sodium diuranate

In the classical procedure for extracting uranium, pitchblende is broken up and mixed with sulfuric and nitric acids.{{cite web |url=http://www.mqes-uranium.com/metallurgy.html |title=MQes Uranium Inc. |language=en |access-date=2016-06-01 }} The uranium dissolves to form uranyl sulfate and sodium carbonate is added to precipitate impurities. If the uranium in the ore is in the tetravalent oxidation state, an oxidiser is added to oxidise it to the hexavalent oxidation state, and sodium hydroxide is then added to make the uranium precipitate as sodium diuranate.[https://patents.google.com/patent/US3034856A/en Purification of sodium diuranate]. Retrieved 2020-04-30

The alkaline process of milling uranium ores involves precipitating sodium uranate from the pregnant leaching solution to produce the semi-refined product referred to as yellowcake.[https://patents.google.com/patent/US3097919A/en Method of precipitation of sodium diuranate]. Retrieved 2020-04-30

These older methods of extracting uranium from its uraninite ores has been replaced in current practice by such procedures as solvent extraction, ion exchange, and volatility methods.Gindler, J. E. (1962). [https://web.archive.org/web/20170827072749/http://www.radiochemistry.org/periodictable/pdf_books/pdf/rc000068.pdf The Radiochemistry of Uranium] p. 39–235

Sodium uranate may be obtained in the amorphous form by heating together urano-uranic oxide and sodium chlorate; or by heating sodium uranyl acetate or carbonate. The crystalline form is produced by adding the green oxide in small quantities to fused sodium chloride, or by dissolving the amorphous form in fused sodium chloride, and allowing crystallization to take place. It yields reddish-yellow to greenish-yellow prisms or leaflets.

File:AW U glass bowl on fiestaware plate.jpg bowl in the shape of a cat, on top of a fiestaware plate, both previous uses of sodium diuranate.]]

In the past it was widely used to produce uranium glass or vaseline glass,{{cite journal|url=https://pubs.rsna.org/doi/pdf/10.1148/radiographics.13.3.8316677|doi = 10.1148/radiographics.13.3.8316677|title = A brief history of radioactive glassware|year = 1993|last1 = Landa|first1 = E. R.|last2 = Disantis|first2 = D. J.|journal = Radiographics|volume = 13|issue = 3|pages = 697–699|pmid = 8316677}} the sodium salt dissolving easily into the silica matrix during the firing of the initial melt.

It was also used in porcelain dentures to give them a fluorescence similar to that of natural teeth and once used in pottery to produce ivory to yellow shades in glazes.{{cite web |url=https://www.orau.org/ptp/collection/consumer%20products/dentures.htm |title=Uranium Containing Dentures (ca. 1960s, 1970s) |language=en |access-date=2016-06-01 }} It was added to these products as a mix with cerium oxide.{{cite journal |last1=Shcherbakov |first1=Alexander B. |last2=Reukov |first2=Vladimir V. |last3=Yakimansky |first3=Alexander V. |last4=Krasnopeeva |first4=Elena L. |last5=Ivanova |first5=Olga S. |last6=Popov |first6=Anton L. |last7=Ivanov |first7=Vladimir K. |title=CeO₂ Nanoparticle-Containing Polymers for Biomedical Applications: A Review |journal=Polymers |date=17 March 2021 |volume=13 |issue=6 |pages=924 |doi=10.3390/polym13060924 |pmid=33802821 |pmc=8002506 |issn=2073-4360|doi-access=free }} The final uranium composition was from 0.008 to 0.1% by weight uranium with an average of about 0.02%. The practice appears to have stopped in the late 1980s.

{{Reflist}}

• [https://www.nrc.gov/reading-rm/basic-ref/glossary/yellowcake.html NRC Glossary]
• [http://uranium.atomistry.com/sodium_uranate.html Sodium Uranate Heats of Formation]
• [http://ibilabs.com/msds/new-uranyl-compounds-msds/sodium-uranate-msds/ MSDS] {{Webarchive|url=https://web.archive.org/web/20210302225749/http://ibilabs.com/msds/new-uranyl-compounds-msds/sodium-uranate-msds/ |date=2021-03-02 }}
• {{cite journal | doi = 10.1016/0022-5088(86)90198-0 | title = Na₂U₂O₇: Synthèse et structure d'un monocristal | year = 1986 | last1 = Gasperin | first1 = M. | journal = Journal of the Less Common Metals | volume = 119 | pages = 83–90}}

{{Sodium compounds}}

{{Uranium compounds}}

{{DEFAULTSORT:Sodium Diuranate}}

Category:Sodium compounds

Category:Uranates

Category:Nuclear materials