mercury(II) nitrate
{{chembox
|Verifiedfields = changed
|Watchedfields = changed
|verifiedrevid = 441024345
|Name = Mercury(II) nitrate
|ImageFile = mercury nitrate.png
|ImageSize = 150px
|ImageFile2 =Mercury_nitrate_II,_hydrate.jpg
|ImageSize2 = 200px
|IUPACName = Mercury dinitrate
Mercury(II) nitrate
|OtherNames = Mercuric nitrate
|Section1={{Chembox Identifiers
|CASNo_Ref = {{cascite|correct|CAS}}
|CASNo = 10045-94-0
|CASNo2_Ref = {{cascite|changed|??}}
|CASNo2 = 7783-34-8
|CASNo2_Comment = (monohydrate)
|UNII_Ref = {{fdacite|changed|FDA}}
|UNII = 2FMV9338BW
|EINECS = 233-152-3
|UNNumber = 1625
|RTECS = OW8225000
|PubChem = 16683796
|ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
|ChemSpiderID = 23247
|SMILES = [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Hg+2]
|InChI = 1/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1
|InChIKey = ORMNPSYMZOGSSV-UHFFFAOYAS
|StdInChI_Ref = {{stdinchicite|changed|chemspider}}
|StdInChI = 1S/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1
|StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
|StdInChIKey = ORMNPSYMZOGSSV-UHFFFAOYSA-N
}}
|Section2={{Chembox Properties
|Formula = {{chem2|Hg(NO3)2}}
|MolarMass = 324.60 g/mol (anhydrous)
|Appearance = colorless crystals or white powder
|Odor = sharp
|Density = 4.3 g/cm3 (monohydrate)
|Solubility = soluble
|SolubleOther = soluble in nitric acid, acetone, ammonia
insoluble in ethanol
|MeltingPtC = 79
|MeltingPt_notes = (monohydrate)
|MagSus = −74.0·10−6 cm3/mol
}}
|Section3={{Chembox Hazards
|ExternalSDS = [http://www.inchem.org/documents/icsc/icsc/eics0980.htm ICSC 0980]
|GHSPictograms= {{GHS03}}{{GHS06}}{{GHS08}}{{GHS09}}
|GHSSignalWord = Danger
|HPhrases = {{H-phrases|272|300|310|330|373|410}}
|PPhrases = {{P-phrases|}}
|NFPA-H = 3
|NFPA-F = 0
|NFPA-R = 1
|NFPA-S = OX
|FlashPt = Nonflammable
}}
|Section4={{Chembox Related
|OtherAnions = Mercury(II) sulfate
Mercury(II) chloride
|OtherCations = Zinc nitrate
Cadmium nitrate
|OtherCompounds = Mercury(I) nitrate
}}
}}
Mercury(II) nitrate is an inorganic compound with the chemical formula {{chem2|Hg(NO3)2|auto=1}}. It is the mercury(II) salt of nitric acid {{chem2|HNO3}}. It contains mercury(II) cations {{chem2|Hg(2+)}} and nitrate anions {{chem2|NO3−}}, and water of crystallization {{chem2|H2O}} in the case of a hydrous salt. Mercury(II) nitrate forms hydrates {{chem2|Hg(NO3)2*xH2O}}. Anhydrous and hydrous salts are colorless or white soluble crystalline solids that are occasionally used as a reagents. Mercury(II) nitrate is made by treating mercury with hot concentrated nitric acid. Neither anhydrous nor monohydrate has been confirmed by X-ray crystallography.{{Cite journal |last=Nolte |first=M. |last2=Pantenburg |first2=I. |last3=Meyer |first3=G. |date=9 December 2005 |title=The Monohydrate of Basic Mercuric Nitrate, [Hg(OH)](NO3)(H2O) |url=https://onlinelibrary.wiley.com/doi/10.1002/zaac.200500344 |journal=Zeitschrift für anorganische und allgemeine Chemie |language=de |publisher=Wiley Publishing |volume=632 |issue=1 |pages=111–113 |doi=10.1002/zaac.200500344 |issn=0044-2313 |access-date=16 May 2022 |archive-date=27 November 2021 |archive-url=https://web.archive.org/web/20211127161557/https://onlinelibrary.wiley.com/doi/10.1002/zaac.200500344 |url-status=live}} The anhydrous material is more widely used.{{cln|reason=The last two sentences contradict each other! Anhydrous form is not confirmed by the X-ray crystallography, but is used widely. What???|date=May 2024}}
Uses
Mercury(II) nitrate is used as an oxidizing agent in organic synthesis, as a nitrification agent, as an analytical reagent in laboratories, in the manufacture of felt, and in the manufacture of mercury fulminate.{{Cite web |date=2023 |title=Mercury nitrate monohydrate |url=https://www.chemicalbook.com/ChemicalProductProperty_EN_CB0355067.htm |access-date=June 30, 2024 |website=Chemical Book}}
An alternative qualitative Zeisel test can be done with the use of mercury(II) nitrate instead of silver nitrate, leading to the formation of scarlet red mercury(II) iodide.{{Cite book|last=Wang|first=Zerong|title=Comprehensive Organic Name Reactions and Reagents|publisher=John Wiley & Sons|year=2010|pages=3115–3118|chapter=Zeisel Determination|doi=10.1002/9780470638859.conrr689|isbn=9780470638859}}
Health information
Mercury compounds are highly toxic. The use of this compound by hatters and the subsequent mercury poisoning of said hatters is a common theory of where the phrase "mad as a hatter" came from.
See also
References
External links
- [https://wwwn.cdc.gov/TSP/ToxFAQs/ToxFAQsLanding.aspx?id=113&tid=24 ATSDR - Toxic Substances Portal - Mercury] (11/14/2013)
- [https://wwwn.cdc.gov/TSP/PHS/PHSLanding.aspx?id=112&tid=24 ATSDR - Public Health Statement: Mercury] (11/14/2013)
- [https://web.archive.org/web/20000115113813/http://www.atsdr.cdc.gov/alerts/970626.html ATSDR - ALERT! Patterns of Metallic Mercury Exposure, 6/26/97] (link not traceable 11/14/2013)
- [https://web.archive.org/web/20091208112104/http://www.atsdr.cdc.gov/MMG/MMG.asp?id=106&tid=24 ATSDR - Medical Management Guidelines for Mercury] (11/14/2013)
- [https://www.atsdr.cdc.gov/toxprofiledocs/index.html?id=115&tid=24 ATSDR - Toxicological Profile: Mercury] (11/14/2013)
- [http://www.pcl.ox.ac.uk/MSDS/ME/mercury_II_nitrate.html Safety data (MSDS)]{{Dead link|date=December 2023 |bot=InternetArchiveBot |fix-attempted=yes}} (link not traceable 11/14/2013)
- [http://www.inchem.org/documents/icsc/icsc/eics0980.htm Mercuric Nitrate (ICSC)]
- [http://www.speclab.com/elements/mercury.htm Mercury] {{Webarchive|url=https://web.archive.org/web/20180217133713/http://www.speclab.com/elements/mercury.htm |date=2018-02-17}}
- [https://web.archive.org/web/20060929051529/http://www.sustainablehospitals.org/HTMLSrc/IP_Merc_Tools_List.html Mercury Information Packages]
- How to Make Good Mercury Electrical Connections, Popular Science monthly, February 1919, Unnumbered page, Scanned by Google Books: https://books.google.com/books?id=7igDAAAAMBAJ&pg=PT14
{{Mercury compounds}}
{{nitrates}}