manganin
{{this|an alloy|the antimicrobial peptides|magainin}}
{{Infobox material
| name = Manganin
| image = 1900 Reichenstalt Pattern Resistor.jpg
| image_size =
| alt =
| caption = A manganin resistor made in 1900 at the Bushy House physics laboratory.
| type = Copper-manganese alloy
| density = {{val|8.4|u=g/cm3}}
| flammability =
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| tensile_strength = 300–600 MPa
| elongation = <50%
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| izod_impact_strength = 107 J/m
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| melting_point = 1020 °C
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| thermal_conductivity_note = at {{val|23|u=degC}}
| thermal_conductivity = 22 W/(m·K)
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| linear_expansion = {{val|14|-|19|e=-6|u=K−1}}
| specific_heat = 0.097 cals/gm
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| volume_resistivity = 43–48 μΩ⋅cm
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| gas_perm_temp = {{val|20|u=degC}}
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}}
Manganin is a trademarked name for an alloy of typically 84.2% copper, 12.1% manganese, and 3.7% nickel. It was first developed by Edward Weston in 1892, improving upon his Constantan (1887).
Manganin foil and wire is used in the manufacture of resistors, particularly ammeter shunts, because of its virtually zero temperature coefficient of resistance value{{Cite web|url=http://www.goodfellow.com/catalogue/GFCat2H.php?ewd_token=09GRBJvlw6lL5lDbZC1qWnos3v9ad5&n=kCvbg9HE4EQs6Xg56ttKPuupoT1SdP&ewd_urlNo=GFCat2L3&Head=CU06|title=Goodfellow Technical Information Manganin® - Resistance Alloy|website=www.goodfellow.com|access-date=2016-09-11}} and long term stability. Several Manganin resistors served as the legal standard for the ohm in the United States from 1901 to 1990.{{Cite web |url=https://nvlpubs.nist.gov/nistpubs/sp958-lide/063-065.pdf |title=Stability of Double-Walled Manganin Resistors |access-date=2007-04-30 |archive-url=https://web.archive.org/web/20240930055258/https://nvlpubs.nist.gov/nistpubs/sp958-lide/063-065.pdf |archive-date=2024-09-30 |url-status=live}} Manganin wire is also used as an electrical conductor in cryogenic systems, minimizing heat transfer between points which need electrical connections.
Manganin is also used in gauges for studies of high-pressure shock waves (such as those generated from the detonation of explosives) because it has low strain sensitivity but high hydrostatic pressure sensitivity.{{cite web |title=Special Use Sensors - Manganin Pressure Sensor |url=http://web.sensor-ic.com:8000/ZLXIAZAI/VISHAY/thumb_2011032859967085.pdf |website=web.sensor-ic.com |publisher=Vishay |access-date=15 April 2023 }}{{Dead link|date=April 2024 |bot=InternetArchiveBot |fix-attempted=yes }}
History
{{Expand section|date=January 2011}}
In 1887 Edward Weston discovered that metals can have a negative temperature coefficient of resistance, inventing what he called his "Alloy No. 2."
It was produced in Germany where it was renamed "Constantan".{{Cite book|url=https://archive.org/details/chronologicalhis00natirich|title=A chronological history of electrical development from 600 B.C.|last=National Electrical Manufacturers Association|date=1946 |publisher=New York, N.Y., National Electrical Manufacturers Association}} In 1888 he patented{{US patent|381304A}} "an alloy containing from 65 to 70 parts of copper, 25 to 30 parts of ferro-manganese, and 2.5 to 10 parts of nickel" which had a nearly constant resistivity.
Manganin wire as we know it was developed by Weston's assistant John Forrest Kelly.{{Cite journal |last=Fessenden |first=Reginald A. |date=1893-07-21 |title=Electrical Notes |url=https://books.google.com/books?id=wdlCTzYLf2kC&pg=RA1-PA36 |journal=Science |language=en |volume=ns-22 |issue=546 |pages=35–36 |doi=10.1126/science.ns-22.546.35 |issn=0036-8075|url-access=subscription }} In May 1893, Weston received a patent{{Source?|date=October 2024}} for the material and its use for resistors. While Manganin represented a significant advance in technology -- the material was a conductive metal with constant resistance over a wide range of working temperatures, Weston did not receive wide recognition at the time.{{Cite book
|url=https://archive.org/details/measureforgreatn001419mbp
|title=A Measure for Greatness; A Short Biography of Edward Weston
|first=David O. |last=Woodbury
|year=1949
|publisher=McGraw-Hill |location=New York, Toronto, London
}}
Properties
= Cu86/Mn12/Ni2 =
{{Cleanup-layout|date=November 2012 }}
Electrical Properties
- Temperature coefficient: {{val|1.5|e=-5|u= K−1}}
Mechanical Properties
- Modulus of elasticity: 124–159 GPa
- Maximum use temperature in air: 300 °C
class="wikitable" style="text-align: center"
|+ Cu84/Mn12/Ni4{{cite book|title=CRC Handbook 27th ed.|date=Feb 1943|page=1875}} |
Temperature [°C]
! coefficient of resistivity |
---|
{{fsp}}12
| +.000006 |
{{fsp}}25
| {{fsp}}.000000 |
100
| −.000042 |
250
| −.000052 |
475
| {{fsp}}.000000 |
500
| +.00011{{fsp}} |
class="wikitable" style="text-align: center"
|+ Resistance of Wires at {{val|20|u=degC}}{{cite book|title=CRC Handbook 27th ed.|date=Feb 1943|page=2485}} |
AWG
! ohms per cm ! ohms per ft |
---|
10
| .000836 | {{fsp}}0.0255 |
12
| .00133{{fsp}} | {{fsp}}0.0405 |
14
| .00211{{fsp}} | {{fsp}}0.0644 |
16
| .00336{{fsp}} | {{fsp}}0.102{{fsp}} |
18
| .00535{{fsp}} | {{fsp}}0.163{{fsp}} |
20
| .00850{{fsp}} | {{fsp}}0.259{{fsp}} |
22
| .0135{{fsp|2}} | {{fsp}}0.412{{fsp}} |
24
| .0215{{fsp|2}} | {{fsp}}0.655{{fsp}} |
26
| .0342{{fsp|2}} | {{fsp}}1.04{{fsp|2}} |
27
| .0431{{fsp|2}} | {{fsp}}1.31{{fsp|2}} |
28
| .0543{{fsp|2}} | {{fsp}}1.66{{fsp|2}} |
30
| .0864{{fsp|2}} | {{fsp}}2.63{{fsp|2}} |
32
| .137{{fsp|3}} | {{fsp}}4.19{{fsp|2}} |
34
| .218{{fsp|3}} | {{fsp}}6.66{{fsp|2}} |
36
| .347{{fsp|3}} | 10.6{{fsp|3}} |
40
| .878{{fsp|3}} | 26.8{{fsp|3}} |
See also
References
{{reflist}}
External links
- [https://archive.today/20071130230852/http://www.isabellenhuette.de/en/research-development/ Isabellenhütte - 1889 Manganin]