polybutylene terephthalate

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| IUPACName = Poly(oxy-1,4-butanediyloxycarbonyl-1,4-phenylenecarbonyl)

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| CASNo = 24968-12-5

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| Properties_ref =[http://www.britannica.com/EBchecked/topic/468341/polybutylene-terephthalate Polybutylene-terephthalate] on Britannica

| Formula = (C12H12O4)n

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Polybutylene terephthalate (PBT) is a thermoplastic engineering polymer that is used as an insulator in the electrical and electronics industries.{{Cite journal|last1=De Vos|first1=Lobke|last2=Van de Voorde|first2=Babs|last3=Van Daele|first3=Lenny|last4=Dubruel|first4=Peter|last5=Van Vlierberghe|first5=Sandra|date=2021-12-05|title=Poly(alkylene terephthalate)s: From current developments in synthetic strategies towards applications|url=https://www.sciencedirect.com/science/article/pii/S0014305721005747|journal=European Polymer Journal|language=en|volume=161|pages=110840|doi=10.1016/j.eurpolymj.2021.110840|bibcode=2021EurPJ.16110840D |issn=0014-3057|hdl=1854/LU-8730084|hdl-access=free}} It is a thermoplastic (semi-)crystalline polymer, and a type of polyester. PBT resists solvents, shrinks very little during forming, is mechanically strong, is heat-resistant up to {{nowrap|150 °C}} (or {{nowrap|200 °C}} with glass-fibre reinforcement), and can be treated with flame retardants to make it noncombustible. It was developed by Britain's Imperial Chemical Industries (ICI).{{cite journal | journal=Le Moniteur de l'Automobile | page= 10 | title=BL passe la 3ème vitesse | trans-title = BL puts it into third | last=Renaux | first=Jean-Jacques | location=Brussels, Belgium | language=fr | volume=34 | number=764 | date=1983-03-10 | ref = mon764 | publisher=Editions Auto-Magazine }}

PBT is closely related to other thermoplastic polyesters. Compared to PET (polyethylene terephthalate), PBT has slightly lower strength and rigidity, slightly better impact resistance, and a slightly lower glass transition temperature. PBT and PET are sensitive to hot water above {{nowrap|60 °C}} (140 °F). PBT and PET need UV protection if used outdoors, and most grades of these polyesters are flammable, although additives can be used to improve both UV and flammability properties.

PBT is produced by the polymerization of 1,4-butanediol and terephthalic acid.{{Cite web |date=2023-06-01 |title=Polybutylene terephthalate (PBT) {{!}} Britannica |url=https://www.britannica.com/science/polybutylene-terephthalate |access-date=2023-11-24 |archive-url=https://web.archive.org/web/20230601202255/https://www.britannica.com/science/polybutylene-terephthalate |archive-date=2023-06-01 }}{{Cite web |date=2023-11-24 |title=Polybutylene Terephthalate PBT and Butanediol – Chemical production and investment cost {{!}} S&P; Global |url=https://www.spglobal.com/commodityinsights/en/ci/products/chemical-technology-pep-polybutylene-terephthalate-1997.html |access-date=2023-11-24 |archive-url=https://web.archive.org/web/20231124155828/https://www.spglobal.com/commodityinsights/en/ci/products/chemical-technology-pep-polybutylene-terephthalate-1997.html |archive-date=2023-11-24 }}

Applications

Polybutylene terephthalate is used for housings in electrical engineering, but also in automotive construction as plug connectors and in households for example in showerheads or irons. It is also found processed into toothbrush fibers and false eyelashes and is used in the keycaps{{cite web |title=ErgoDox-EZ—Our Keycaps |url=https://ergodox-ez.com/pages/our-keycaps |website=ErgoDox-EZ |publisher=ZSA Technology Labs, Inc. |access-date=17 April 2020}}{{cite web |title=Prismcaps | SteelSeries |url=https://steelseries.com/gaming-accessories/prismcaps?color=black |website=Steelseries |publisher=SteelSeries ApS |access-date=29 March 2023}} of some high-end computer keyboards because the texture is highly resistant to wear and the plastic is less vulnerable to ultraviolet degradation{{cite web |title=UV Properties of Plastics: Transmission and Resistance|url=https://www.coleparmer.com/tech-article/uv-properties-of-plastics |website=Cole-Parmer |access-date=27 January 2023}} and discoloration than the conventional ABS alternative.

PBT can also be made into yarn. This has a natural stretch similar to Lycra and can be incorporated into sportswear. Due to its chlorine resistance it is commonly found in swimwear. Further, recent studies have shown that PBT has superior UV properties to PET based fabrics such as T400.{{cite web|url=https://www.macrointlco.com/sports-performance-fabrics/pbt-fabric|title=Macro PBT fabric in stock in the USA|date=7 March 2017|access-date=27 August 2018}}

PBT, especially glass fibre grades, can be effectively fire-retarded with halogen-free products. Phosphorus-based flame retardant systems are used in these fire-safe polymers and are based on aluminium diethyl phosphinate and synergists. They are designed to meet UL 94 flammability tests as well as Glow Wire Ignition Tests (GWIT), Glow Wire Flammability Test (GWFI) and Comparative Tracking Index (CTI). Main applications are in the electrical and electronics (E&E) industry.

Producers

References