sinoite

{{Infobox mineral

| name = Sinoite

| category = Silicate mineral

| boxwidth =

| boxbgcolor =

| image = Sinoite.png

| caption = Crystal structure of sinoite. Atoms: red – O, blue – N, gray – Si.

| formula = Si2N2O

| IMAsymbol = Sno{{Cite journal|last=Warr|first=L.N.|date=2021|title=IMA–CNMNC approved mineral symbols|journal=Mineralogical Magazine|volume=85|issue=3|pages=291–320|doi=10.1180/mgm.2021.43|bibcode=2021MinM...85..291W|s2cid=235729616|doi-access=free}}

| molweight =

| strunz = 1.DB.10

| dana = 1.3.9.1

| system = Orthorhombic

| class = Pyramidal (mm2)
H-M symbol: (mm2)

| symmetry = Cmc21

| unit cell = a = 8.84 Å, b = 5.47 Å
c = 4.83 Å, Z = 4

| color = From colorless to light gray

| twinning =

| cleavage = None

| fracture =

| tenacity =

| mohs =

| luster = Vitreous

| refractive = nα = 1.740
nβ = 1.855
nγ = 1.855

| opticalprop = Biaxial (-)

| birefringence = δ = 0.115

| pleochroism =

| streak = White

| gravity = 2.83

| diaphaneity = Transparent to translucent

| references = [http://rruff.geo.arizona.edu/doclib/hom/sinoite.pdf Sinoite]. Handbook of Mineralogy[http://www.mindat.org/min-3676.html Sinoite]. Mindat.org[http://webmineral.com/data/Sinoite.shtml Sinoite]. Webmineral

}}

Sinoite is a rare mineral with the chemical formula Si2N2O. It was first found in 1905 in chondrite meteorites and identified as a distinct mineral in 1965. Sinoite crystallizes upon meteorite impact as grains smaller than 0.2 mm surrounded by Fe-Ni alloys and the mineral enstatite. It is named after its SiNO composition and can be prepared in the laboratory as a silicon oxynitride ceramic.

The crystalline structure of silicon oxynitride is built by SiN3O tetrahedra connected through oxygen atoms along the c axis and through nitrogen atoms perpendicular to it. The strong covalent bonding of this structure results in high flexural strength and resistance to heating and oxidation up to temperatures of about 1600 °C.

{{clear|left}}

References

{{reflist|refs=

{{cite book|author=Ralf Riedel|title=Ceramics science and technology: Structures|url=https://books.google.com/books?id=I-WFvgkBiEMC&pg=PA97|accessdate=8 October 2011|date=18 April 2008|publisher=Wiley-VCH|isbn=978-3-527-31155-2|pages=97–}}

{{cite journal|url=http://www.minsocam.org/msa/ammin/toc/Articles_Free/1997/Rubin_p1001-1006_97.pdf|journal=American Mineralogist|author=A. E. Rubin|title=Sinoite (Si2N2O): Crystallization from EL chondrite impact melts|volume=82|page=1001|year=1997|issue=9–10|doi=10.2138/am-1997-9-1016|bibcode=1997AmMin..82.1001R|s2cid=128629202}}

{{cite journal|title=Solid Solubility of Aluminum in O'-SiAlON|journal=J. Am. Ceram. Soc.|author= Ohashi, Masayoshi|year=1993|volume=76|pages=2112–2114|doi=10.1111/j.1151-2916.1993.tb08343.x|issue=8|display-authors=etal}}

}}

Category:Native element minerals

Category:Orthorhombic minerals

Category:Minerals in space group 36