reidite

{{Short description|Polymorph of ZrSiO4}}

{{Infobox mineral

| name = Reidite

| category = Zircon group

| boxwidth =

| boxbgcolor = #7da7d9

| image =

| caption =

| formula = ZrSiO4

| IMAsymbol = Rei{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3 |pages=291–320|doi=10.1180/mgm.2021.43 |bibcode=2021MinM...85..291W |s2cid=235729616 |doi-access=free}}

| molweight = 183.31 g/mol

| strunz = 9.AD.45

| dana =

| system = Tetragonal

| class = Dipyramidal (4/m)
H-M symbol: (4/m)

| symmetry = I41/a

| unit cell = a = 4.738, c = 10.506 [Å], Z = 4

| color = Colorless to white

| habit = Epitaxial - crystallographic alignment with a precursor mineral,

occurs as inclusions in other minerals.

| twinning =

| cleavage = None

| fracture = Irregular/uneven

| tenacity = Brittle

| mohs = 7.5

| luster = Adamantine

| refractive = nω=1.64, nε=1.655

| opticalprop = Uniaxial (+)

| birefringence = 0.0150

| pleochroism = None

| streak = White

| gravity = 5.16

| density =

| melt =

| fusibility =

| diagnostic =

| solubility =

| diaphaneity = Translucent

| other =

| references = {{cite web|title=Reidite|url=http://www.mindat.org/min-11467.html|website=mindat.org|publisher=Hudson Institute of Mineralogy|accessdate=18 March 2015}}{{cite web|title=Reidite Mineral Data|url=http://webmineral.com/data/Reidite.shtml#.VQivio7F-So|website=Webmineral.com|accessdate=18 March 2015}}}}

Reidite is a rare polymorph of ZrSiO4 created when zircon experiences high pressure and temperature. Reidite is denser than zircon and has the same crystal structure as scheelite. All natural occurrences of reidite are associated with meteorite impact events.

On Earth, reidite has been reported from ten impact structures: the Chesapeake Bay Crater in Virginia; Ries Crater in Germany; Xiuyan Crater in China; Woodleigh Crater in Western Australia;[https://www.abc.net.au/news/2018-10-16/rare-mineral-reidite-found-in-woodleigh-meteorite-crater-in-wa/10382888 Discovery of reidite, one of the rarest minerals on Earth, may reveal Australia's biggest crater] ABC News, 16 October 2018. Retrieved 17 October 2018. Rock Elm Crater in Wisconsin;{{cite web| last1=Oskin| first1=Becky| title=Rare Mineral Discovered in Ancient Meteorite Impact Crater| url=http://www.livescience.com/48584-reidite-discovered-rock-elm-wisconsin.html| website=Livescience.com| date=3 November 2014|publisher=Livescience|accessdate=24 March 2015}} Dhala Crater in India;{{Cite journal|last1=Li|first1=Shan-Shan|last2=Keerthy|first2=S.|last3=Santosh|first3=M.|last4=Singh|first4=S.P.|last5=Deering|first5=C.D.|last6=Satyanarayanan|first6=M.|last7=Praveen|first7=M.N.|last8=Aneeshkumar|first8=V.|last9=Indu|first9=G.K.|title=Anatomy of impactites and shocked zircon grains from Dhala reveals Paleoproterozoic meteorite impact in the Archean basement rocks of Central India|journal=Gondwana Research|volume=54|pages=81–101 |date=February 2018 |doi=10.1016/j.gr.2017.10.006|bibcode=2018GondR..54...81L}} Stac Fada in Scotland; Haughton in Canada; Steen River in Canada, and Rochechouart in France. Reidite has also been found in one lunar meteorite.{{Cite journal |last1=Xing |first1=Weifan |last2=Lin |first2=Yangting |last3=Zhang |first3=Chi |last4=Zhang |first4=Mingming |last5=Hu |first5=Sen |last6=Hofmann |first6=Beda A. |last7=Sekine |first7=Toshimori |last8=Xiao |first8=Long |last9=Gu |first9=Lixin |date=2020-11-16 |title=Discovery of Reidite in the Lunar Meteorite Sayh al Uhaymir 169 |url=https://onlinelibrary.wiley.com/doi/10.1029/2020GL089583 |journal=Geophysical Research Letters |language=en |volume=47 |issue=21 |doi=10.1029/2020GL089583 |bibcode=2020GeoRL..4789583X |s2cid=226337486 |issn=0094-8276}}

