methylcyclohexanone
Methylcyclohexanones are a group of three isomers: 2-methylcyclohexanone, 3-methylcyclohexanone, and 4-methylcyclohexanone.{{cite book |doi=10.1002/14356007.a08_217 |chapter=Cyclohexanol and Cyclohexanone |title=Ullmann's Encyclopedia of Industrial Chemistry |date=2000 |last1=Musser |first1=Michael Tuttle |isbn=3527306730 }} They can be viewed as derivative of cyclohexanone. They can be prepared by oxidation of methylcyclohexane as well as partial hydrogenation of the corresponding cresols. All are colorless liquids. The 2- and 3-isomers are chiral.
class="wikitable"
|+ Methylcyclohexanones | |||||
Isomer | Structure | CAS RN | m.p. (°C) | b.p. (°C) | density (g/cm3) |
---|---|---|---|---|---|
2-Methylcyclohexanone | 90px | 583-60-8 | −13.9 | 165.1 | 0.925 |
3-Methylcyclohexanone | 90px | 591-24-2 | −73.5 | 170.0 | 0.920 |
4-Methylcyclohexanone | 66px | 589-92-4 | −40.6 | 171.3 | 0.916 |