.npi.gov.au/database/substance-info/profiles/44.html National Pollutant Inventory - Fluoride and compounds fact sheet]
- [http://www.crystran.co.uk/magnesium-fluoride-mgf2.htm Crystran Data] [http://www.crystran.co.uk/getfile.php?file=134 Crystran MSDS]{{dead link|date=January 2018 |bot=InternetArchiveBot |fix-attempted=yes}}
{{Magnesium compounds}}
{{Fluorides}}