phenoxathiin
{{Chembox
| ImageFile = Phenoxathiin.svg
| ImageSize = 200px
| ImageAlt =
| PIN = Phenoxathiine
| OtherNames = 1,4-Dibenzothioxine
| Section1 = {{Chembox Identifiers
| CASNo = 262-20-4
| CASNo_Ref = {{cascite|correct|CAS}}
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = BJC51V8XW8
| PubChem = 9217
| ChemSpiderID = 8862
| SMILES = c1ccc2c(c1)Oc3ccccc3S2
| StdInChI=1S/C12H8OS/c1-3-7-11-9(5-1)13-10-6-2-4-8-12(10)14-11/h1-8H
| StdInChIKey = GJSGGHOYGKMUPT-UHFFFAOYSA-N
}}
| Section2 = {{Chembox Properties
| C=12|H=8|O=1|S=1
| Appearance =
| Density =
| MeltingPtC = 52-56
| MeltingPt_ref = {{cite web | url = http://www.sigmaaldrich.com/catalog/product/aldrich/218820?lang=en | title = Phenoxathiin | publisher = Sigma-Aldrich}}
| BoilingPtC = 150-152
| BoilingPt_notes = (at 5 mmHg)
| Solubility =
}}
| Section3 = {{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt =
}}
}}
Phenoxathiin (dibenzooxathiane) C12H8OS is a heterocyclic compound of molecular weight 200.25632 g/mol with the CAS Registry Number 262-20-4.The Chemistry of Phenoxathiin and its Derivatives. Clara L. Deasy Chem. Rev., 1943, 32 (2), pp 173–194 DOI: 10.1021/cr60102a001 Publication Date: April 1943
Diphenyl ether is a starting material in the production of phenoxathiin via the Ferrario reaction.{{OrgSynth
| author = Suter, C. M.
| author2 = Maxwell, C. E.
| title = Phenoxthin
| journal = Organic Syntheses
| collvol = 2
| issue =
| collvolpages = 485
| year = 1943
| prep = cv2p0485}} Phenoxathiin is used in polyamide and polyimide production.{{cite journal
|author1=Mitsuru Ueoda |author2=Tatsuo Aizawa |author3=Yoshio Imai | title = Preparation and properties of polyamides and polyimides containing phenoxathiin units
| journal = Journal of Polymer Science: Polymer Chemistry Edition
| volume = 15
| issue = 11
| pages = 2739–2747
| year = 1977
| publisher =
| location =
| doi =10.1002/pol.1977.170151119 }}
References
{{Reflist}}
External links
- [http://www.chemicalbook.com/ChemicalProductProperty_EN_CB9759761.htm Chemicalbook.com]
- [http://webbook.nist.gov/cgi/cbook.cgi?ID=262-20-4 Webbook.nist.gov]