methanetellurol

{{Chembox

| ImageFile = MeTeH.svg

| ImageSize =

| ImageAlt =

| IUPACName = Methanetellurol

| OtherNames =

|Section1={{Chembox Identifiers

| CASNo = 25284-83-7

| PubChem = 356643

| ChemSpiderID = 14564633

| InChI = 1S/CH4Te/c1-2/h2H,1H3

| InChIKey = JNLXBRURJAYDTD-UHFFFAOYSA-N

| SMILES = C[TeH]

}}

|Section2={{Chembox Properties

| Formula = {{chem2|CH3TeH}}

| C=1|H=4|Te=1

| Appearance = colorless gas

}}

|Section8={{Chembox Related

| OtherCompounds = {{ubl|Methanol|Methanethiol|Methaneselenol}}

}}

}}

Methanetellurol is the organotellurium compound with the formula {{chem2|CH3TeH|auto=1}}. It is the simplest organotellurium compound that has been purified in bulk. It is classified as a tellurol. A colorless gas, it decomposes to Te and methane near room temperature. It is prepared by reduction of dimethyl ditelluride using Na/Ammonia followed by protonation of the {{chem2|CH3Te−Na+}} (sodium methanetellurolate) with sulfuric acid. Few publications describe this compound as a consequence of its instability and paucity of applications.

According to IR spectroscopy, νTe-H = 1995 cm−1. For the lighter homologues, νE-H = 2342 (E = Se), 2606 (E = S), and 3710 cm−1 (E = O) for methaneselenol, methanethiol, and methanol.{{cite journal |doi=10.1080/00945717708069709|title=The Synthesis and the Raman and Infrared Spectra of Methanetellurol|year=1977|last1=Hamada|first1=K.|last2=Morishita|first2=H.|journal=Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry|volume=7|issue=4|pages=355–366}}

References