Name origin and discovery

Reidite is named after Alan F. Reid, the scientist who first synthesized it during high-pressure experiments in the laboratory in 1969.{{Cite journal |last1=Reid |first1=A. F. |last2=Ringwood |first2=A. E. |date=1969-06-01 |title=Newly observed high pressure transformations in Mn3O4, CaAl2O4, and ZrSiO4 |url=https://dx.doi.org/10.1016/0012-821X%2869%2990091-0 |journal=Earth and Planetary Science Letters |language=en |volume=6 |issue=3 |pages=205–208 |doi=10.1016/0012-821X(69)90091-0 |issn=0012-821X}}

Reidite was first discovered in natural samples by B.P. Glass and Shaobin Liu in 2001.{{Cite journal |last1=Glass |first1=B.P. |last2=Liu |first2=Shaobin |date=2001-04-01 |title=Discovery of high-pressure ZrSiO4 polymorph in naturally occurring shock-metamorphosed zircons |url=https://doi.org/10.1130/0091-7613(2001)0292.0.CO;2 |journal=Geology |volume=29 |issue=4 |pages=371–373 |doi=10.1130/0091-7613(2001)029<0371:DOHPZP>2.0.CO;2 |issn=0091-7613}}

Occurrence

Reidite is formed from zircon above ~30GPa in shock recovery experiments. However, the temperatures generated during meteorite impacts are much higher, and reidite can be formed down to ~9GPa under natural impact conditions.{{Cite journal |last1=Timms |first1=Nicholas E. |last2=Erickson |first2=Timmons M. |last3=Pearce |first3=Mark A. |last4=Cavosie |first4=Aaron J. |last5=Schmieder |first5=Martin |last6=Tohver |first6=Eric |last7=Reddy |first7=Steven M. |last8=Zanetti |first8=Michael R. |last9=Nemchin |first9=Alexander A. |last10=Wittmann |first10=Axel |date=2017-02-01 |title=A pressure-temperature phase diagram for zircon at extreme conditions |journal=Earth-Science Reviews |language=en |volume=165 |pages=185–202 |doi=10.1016/j.earscirev.2016.12.008 |issn=0012-8252|doi-access=free |bibcode=2017ESRv..165..185T }} Reidite has been found in lamellar, granular, and dendritic forms within host zircon, typically making up less than 10% of the grain. Reidite from Rochechouart impact structure has also been reported as bladed, wedged, and massive.{{Cite journal |last1=Plan |first1=Anders |last2=Kenny |first2=Gavin G. |last3=Erickson |first3=Timmons M. |last4=Lindgren |first4=Paula |last5=Alwmark |first5=Carl |last6=Holm-Alwmark |first6=Sanna |last7=Lambert |first7=Philippe |last8=Scherstén |first8=Anders |last9=Söderlund |first9=Ulf |last10=Osinski |first10=Gordon |date=October 2021 |title=Exceptional preservation of reidite in the Rochechouart impact structure, France: New insights into shock deformation and phase transition of zircon |journal=Meteoritics & Planetary Science |language=en |volume=56 |issue=10 |pages=1795–1828 |doi=10.1111/maps.13723 |s2cid=238711754 |issn=1086-9379|doi-access=free |bibcode=2021M&PS...56.1795P }}

Libyan desert glass may show lattice deformation in zircon that is interpreted as evidence of this material having previously contained reidite, and as such constitutes strong evidence for its impact origin.{{Cite web |last=Cavosie |first=Aaron J. |title=How we solved the mystery of Libyan desert glass |url=http://theconversation.com/how-we-solved-the-mystery-of-libyan-desert-glass-117253 |access-date=2019-10-12 |website=The Conversation |date=22 May 2019 |language=en}}

Related silica minerals

class="wikitable"

|+ Relationship of Reidite to Other Specimens

| 9.AD.25

UvaroviteCa3Cr2(SiO4)3
9.AD.25Wadalite(Ca,Mg)6(Al,Fe3+)4((Si,Al)O4)3O4Cl3
9.AD.25HoltstamiteCa3(Al,Mn3+)2(SiO4)2(OH)4
9.AD.25KerimasiteCa3Zr2(SiO4)(Fe3+O4)2
9.AD.25ToturiteCa3Sn2(SiO4)(Fe3+O4)2
9.AD.25Momoiite(Mn2+,Ca)3V23+(SiO4)3
9.AD.25EltyubyuiteCa12Fe103+Si4O32Cl6
9.AD.25HutcheoniteCa3Ti2(SiAl2)O12
9.AD.30Coffinite(U4+,Th)(SiO4)1-x(OH)4x
9.AD.30HafnonHfSiO4
9.AD.30Thorite(Th,U)SiO4
9.AD.30ZirconZrSiO4
9.AD.30StetinditeCe4+SiO4
9.AD.35HuttoniteThSiO4
9.AD.35Tombarthite-(Y)Y4(Si,H4)4O12−x(OH)4+2x
9.AD.40EulytineBi4(SiO4)3

See also

References